RESUMEN
Bromide ions (Br-) affected non-brominated nitroso-dimethylamine (NDMA) formation during ozonation, but the mechanism is still unclear. 1,1,1',1'-tetramethyl-4,4'-(methylene-di-p-phenylene) di-semicarbazide (TMDS) was chosen to further probe this problem. The results indicated that low levels of Br- (≤20 µM) enhanced NDMA from 3.27 to 7.56 µg/L, while its amount slightly dropped to 6.22 µg/L raising Br- to 100 µM. It was experimentally verified that intermediates 1,1-dimethylsemicarbazide (DMSC) and 1,1-dimethylhydrazine (UDMH) played important roles on promoting NDMA generation, whose contribution rates were 40.2% and 32.2%, respectively. The brominated substances with higher NDMA molar yields were detected. âOH reduced NDMA formation without Br-, while it played promotion role with Br-; the corresponding contribution rates were - 26.9% and 29.2%, respectively. No matter with or without Br-, both âO2- and lO2 brought a boost to NDMA formation, their contribution ratios were 34.9% and 58.1% without Br-, while raised significantly to 64.6% and 81.5% when Br- existed. Br- not only facilitated NDMA formation, but also benefited the degradation of TMDS. Based on the calculation results and intermediates detected, the influence mechanisms of Br- were proposed. The results would provide theoretical basis and technical guarantee for treating NDMA precursors and bromide co-existing water in the future.
Asunto(s)
Dimetilnitrosamina , Ozono , Especies Reactivas de Oxígeno , BromurosRESUMEN
In this study, calcined water treatment plant sludge (C-WTPS) was used as a catalyst for peroxymonosulfate (PMS) activation to simultaneously remove Disperse Blue 56 (DB56) and phosphates. Firstly, the performance of the C-WTPS/PMS system was examined for the degradation of DB56. The results showed that 96.7% of DB56 (400 mg L-1) was removed within 60 min in the presence of 4.8 g L-1 PMS and 0.8 g L-1 C-WTPS at pH 3 and 50 °C. Hydroxyl radicals (·OH), sulfate radicals (SO4·-), and singlet oxygen (1O2) were generated during the oxidation process, and 1O2 was the main active species. The relatively high surface area, proper Fe content, and abundant ketone groups on the catalyst surface were responsible for PMS activation. Furthermore, the possible degradation pathways of DB56 were proposed based on the gas chromatography-mass spectrometry (GC-MS) results. Secondly, the simultaneous removal of DB56 and phosphates by the C-WTPS/PMS system was investigated. Due to the different removal mechanisms, the effects of the initial phosphate concentration and water matrix species on the removal of DB56 and phosphates showed different trends. Reusability tests results showed that C-WTPS had relatively high stability. In addition, the C-WTPS/PMS system exhibited a high decolorization ratio and phosphate removal efficiency in real wastewater tests. This article offers a value-added approach for reusing WTPS as a catalyst for treating organic contaminants and phosphates.
Asunto(s)
Aguas del Alcantarillado , Purificación del Agua , Fosfatos , Peróxidos/química , Purificación del Agua/métodosRESUMEN
In this study, aluminum-based P-inactivation agent (Al-PIA) was used as a high-efficiency microbial carrier, and the biological Al-PIA (BA-PIA) was prepared by artificial aeration. Laboratory static experiments were conducted to study the effect of BA-PIA on reducing nitrogen and phosphorus contents in water. Physicochemical characterization and isotope tracing method were applied to analyze the removal mechanism of nitrogen and phosphorus. High-throughput techniques were used to analyze the characteristic bacterial genus in the BA-PIA system. The nitrogen and phosphorus removal experiment was conducted for 30 days, and the removal rates of NH4+-N, TN and TP by BA-PIA were 81.87%, 66.08% and 87.97%, respectively. The nitrogen removal pathways of BA-PIA were as follows: the nitrification reaction accounted for 59.0% (of which denitrification reaction accounted for 56.4%), microbial assimilation accounted for 18.1%, and the unreacted part accounted for 22.9%. The characteristic bacteria in the BA-PIA system were Streptomyces, Nocardioides, Saccharopolyspora, Nitrosomonas, and Marinobacter. The loading of microorganisms only changed the surface physical properties of Al-PIA (such as specific surface area, pore volume and pore size), without changing its surface chemical properties. The removal mechanism of nitrogen by BA-PIA is the conversion of NH4+-N into NO2--N and NO3--N by nitrifying bacteria, which are then reduced to nitrogen-containing gas by aerobic denitrifying bacteria. The phosphorus removal mechanism is that metal compounds (such as Al) on the surface of BA-PIA fix phosphorus through chemisorption processes, such as ligand exchange. Therefore, BA-PIA overcomes the deficiency of Al-PIA with only phosphorus removal ability, and has better application prospects.
