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1.
Molecules ; 29(14)2024 Jul 16.
Artículo en Inglés | MEDLINE | ID: mdl-39064914

RESUMEN

Wood characterized by desired mechanical properties and wood joining material is essential for creating wooden structures. The polymer adhesives are suitable for such applications due to the possibility of energy dissipation from stresses generated by wooden structures and the elimination of thermal bridging, which are common problems in metal joining materials. This research focuses on the thermophysical properties of the laboratory-prepared flexible and rigid polyurethanes to select an appropriate polymer adhesive. Our results showed that the highest thermal stability was in the case of the new PSTF-S adhesive, which reached 230 °C, but the lowest mass loss in the air environment was around 54% for the PS material. The mean thermal expansion coefficient for F&R PU adhesives was 124-164∙10-6 K-1. The thermal diffusivity of examined adhesives varied between 0.100 and 0.180 mm2s-1. The thermal conductivity, depending on the type of polyurethane, was in the 0.13-0.29 W∙m-1∙K-1 range. The relative decrease in thermal diffusivity after heating the adhesives to 150 °C was from 2% for materials with the lowest diffusivity to 23% for the PU with the highest value of heat transfer. It was found that such data can be used to simulate wooden construction joints in future research.

2.
Polymers (Basel) ; 16(3)2024 Feb 05.
Artículo en Inglés | MEDLINE | ID: mdl-38337333

RESUMEN

This study addresses the challenges of modeling flexible connections in composite structures employing a polymeric adhesive layer. These types of connections provide a more uniform stress distribution compared to conventional rigid connectors. However, they lack standardized design rules and still require much research to sufficiently comprehend their properties. The novelty of this research lies in proposing an analytical solution to address these issues. Its aim is to investigate the influence of the stiffness of the polymer adhesive on the girder's deflection and on the maximum stresses in both the adhesive and concrete. The analyzed composite structure consists of a reinforced concrete (RC) slab and an RC beam connected with a layer of flexible polyurethane (FPU) adhesive. Analytical and numerical approaches for the description of the mechanical response of a composite bridge girder are presented. Another objective is to validate the analytical design formulas using 3D nonlinear numerical analysis, both in the case of uncracked and cracked concrete. Seven types of FPUs are tested in the uniaxial tension test, each examined at five strain rates. The obtained data is used to predict the mechanical response of the considered girder using finite element analysis (FEA) as well as with a simplified one-dimensional composite beam theory. Fair agreement is found between the FEA results and theoretical predictions. A comparison of the results obtained for these two models is performed, and the similarities and discrepancies are highlighted and discussed.

3.
Materials (Basel) ; 14(12)2021 Jun 11.
Artículo en Inglés | MEDLINE | ID: mdl-34208116

RESUMEN

It is a common situation that seismic excitations may lead to collisions between adjacent civil engineering structures. This phenomenon, called earthquake-induced structural pounding, may result in serious damage or even the total collapse of the colliding structures. Filling the gap between two buildings erected close to one another by using visco-elastic materials can be considered to be one of the most effective methods to avoid seismic pounding. In this paper, a new polymer-metal composite material made of polyurethane and closed-cell aluminum foam is proposed as a pounding energy absorber for protection against earthquake hazards. The composite was created in two versions, with and without an adhesive interface. A series of experiments which reflect the conditions of seismic collision were performed: quasi-static compression, dynamic uniaxial compression and low-cycle dynamic compression with 10 loops of unloading at 10% strain. The composite material's behavior was observed and compared with respect to uniform material specimens: polymer and metal foam. The experimental results showed that the maximum energy absorption efficiency in the case of the new material with the bonding layer was improved by 34% and 49% in quasi-static and dynamic conditions, respectively, in comparison to a sole polymer bumper. Furthermore, the newly proposed composites dissipated from 35% to 44% of the energy absorbed in the cyclic procedure, whereas the polymer specimen dissipated 25%. The capacity of the maintenance of the dissipative properties throughout the complete low-cycle loading was also satisfactory: it achieved an additional 100% to 300% of the energy dissipated in the first loading-unloading loop.

