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1.
Sci Adv ; 10(23): eadl4264, 2024 Jun 07.
Artículo en Inglés | MEDLINE | ID: mdl-38838148

RESUMEN

Rock strength has long been linked to lithospheric deformation and seismicity. However, independent constraints on the related elastic heterogeneity are missing, yet could provide key information for solid Earth dynamics. Using coseismic Global Navigation Satellite Systems (GNSS) data for the 2011 M9 Tohoku-oki earthquake in Japan, we apply an inverse method to infer elastic structure and fault slip simultaneously. We find compliant material beneath the volcanic arc and in the mantle wedge within the partial melt generation zone inferred to lie above ~100 km slab depth. We also identify low-rigidity material closer to the trench matching seismicity patterns, likely associated with accretionary wedge structure. Along with traditional seismic and electromagnetic methods, our approach opens up avenues for multiphysics inversions. Those have the potential to advance earthquake and volcano science, and in particular once expanded to InSAR type constraints, may lead to a better understanding of transient lithospheric deformation across scales.

2.
ACS Omega ; 8(34): 31468-31479, 2023 Aug 29.
Artículo en Inglés | MEDLINE | ID: mdl-37663458

RESUMEN

CaSO4 has the advantages of abundant yield, high oxygen-carrying capacity, low cost, and no heavy metal pollution, making it promising as an oxygen carrier for chemical looping combustion (CLC). In comparison with other oxygen carriers, CaS as the reduced product of CaSO4 exhibits superior adsorption efficiency for Hg0 in the flue gas. In this paper, density functional theory (DFT) was used to investigate the adsorption mechanism of Hg0 on the adsorbent surface of CaS(001). The adsorption energies of different oxidized mercury species such as HgS, HgCl, and HgBr over the CaS surface were summarized. Furthermore, the effects of various flue gas components including SO2, H2S, S, HCl, Cl2, CO, H2, H2O, and C on Hg0 adsorption over the CaS(001) surface were evaluated. The results show that Hg0 can be adsorbed on the CaS(001) surface in a chemisorption manner with a reaction energy of -65.1 kJ/mol. The adsorption energy of different forms of mercury on the CaS(001) surface varies greatly, and mercury in the oxidized state is more easily captured by CaS. SO2 inhibits while other flue gas components promote Hg0 adsorption over the CaS surface. Overall, CaS tends to adsorb mercury in the reduction reactor and release mercury when CaS is re-oxidized to CaSO4 in the oxidation reactor. This is detrimental to mercury removal in the CLC of coal. This study sheds light on the migration and transformation of mercury in the CLC of coal with CaSO4 as the oxygen carrier.

3.
Artículo en Inglés | MEDLINE | ID: mdl-37482681

RESUMEN

A bubbling reactor is an important type of gas scrubber to reduce SO2 emissions in maritime shipping. Both experiments and simulations were conducted to study the relationship between the periodic gas bubbling process and SO2 concentration at the outlet of the reactor, and the entrainment of liquid droplets on SO2 absorption. The accuracy of the model was verified by comparing the bubble size, the depth of bubbles injected into the water, and the SO2 concentration obtained in both experiments and simulations. The gas bubbling process is accompanied by bubble formation, rise, and collapse. The gas bubbling period is affected by the disturbance of the liquid level. The period of the SO2 concentration at the outlet of the gas bubbling reactor is smaller than that at the gas jar outlet which acts as the gas buffering region. The amounts of water carried out of the bubbling reactor by the gas bubbling process increase with the gas flow rates. The droplets and liquid film in the gas jar and the connecting tube play an important role in the absorption of SO2. This study encourages more research to reduce the fluctuation of SO2 concentration and consider droplet entrainment in the design of bubbling reactors.


Asunto(s)
Agua
4.
Anat Rec (Hoboken) ; 306(10): 2636-2645, 2023 10.
Artículo en Inglés | MEDLINE | ID: mdl-36922637

