RESUMEN
Polymers reinforced with nanofillers, especially graphene in recent times, have continued to attract attention to realize novel materials that are cheap and also have better properties. At a different level, encapsulating liquid crystals (LCs) in polymer networks not only adds mechanical strength, but could also result in device-based refractive index mismatch. Here, we describe a novel strategy combining the best of both these concepts to create graphene-incorporated polymer-stabilized LC (PSLC) devices. The presence of graphene associated with the virtual surface of the polymer network besides introducing distinct morphological changes to the polymer architecture as seen by electron microscopy brings out several advantages for the PSLC characteristics, which include 7-fold lowered critical voltage, its temperature invariance, and enhanced contrast ratio between field-off scattering/field-on transparent states. The results bring to fore the importance of working at very-dilute-concentration limits of the filler nanoparticles in augmenting the desired properties. These observations open up a new vista for polymer-graphene composites in the area of device engineering, including substrate-free smart windows.
RESUMEN
Bulk phase binary mixture of two rotator phase forming alkanes, n-tricosane (C23H48) and n-octacosane (C28H58), has been previously studied. C23H48 exists in the RII and RI phases, whereas C28H58 exists in the RIII and RIV phases. Over a certain range of composition, this binary mixture was found to exist in RII, RI and an intervening mesophase was reported to be the hexatic phase, wherein the long-range two-dimensional in-plane hexagonal lattice order of the RII is lost and what remains is molecules present in hexagonal geometry without long-range positional correlation between individual hexagons. Upon confinement in cylindrical anodized alumina pores 200 nm wide, on the one hand, the temperature range of the hexatic phase was found to extend, and on the other hand, it underwent increased molecular ordering compared to the hexatic phase in bulk, exhibiting two counter-reacting behaviors in confinement. We provide here a temperature-dependent X-ray diffraction study and a theoretical approach combining the Landau and Flory-Huggins theories to, first, understand the underlying mechanism leading to emergence of the hexatic phase and then to explain the effect of confinement on it in the light of finite size and interfacial interaction between the alkanes and alumina pores.
RESUMEN
Morphology influences the functionality of covalent organic networks and determines potential applications. Here, we report for the first time the use of Zincke reaction to fabricate, under either solvothermal or microwave conditions, a viologen-linked covalent organic network in the form of hollow particles or nanosheets. The synthesized materials are stable in acidic, neutral, and basic aqueous solutions. Under basic conditions, the neutral network assumes radical cationic character without decomposing or changing structure. Solvent polarity and heating method determine product morphology. Depending upon solvent polarity, the resulting polymeric network forms either uniform self-templated hollow spheres (HS) or hollow tubes (HT). The spheres develop via an inside-out Ostwald ripening mechanism. Interestingly, microwave conditions and certain solvent polarities result in the formation of a robust covalent organic gel framework (COGF) that is organized in nanosheets stacked several layers thick. In the gel phase, the nanosheets are crystalline and form honeycomb lattices. The use of the Zincke reaction has previously been limited to the synthesis of small viologen molecules and conjugated viologen oligomers. Its application here expands the repertoire of tools for the fabrication of covalent organic networks (which are usually prepared by dynamic covalent chemistry) and for the synthesis of viologen-based materials. All three materials-HT, HS, and COGF-serve as efficient adsorbents of iodine due to the presence of the cationic viologen linker and, in the cases of HT and HS, permanent porosity.