RESUMEN

Biocompatible batteries can power implantable electronic devices and have broad applications in medicine. However, the controlled degradation of implantable batteries, the impact of battery catabolites on surrounding tissues, and wireless charging designs are often overlooked. Here, we designed an implantable zinc ion battery (ZIB) using a gelatin/polycaprolactone-based composite gel electrolyte. The prepared ZIBs deliver a high specific capacity of 244.0 mA h g-1 (0.5C) and long cycling stability of 300 cycles (4C). ZIBs were completely degraded within 8 weeks in rats and 30 days in a phosphate-buffered saline lipase solution, demonstrating good biocompatibility and degradability. ZIBs catabolites induced macrophage M2 polarization and exhibited anti-inflammatory properties, with mRNA levels of the M2 markers Arg-1 and CD206 up-regulated 15.8-fold and 13.4-fold, respectively, compared to the blank control group. Meanwhile, the expressions of two typical osteogenic markers, osteopontin and osteocalcin, were up-regulated by 3.6-fold and 5.6-fold, respectively, demonstrating that designed ZIBs promoted osteogenic differentiation of bone marrow mesenchymal stem cells. Additionally, a wireless energy transmission module was designed using 3D printing technology to realize real-time charging of the ZIB in rats. The designed ZIB is a promising power source for implantable medical electronic devices and also serves as a functional material to accelerate bone repair.

Asunto(s)

Suministros de Energía Eléctrica , Osteogénesis , Zinc , Osteogénesis/efectos de los fármacos , Animales , Ratas , Zinc/química , Células Madre Mesenquimatosas/metabolismo , Poliésteres/química , Ratas Sprague-Dawley , Masculino , Prótesis e Implantes , Gelatina/química , Iones/química , Ratones , Materiales Biocompatibles/química , Materiales Biocompatibles/farmacología , Diferenciación Celular/efectos de los fármacos

RESUMEN

Li metal batteries (LMBs) offer significant potential as high energy density alternatives; nevertheless, their performance is hindered by the slow desolvation process of electrolytes, particularly at low temperatures (LT), leading to low coulombic efficiency and limited cycle stability. Thus, it is essential to optimize the solvation structure thereby achieving a rapid desolvation process in LMBs at LT. Herein, we introduce branch chain-rich diisopropyl ether (DIPE) into a 2.5 M Li bis(fluorosulfonyl)imide dipropyl ether (DPE) electrolyte as a co-solvent for high-performance LMBs at - 20 °C. The incorporation of DIPE not only enhances the disorder within the electrolyte, but also induces a steric hindrance effect form DIPE's branch chain, excluding other solvent molecules from Li+ solvation sheath. Both of these factors contribute to the weak interactions between Li+ and solvent molecules, effectively reducing the desolvation energy of the electrolyte. Consequently, Li (50 µm)||LFP (mass loading ~ 10 mg cm-2) cells in DPE/DIPE based electrolyte demonstrate stable performance over 650 cycles at - 20 °C, delivering 87.2 mAh g-1, and over 255 cycles at 25 °C with 124.8 mAh g-1. DIPE broadens the electrolyte design from molecular structure considerations, offering a promising avenue for highly stable LMBs at LT.

RESUMEN

Rechargeable aqueous zinc-ion batteries (ZIBs) are promising portable and large-scale grid energy storage devices, as they are safe and economical. However, developing suitable ZIB cathode materials with excellent cycling performance characteristics remains a challenging task. Here, ammonium heptavanadate (NH4)2V7O16·3.2H2O (NHVO) nanosquares with mixed-valence V5+/V4+ as a cathode are developed for high-performance ZIBs. The layered NHVO shows a capacity of 362 mA h g-1 at 0.05 A g-1, with a high energy density of 263.5 W h kg-1. It exhibits an initial specific capacity of 250.7 mA h g-1 at a current density of 4 A g-1 and retains 255 mA h g-1 capacity after 1000 charge/discharge cycles. The V7O16-based cathode was demonstrated with a phase transition to the V2O5-based cathode upon initial cycling. Moreover, the in situ generated V2O5-based cathodes show excellent electrochemical properties, which provide a different perspective on the electrochemical reaction of cathode materials for aqueous ZIBs.

RESUMEN

Extreme multistability with coexisting infinite orbits has been reported in many continuous memristor-based dynamical circuits and systems, but rarely in discrete dynamical systems. This paper reports the finding of initial values-related coexisting infinite orbits in an area-preserving Lozi map under specific parameter settings. We use the bifurcation diagram and phase orbit diagram to disclose the coexisting infinite orbits that include period, quasi-period and chaos with different types and topologies, and we employ the spectral entropy and sample entropy to depict the initial values-related complexity. Finally, a microprocessor-based hardware platform is developed to acquire four sets of four-channel voltage sequences by switching the initial values. The results show that the area-preserving Lozi map displays coexisting infinite orbits with complicated complexity distributions, which heavily rely on its initial values.