RESUMEN
For practical application of lithium-sulfur batteries (LSBs), designing devices with an overall optimal structure instead of modifying electrode materials is significant. Herein, we report a chip-inspired design of a vertically integrated structure as an LSB cathode by implanting Mo2C nanoparticles and nanosulfur into the reduced graphene oxide (rGO) matrix. This configuration enabled the synthesis of isolated sulfur nanoreactors (S-NRs) integrated in a tandem array on the rGO, generating chip-like integrated LSBs. The spatial confinement/protection and concentration gradient of the S-NRs effectively avoided the dissolution, diffusion, and loss of polysulfides, thereby enhancing the sulfur utilization and redox reaction kinetics. Additionally, the adaptive storage energy can be improved by utilizing the tandem, isolation, and synergistic multiplicative effect among the nanoreactor units. As a result, the integrated LSB cathode obtained excellent electrochemical performances with an initial capacity of 1392 mAh g-1 at 0.1C, a low capacity decay rate of 0.017% per cycle during 1500 cycles of operation at 0.5C, and a superior rate performance. This work provides a rational design idea and method of further advancing the precise preparation of high-performance energy storage devices.
RESUMEN
Apart from electrode material modification, architecture design and optimization are important approaches for improving lithium-sulfur battery performance. Herein, an integrated structure with tandem connection is constructed by confining nanosulfur (NS) in conductive poly(3,4-ethylenedioxythiophene) (PEDOT) reaction chambers, forming an interface of discrete independent nanoreactor units bonded onto carbon nanotubes (noted as CNT/NS@PEDOT). The unique spatial confinement and concentration gradients of sulfur@PEDOT nanoreactors (SP-NRs) can promote reaction kinetics while facilitating rapid polysulfide transformation and minimizing dissolution and diffusion losses. Meanwhile, overall ultrahigh energy input and output are achieved through tandem connection with carbon nanotubes, isolation with PEDOT coating, and synergistic multiplicative effects among SP-NRs. As a result, it delivers a high initial discharge capacity of 1246â mAh g-1 at 0.1 C and 918â mAh g-1 at 1 C, the low capacity decay rate per lap of 0.011 % is achieved at a current density of 1 C after 1000 cycles. This research emphasizes the innovative structural design to provide a fresh trajectory for the further advancement of high-performance energy storage devices.
RESUMEN
This study investigated the reflected spectral deformation mechanism of fiber Bragg grating (FBG) sensors with crack propagation. This analysis was performed based on the simulated FBG response by applying modified-transfer matrix modeling (TMM) with the strain states, which were extracted by the finite element method (FEM) analysis. Experimental data were obtained from FBG sensors bonded in an aluminum alloy structure and subjected to multiple crack lengths, and the strain values were obtained by digital image correlation (DIC) technology. Based on the simulations and the experimental full spectral response, we compared the performance of two damage features: The full width at half maximum (FWHM) and the spectral difference. In addition, results showed that the two features were insensitive to experimental noise and were highly sensitive to the complex strain field caused by crack propagation. Moreover, the damage features changes in the crack propagation process also provided a way for crack position measurement. Ultimately, the 10 mm grating lengths sensors showed better performance to the crack detection with longer sensitivity distance. According to the research in this paper, the crack position was quantitatively determined by evaluating different damage features of the reflected spectrum.