RESUMEN

To investigate the impacts of ferulic acid (FA) on jumonji C domain-containing protein 6 (JMJD6) and synaptophysin in the tissues of the hippocampus in neonatal and juvenile rats with intrauterine hypoxia-induced cognitive impairment. The Sprague-Dawley pregnant rats were randomly divided into three groups: control, hypoxia, and hypoxia + FA. On day 14 of pregnancy, the intrauterine hypoxia model was created by placing pregnant rats in the hypoxic and low-pressure experimental chamber for 2 hr a day for 3 days. In the hypoxia + FA group, pregnant rats were injected intraperitoneally with 4% FA, once a day for 7 days. The hypoxia group was treated with equal amounts of saline. After delivery, JMJD6 and synaptophysin mRNA and proteins in the hippocampus regions were detected by in situ hybridization and western blotting. The Morris water maze was used to evaluate cognitive function. The neonatal and juvenile rats in the hypoxia group had significantly increased expression of JMJD6 and decreased expression of synaptophysin protein and synaptophysin I mRNA in the hippocampus than those in the control group. Meanwhile, hypoxia also clearly prolonged the escape latency and shortened the stay time in the target quadrant. FA decreased the expression of JMJD6 and increased the expression of synaptophysin and improved cognitive function compared with those in the hypoxia group. FA probably ameliorated the cognitive impairment by regulating JMJD6 and synaptophysin in the hippocampus of neonatal and juvenile rats who had intrauterine hypoxia during pregnancy.


Asunto(s)
Disfunción Cognitiva , Hipoxia , Embarazo , Femenino , Ratas , Animales , Ratas Sprague-Dawley , Sinaptofisina/genética , Sinaptofisina/metabolismo , Hipoxia/metabolismo , Hipocampo/metabolismo , Disfunción Cognitiva/tratamiento farmacológico , Disfunción Cognitiva/etiología , Disfunción Cognitiva/metabolismo , Aprendizaje por Laberinto/fisiología
5.
ACS Omega ; 7(24): 20959-20967, 2022 Jun 21.
Artículo en Inglés | MEDLINE | ID: mdl-35755379

RESUMEN

Mercury emission is an important issue during chemical looping combustion (CLC) of coal. The aim of this work is to explore the effects of different flue gas components (e.g., HCl, NO, SO2, and CO2) on mercury transformation in the flue gas cooling process. A two-stage simulation method is used to reveal the reaction mechanism of these gases affecting elemental mercury (Hg0) oxidation. Furthermore, using this method, Hg0 oxidation by eight oxygen carriers (Co3O4, CaSO4, CeO2, Fe2O3, Al2O3, Mn2O3, SiO2, and CuO) commonly used in CLC are investigated and their Hg0 oxidation efficiencies were compared with the existing experimental results. The results show that HCl, NO, and CO2 promote Hg0 oxidation during flue gas cooling, while SO2 inhibits Hg0 oxidation. The stronger the oxygen release capacity of oxygen carriers, the higher the oxidation efficiency of Hg0 becomes. The order of Hg0 removal efficiency from high to low is Co3O4, CuO, Mn2O3, CaSO4, Fe2O3, CeO2, Al2O3, and SiO2, and this sequence is in good agreement with the existing experimental results. Different flue gas components directly or indirectly affect the O2 content, thus affecting the content of gaseous oxidized mercury (Hg2+). Different oxygen carriers have different oxygen release capacities and different Hg0 oxidation efficiencies. Therefore, O2 is the core species affecting the mercury transformation in CLC.

6.
Environ Sci Pollut Res Int ; 28(34): 46130-46146, 2021 Sep.
Artículo en Inglés | MEDLINE | ID: mdl-33410014

RESUMEN

Coal-based mercury pollution from power plants has received increasing attention. In a previous study, high iron and calcium coal ash (HICCA) was found as a promising oxygen carrier (OC) for chemical looping combustion (CLC). The purpose of this study was to investigate the catalytic effect of HICCA on Hg0 removal as well as the impacts of several gas impurities, such as HCl, SO2, and NO. Experiments on Hg0 removal efficiencies for different atmospheres were performed in the fixed-bed reactor at 850 °C. Based upon the characterization of BET, SEM, XRD, XPS, and EDS of reaction products, the reaction mechanisms of different gases with the HICCA samples were established. The mechanisms were further explained using the thermodynamic equilibrium calculations. The experimental results showed that the Hg0 removal efficiency using HICCA was 11.60%, while the corresponding value in the presence of 50 ppm HCl was 90.46%. Hg0 removal by HICCA involving HCl is mainly attributed to homogeneous reaction between Hg0 and HCl as well as the formation of reactive species (Cl, Cl2, Cl2O, O, S, and SCl2) through the reactions of HCl with Fe2O3 and CaSO4 in HICCA. The formation of C-Cl bond is not the main pathway for the promotional effect of HCl on Hg0 removal. SO2 played a negative role in Hg0 removal by HICCA. The inhibition of SO2 may be attributed to its effect on the reduction of Fe2O3 and its bonding with C-O, COOH, and C(O)-O-C. NO enhanced Hg0 removal by HICCA primarily through the homogeneous reactions of Hg0 with N2O and O. In addition, NO also interacted with HICCA and promoted the heterogeneous oxidation of Hg0 by producing more C-O, C=O, and COOH/C(O)-O-C on HICCA surface. This study proved the effectiveness of HICCA on Hg0 removal in iG-CLC and revealed the mechanisms of the interaction between HCl/SO2/NO and MxOy/CaSO4 as well as carbon-oxygen groups.