4.
Polymers (Basel) ; 13(10)2021 May 18.
Artículo en Inglés | MEDLINE | ID: mdl-34070200

RESUMEN

Practical aspects of modelling of flexible adhesives with the energy conjugate measures of stress and strain of the Darijani-Naghdabadi (D-N) family are discussed. A possibility of description of materials exhibiting non-linear physical characteristics with the use of non-linear geometric relationships and linear elastic constitutive law is considered. Nominal stress vs. stretch relations are specified in cases of simple tension and simple shear with the use of the Kirchhoff-de Saint-Venant elastic potential and D-N energy conjugate stress and strain measures. Obtained theoretical estimates were compared with experimental results of simple tension and simple shear tests performed on Sika PM polyurethane (Cracow, Sika Poland). The deformation rate was fixed in order to minimize the influence of viscosity. Values of parameters α,ß in the definition of the D-N strain tensor were optimized in order to provide good agreement between model predictions and experimental results. Observed discrepancies indicate that the proposed approach is not appropriate for constitutive modelling of the PM polymer. The presented approach is proposed to be used as a simple design model providing practical formulas describing the behavior of materials of non-linear characteristics in chosen mechanical states. Admissible values of exponents α,ß are discussed regarding its bijectivity in a limited range of variation of principal stretches.

5.
Polymers (Basel) ; 12(12)2020 Nov 30.
Artículo en Inglés | MEDLINE | ID: mdl-33266106

RESUMEN

The behaviour of reinforced concrete frames with masonry wall infills is influenced a lot by the stiffness and strength difference between the frame and the infill, causing early detrimental damage to the infill or to the critical concrete columns. The paper reports the results from shake table seismic tests on a full-scale reinforced concrete (RC) frame building with modified hollow clay block (orthoblock brick) infill walls, within INMASPOL SERA Horizon 2020 project. The building received innovative resilient protection using Polyurethane Flexible Joints (PUFJs) made of polyurethane resin (PU), applied at the frame-infill interface in different schemes. Further, PUs were used for bonding of glass fibre grids to the weak masonry substrate to form Fibre Reinforced Polyurethanes (FRPUs) as an emergency repair intervention. The test results showed enhancement in the in-plane and out-of-plane infill performance under seismic excitations. The results confirmed remarkable delay of significant infill damages at very high RC frame inter-story drifts as a consequence of the use of PUFJs. Further, the PUFJ protection enabled the resilient repair of the infill even after very high inter-story drift of the structure up to 3.7%. The applied glass FRPU system efficiently protected the damaged infills against collapse under out-of-plane excitation while they restored large part of their in-plane stiffness.

6.
Polymers (Basel) ; 12(12)2020 Nov 28.
Artículo en Inglés | MEDLINE | ID: mdl-33260747

RESUMEN

Polyurethane flexible joints (PUFJ) and fiber reinforced polyurethanes (FRPU) have shown great potential in the repair and protection of masonry and concrete structures. However, some questions have been raised about the durability of such solutions. The accelerated weathering and thermal stability tests carried out so far have shown the mechanical stability of PS-polyurethane in temperatures up to 100 °C and some UV-induced surface degradation. The paper reports the results from tensile tests of PS-polyurethane, used in the technologies mentioned above after being subjected to aging in different corrosive factors, a thermal analysis of unaged polymer which consists of DSC-TGA and dilatometry studies, and SEM-microscopy observation of the specimens with the indication of the elemental composition (EDS). PS-polyurethane showed low sensitivity to weathering with exposition to UV-radiation, some reactiveness to aqueous environments of a different chemical nature, and resistivity to soil and freezing in both air and water. SEM observations indicated changes in the composition of mineral fillers as the main effect of immersion in different water solutions. DSC-TGA studies showed the thermal stability of PS-polyurethane up to 200 °C and degradation proceeding in five stages. Dilatometry studies revealed that the first-degree thermal degradation over 200 °C causes a serious loss of mechanical properties.

7.
Materials (Basel) ; 13(24)2020 Dec 16.
Artículo en Inglés | MEDLINE | ID: mdl-33339163

RESUMEN

Polymer Flexible Joint (PFJ) is a method for repairs of concrete elements, which enables carrying loads and large deformations effectively. This article presents the possibility of applying PFJ on beams subjected to bending and describes the influence of such joints on concrete elements. An experimental investigation was conducted to determine the behavior of concrete in a four-point bending test. The research program included flexural tests of plain concrete elements with a notch, as well as tests of elements which were repaired with PFJ after failure. Based on the experimental results, the numerical characteristics of analyzed polymer and concrete were calibrated. A nonlinear numerical model is developed, which describes the behavior of concrete elements and polymer in the experiments. The model is used to numerically analyze deformations and stresses under increasing load. The influence of flexible joint on concrete elements is described and behavior of elements repaired with PFJ is compared to original elements. Particular attention was paid to the stress redistribution in concrete. The application of flexible joint positively influences load capacity of the connected concrete elements. Furthermore, because of stress redistribution, connected elements can bear larger deformations than original ones. PFJ can therefore be considered an efficient repair method for connecting concrete elements.