Asunto(s)
Nitrógeno , Fósforo , Fósforo/metabolismo , Nitrógeno/metabolismo , Desnitrificación , Aluminio , Reactores Biológicos/microbiología , Aguas del Alcantarillado/química , Factores Biológicos/metabolismo , Nitrificación , Bacterias/metabolismo , Eliminación de Residuos LíquidosRESUMEN
In this article, dynamic simulation experiments have studied the effects of three capping materials, quartz sand (QS), aluminum-based phosphorus-locking agent (Al-PIA), and lanthanum-modified bentonite (LMB) in reducing phosphorus load in eutrophic water bodies. The changes of various forms of phosphorus in Al-PIA and sediment before and after the test were analyzed, and the mechanism of phosphorus migration and transformation in different capping systems was described. The dynamic simulation test lasted 95 days. The results showed that when the initial concentration of total phosphorus (TP) was 3.55 mg/L, the capping strength was 2 kg/m2 and the hydraulic retention time of water circulation was 0.5 days, indicating that the average reduction rates of TP by LMB, Al-PIA and QS systems were 74.66%, 69.54%, and 3.64%, respectively, compared with the control system. The analysis of variance showed that there were significant differences (P < 0.05) in the TP concentration of the overlying water between the LMB, Al-PIA capping system, and the control system. Lanthanum ions in LMB can fix phosphorus. Al-PIA reduces the phosphorus concentration in water by means of ion exchange, adsorption, complexation, etc. LMB and Al-PIA promoted the migration of phosphorus in sediment. Among them, the phosphorus fixed by Al-PIA was mainly in the form of non-apatite inorganic phosphorus (NAIP) in inorganic phosphorus (IP), which can be seen; Al-PIA can effectively reduce the phosphorus load of eutrophic water.
Asunto(s)
Fósforo , Contaminantes Químicos del Agua , Eutrofización , Sedimentos Geológicos , Lagos , Agua , Contaminantes Químicos del Agua/análisisRESUMEN
It is well-known that the activated thin-layer capping covering by secondary capping of contaminated sediment poses a threat to the inactivation of activated material. In this study, the static simulation experiment was conducted to study the effect of secondary capping thickness by sediment on the control of TP release from the sediment by aluminum-based P-inactivation agent (Al-PIA), and to propose the phosphorus adsorption pathway of Al-PIA. The results showed that Al-PIA could effectively reduce the release of phosphorus pollutants from the sediment at the capping intensity of 2 kg/m2. When the secondary capping thickness of sediment were 0, 2, 4, 7, 10, and 15 mm, the average removal rates of TP were 87.57%, 76.39%, 61.22%, 51.32%, 41.93%, and 32.11%, respectively, indicating that the removal efficiency of phosphorus decreased with the increase of the secondary capping thickness of the sediment. The adsorbed phosphorus by Al-PIA was mainly non-apatite inorganic phosphorus (NAIP) in inorganic phosphorus. With the increase of the secondary capping thickness of sediment, the NAIP proportion of phosphorus adsorbed by Al-PIA increased. Meanwhile, the removal rate of phosphorus in the activated capping system showed a first increase and then decrease trend, and the removal rates of total phosphorus (TP), inorganic phosphorus (IP), and organic phosphorus (OP) were obvious except for that of organic phosphorus (OP).