RESUMEN
The quantification of macroplastic fluxes transferred by rivers toward the pelagic environment requires a better understanding of macrodebris transfer processes in estuarine environments. Following the strategy adopted in the Seine estuary, this study aims to characterize macroplastic trajectories in the Loire estuary. Between January 2020 and July 2021, 35 trajectories were monitored using plastic bottles equipped with GPS-trackers. With total travelled distances between 100 m and 103.6 km, trajectories show great spatiotemporal variability. The various forcing factors (macroplastic buoyancy, estuaries tidal and hydrometeorological conditions, geomorphology and vegetation) lead to chaotic trajectories, preventing accurate predictions in macroplastic transfer and storage/remobilization dynamics. In the Loire estuary like in the Seine one, no tracked bottle reached the Atlantic Ocean. It confirms that macrotidal estuaries under temperate climates constitute accumulation zones and slow pathways for macroplastics, but raises question on the real fluxes transferred from continental areas to oceans.
Asunto(s)
Estuarios , Ríos , Océano Atlántico , Monitoreo del Ambiente , Océanos y MaresRESUMEN
Many researches mention the need to identify the land-based sources of riverine macrolitter but few field data on litter amount, composition and sources are available in the scientific literature. Describing macrolitter hotspot dynamics would actually allow a better estimation of fluxes in the receiving environments and a better identification of the more appropriate mitigation strategies. This study provides new insights in roadway macrolitter production rates, typologies and input sources (i.e. deliberate or accidental). The macrolitter from an 800 m portion of a highly frequented roadway (around 90,000 vehicles per day) was collected during almost one year. Typologies were defined using the OSPAR/TGML classification. Results show high annual loads of macrolitter (42.8 kg/yr/ha), suggesting significant contributions of the road runoff to the litter fluxes in urban stormwater. Over the course of a year, 88.5 kg of debris were collected, including 53.2 kg (60%) of plastic debris. In total, 36,439 items were characterized, of which 84% were plastics. The macrodebris collected present a low diversity of components with Top 10 items accounting for 92% by count and a majority of small and lightweight items like plastic fragments (31%) or cigarette butts (18%). Input sources were estimated for 43% of the mass collected in which 37.2% were deliberately littered and 62.8% were accidental leaks, illustrating a major contribution of uncovered trucks and unsecured loads. The accumulation rates show a linear correlation with the road traffic. Such data are of prime interest since they enable to determine the potential contribution of road traffic to plastic fluxes to the environment.
Asunto(s)
Monitoreo del Ambiente , Residuos , Monitoreo del Ambiente/métodos , Plásticos , Residuos/análisisRESUMEN
Pharmaceutical products (PPs) are consumed worldwide and are continuously released into hydrological environments, but are not efficiently removed by sewage treatment plants. Their occurrence within the dissolved phase has been extensively studied, but only a few articles concern solid matrices. The mechanisms and extent of sorption depend on the properties of both the molecules (degradability, charge, hydrophobicity) and the matrices (clay content, organic matter content), making the spatio-temporal distribution of PPs in natural environments complex and poorly elucidated. To improve our understanding of PP distribution at a catchment scale, this study investigated different groups of molecules with varying solubility and charges, in water, suspended particulate matter, bed-load and pond sediments. The Egoutier stream, which collects the sewage effluents from two health institutions sewage effluents, is a good candidate for this investigation. Results indicate that PP occurrences in the different particulate compartments were mainly regulated by their wastewater occurrences and charges. Particulate phases all along the Egoutier stream were characterized by a limited clay content (i.e. less than 1%) and significant organic carbon content (i.e. between 0.3% and 18.0%) favouring non-specific adsorption. Therefore, neutral PPs, exhibiting higher discharge rates, persistence and hydrophobicities in comparison with cationic and anionic molecules, were the most abundant PPs in the particulate phases of this catchment. In bed-load sediments, global PP spatial distributions reflected discharge sites and sedimentary accumulation zones, mostly that of organic matter. Spatial distributions of the more hydrophobic and persistent PP in the particulate phases thus followed the stream sedimentary dynamic.