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1.
Phys Rev Lett ; 111(17): 176601, 2013 Oct 25.
Artículo en Inglés | MEDLINE | ID: mdl-24206509

RESUMEN

We perform a quantitative, comparative study of the spin pumping, spin Seebeck, and spin Hall magnetoresistance effects, all detected via the inverse spin Hall effect in a series of over 20 yttrium iron garnet/Pt samples. Our experimental results fully support present, exclusively spin current-based, theoretical models using a single set of plausible parameters for spin mixing conductance, spin Hall angle, and spin diffusion length. Our findings establish the purely spintronic nature of the aforementioned effects and provide a quantitative description, in particular, of the spin Seebeck effect.

2.
Phys Rev Lett ; 111(12): 127003, 2013 Sep 20.
Artículo en Inglés | MEDLINE | ID: mdl-24093293

RESUMEN

We report the observation of strong coupling between the exchange-coupled spins in a gallium-doped yttrium iron garnet and a superconducting coplanar microwave resonator made from Nb. The measured coupling rate of 450 MHz is proportional to the square root of the number of exchange-coupled spins and well exceeds the loss rate of 50 MHz of the spin system. This demonstrates that exchange-coupled systems are suitable for cavity quantum electrodynamics experiments, while allowing high integration densities due to their spin densities of the order of one Bohr magneton per atom. Our results furthermore show, that experiments with multiple exchange-coupled spin systems interacting via a single resonator are within reach.

3.
J Am Chem Soc ; 130(47): 15927-37, 2008 Nov 26.
Artículo en Inglés | MEDLINE | ID: mdl-18959402

RESUMEN

Residual dipolar couplings (RDCs) measured for internally rigid molecular fragments provide important information about the relative orientations of these fragments. Dependent on the symmetry of the alignment tensor and the symmetry of the molecular fragment, however, there generally exist more than one solution for the fragment orientation consistent with the measured RDCs. Analytical solutions are presented that describe the complete set of orientations of internally rigid fragments that are consistent with multiple dipolar couplings measured in a single alignment medium that is rhombic. For the first time, it is shown that, for a planar fragment such as the peptide plane, there generally exist 16 different solutions with their analytical expressions presented explicitly. The presence of these solutions is shown to be highly relevant for standard structure determination protocols using RDCs to refine molecular structures. In particular, when using standard protein structure refinement with RDCs that were measured in a single alignment medium as constraints, it is found that often more than one of the peptide plane solutions is physically viable; i.e., despite being consistent with measured RDCs, the local backbone structure can be incorrect. On the basis of experimental and simulated examples, it is rationalized why protein structures that are refined against RDCs measured in a single medium can have lower resolution (precision) than one would expect on the basis of the experimental accuracy of the RDCs. Conditions are discussed under which the correct solution can be identified.


Asunto(s)
Péptidos/química , Péptidos/metabolismo , Pliegue de Proteína , Proteínas/química , Proteínas/metabolismo , Aminoácidos/química , Simulación por Computador , Modelos Moleculares , Estructura Terciaria de Proteína , Estereoisomerismo
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