RESUMEN
The droplet transfer across an interface in a microchannel is extensively utilized in diverse fields; however, it is challenging to drive droplets to penetrate the interface at such a small scale. In this study, a novel flow pattern of droplet transfer is observed and the mechanism is investigated; accordingly, an accurate prediction equation for determining the critical condition of droplet transfer is proposed. Meanwhile, the liquid film entrainment is also observed, which leads to the formation of an oil-in-water-in-water system. This study serves as a valuable reference for further studies on the mechanism of droplet transfer and provides practical guidance for its industrial application.
RESUMEN
Cis-alkenes are ubiquitous in biological molecules, which makes it greatly significant to develop efficient methods toward construction of cis-olefins. Herein, we reported a facile semi-hydrogenation of alkynes to cis-alkenes in an efficient way with cuprous bromide/tributylphosphine as the catalyst and bis(pinacolato)diboron/methanol as the hydrogen donor. The method features convenient and facile reaction conditions, wide substrate scope, high yields, and high stereoselectivity.