Asunto(s)
Contaminantes Atmosféricos , Mercurio , Calcio , Carbón Mineral , Ceniza del Carbón , Gases , Hierro , Oxidación-Reducción , Centrales Eléctricas
7.
Data Brief ; 20: 535-543, 2018 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-30197910

RESUMEN

The dataset on equations and procedures for the estimation of detailed capital and annual costs for direct contact condenser are presented. Full dataset on four design cases relevant to the comparisons on the costs of air and oxy-fuel direct contact condenser is given. The data are presented in this format to allow the comparison with those from other researchers in this field. The data presented are related to the article entitled "A comparative study on the design of direct contact condenser for air and oxy-fuel combustion flue gas based on Callide Oxy-fuel Project" (Liu et al., 2018) [1].

8.
Bioresour Technol ; 100(24): 6505-13, 2009 Dec.
Artículo en Inglés | MEDLINE | ID: mdl-19664917

RESUMEN

In this paper, the effects of fluidization velocity, bed temperature and fuel feeding rate on the defluidization time and agglomerate fraction in the fluidized bed combustion of rice straw were studied. The fuel ash, necks in agglomerates and coating layers of bed particles were studied by means of the scanning electron microscope, coupled with energy-dispersive spectroscopy (SEM/EDS). Results showed that the stickiness of bed particles induced by coating layers is the direct reason for bed defluidization. The alkali metals such as K and Na mainly exist in the outer layer of rice straw particles. During combustion the high temperature can cause the alkali species melting and coating the surfaces of ash particles. Consequently, ash particles become sticky and tend to adhere to the surfaces of bed particles. The large-sized ash particles may act as the necks in the formation of agglomerates. The small-sized ash particles may contribute to the formation of coating layers.


Asunto(s)
Biotecnología/métodos , Oryza/química , Material Particulado/química , Álcalis/química , Elementos Químicos , Microscopía Electrónica de Rastreo , Oryza/ultraestructura , Análisis Espectral , Propiedades de Superficie , Factores de Tiempo
9.
Chemosphere ; 76(9): 1199-205, 2009 Aug.
Artículo en Inglés | MEDLINE | ID: mdl-19577276

RESUMEN

The influence of multicomponent additives on NO reduction by selective non-catalytic reduction process has been investigated experimentally in an electricity-heated tube reactor. The multicomponent additives are composed of two species of CO, CH(4) and H(2), and the molar ratio of their two components varies from 1/3 to 3/1. The results show that all the investigated additives could decrease the optimal temperature for NO reduction effectively, but the contributions of their components are different. The performance of multicomponent additive composed of CO and CH(4) depends mainly on CH(4) component. The function of CO component is shifting the temperature window for NO reduction to lower temperature slightly and narrowing the temperature window a little. The temperature window with multicomponent additive composed of H(2) and CH(4) is distinct from that with its each component, so both H(2) and CH(4) component make important contributions. While the fraction of CO is no more than that of H(2) in multicomponent additives composed of them, the performance of multicomponent additives is dominated by H(2) component; while the fraction of CO becomes larger, the influence of CO component becomes notable. Qualitatively the modeling results using a detailed chemical kinetic mechanism exhibit the same characteristics of the temperature window shift as observed experimentally. By reaction mechanism analysis, the distinct influences of CO, CH(4) or H(2) component on the property of multicomponent additive are mainly caused by the different production rates of (*)OH radical in their own oxidation process.


Asunto(s)
Contaminantes Atmosféricos/química , Gases/química , Óxido Nítrico/química , Algoritmos , Monóxido de Carbono/química , Cinética , Metano/química , Modelos Químicos , Oxidación-Reducción , Temperatura
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