8.
Polymers (Basel) ; 12(10)2020 Oct 15.
Artículo en Inglés | MEDLINE | ID: mdl-33076343

RESUMEN

The aim of the present study is to consider the idea of using polyurethane flexible adhesive in to reduce the vibrations in structures exposed to dynamic loads and evaluate their damping properties in relation to large deformations. Firstly, two aluminium cantilever beams, simulating structural elements (without and with polyurethane layer in the form of tape), were analysed, in order to check the damping of the unconstrained polymer layer. In the second stage of the study, a composite beam consisting of two aluminium flat beams bonded with polymer adhesive was considered, so as to check the damping of the constrained polymer layer. Dynamic parameters, such as modes of free vibrations, corresponding natural frequencies and damping ratios, were determined and compared. The third stage of the investigation was aimed at solving the problem of the additional mass of the applied polymer layer, which influences the frequencies and damping of the tested structure. A special separating procedure is proposed that makes it possible to calculate the corrected real values of the polymer layer's damping. The results of the study clearly show that the response of the composite aluminium beam with and without polymer adhesive layer is mainly influenced by the layers' thickness and the large strain deformation, in terms of its damping characteristics. The use of polymer adhesive layers in constrained and unconstrained conditions leads to a significant reduction in the vibrations of tested beams, while preserving their stiffness at nearly the same level. The applied analysis procedure made it possible for us to separate the damping properties of the analysed polymer layers and evaluate them independently with respect to the influence of integrated structural elements on damping.

9.
Sci Technol Adv Mater ; 21(1): 661-682, 2020 Sep 22.
Artículo en Inglés | MEDLINE | ID: mdl-33061839

RESUMEN

Development and commercialization of self-healing concrete is hampered due to a lack of standardized test methods. Six inter-laboratory testing programs are being executed by the EU COST action SARCOS, each focusing on test methods for a specific self-healing technique. This paper reports on the comparison of tests for mortar and concrete specimens with polyurethane encapsulated in glass macrocapsules. First, the pre-cracking method was analysed: mortar specimens were cracked in a three-point bending test followed by an active crack width control technique to restrain the crack width up to a predefined value, while the concrete specimens were cracked in a three-point bending setup with a displacement-controlled loading system. Microscopic measurements showed that with the application of the active control technique almost all crack widths were within a narrow predefined range. Conversely, for the concrete specimens the variation on the crack width was higher. After pre-cracking, the self-healing effect was characterized via durability tests: the mortar specimens were tested in a water permeability test and the spread of the healing agent on the crack surfaces was determined, while the concrete specimens were subjected to two capillary water absorption tests, executed with a different type of waterproofing applied on the zone around the crack. The quality of the waterproofing was found to be important, as different results were obtained in each absorption test. For the permeability test, 4 out of 6 labs obtained a comparable flow rate for the reference specimens, yet all 6 labs obtained comparable sealing efficiencies, highlighting the potential for further standardization.

10.
Polymers (Basel) ; 10(4)2018 Mar 22.
Artículo en Inglés | MEDLINE | ID: mdl-30966391

RESUMEN

This paper investigates composite-to-brick strengthening systems with flexible adhesive made of polyurethane (Carbon Fibre Reinforced Polyurethane (CFRPU) and Steel Reinforced Polyurethane (SRPU)) and epoxy resin (Carbon Fibre Reinforced Polymer (CFRP) and Steel Reinforced Polymer (SRP). The specimens were tested in a single lap shear test (SLST). LVDT displacement transducers (LVDT ⁻ Linear Variable Differential Transformer) and digital image correlation method (DIC) based measurement systems were used to measure displacements and strains. The obtained results were applied in a numerical analysis of the 3D model of the SLST specimen, with flexible adhesives modeled as a hyper-elastic model. The DIC and LVDT based systems demonstrated a good correlation. Experimental and numerical analysis confirmed that composite-to-brick strengthening systems with flexible adhesives are more effective on brittle substrates than stiff ones, as they are able to reduce stress concentrations and more evenly distribute stress along the entire bonded length, thus having a higher load carrying capacity.

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