RESUMEN
The utilization of banana fiber derived from micro-cellulose (MC) was exploited as a supporting material for advanced oxidation process (AOP) on the degradation of methylene blue and methyl violet dyes in the presence of H2O2-UV in aqueous medium for the first time using green chemistry protocols. Additionally, it was also effectively utilized for the adsorption of methylene blue dye using addition of H2O2 in the presence of sunlight. The MC powder was fabricated using an acid alkali process from the pseudo-stem of a banana tree. The as-fabricated MC powder was systematically characterized using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectrometer (EDX), and zero point charge (pHzpc). The AOP assisted degradation of dye molecules was monitored by using calorimetric techniques as a function of dye concentration and pH in a batch reactor. In a short period of time, the maximum degradation efficiency of 98 % of methylene blue was achieved using MC powder assisted H2O2 under UV irradiation at a minimum irradiation time of 120 min at pH 7.0 using dosage of 0.2 g/L. However, in the absence of UV light, the degradation efficiency of MC powder assisted H2O2 was only about 5-10 % without UV light irradiation. The dye removal was studied as a function of various operational parameters such as pH (3-11), catalyst dose (0.2-0.6 g/L), and initial dye concentration (100-400 mg/L). In the presence of H2O2-sunlight and 0.2 g/L of dosage at pH 7.0 at a minimum contact time of 120 min, MC fiber showed maximum adsorption capacities of 98% and 85% for 100 mg/L and 400 mg/L of methylene blue concentrations. According to the obtained data, the adsorption of methylene blue dye on MC follows the Freundlich isotherm model (R2 = 0.9886) and pseudo-first-order kinetic model (R2 = 0.9596) due to the higher regression coefficients. This process of dye degradation and adsorption process is a novel one and environmentally benign for an effective removal of hazardous dyes.
Asunto(s)
Musa , Contaminantes Químicos del Agua , Celulosa , Vapor , Adsorción , Colorantes/química , Azul de Metileno/química , Peróxido de Hidrógeno , Polvos , Catálisis , Cinética , Contaminantes Químicos del Agua/química , Concentración de Iones de Hidrógeno , Espectroscopía Infrarroja por Transformada de FourierRESUMEN
The present study demonstrates an unprecedented green process for the production of spherical-shaped Au and Ag nanoparticles synthesized and stabilized using a bacterium, Brevibacterium casei. Aqueous solutions of chloroaurate ions for Au and Ag(+) ions for silver were treated with B. casei biomass for the formation of Au nanoparticles (AuNP) and Ag nanoparticles (AgNP). The nanometallic dispersions were characterized by surface plasmon absorbance measuring at 420 and 540 nm for Ag and Au nanoparticles, respectively. Transmission electron microscopy showed the formation of nanoparticles in the range of 10-50 nm (silver), and 10-50 nm (gold). XRD analysis of the silver and gold nanoparticles confirmed the formation of metallic silver and gold. Further analysis carried out by Fourier Transform Infrared Spectroscopy (FTIR), provides evidence for the presence of proteins as possible biomolecules responsible for the reduction and capping agent which helps in increasing the stability of the synthesized silver and gold nanoparticles. The biological activities of the synthesized particles were confirmed based on their stable anti-coagulant effects. The use of bacterium for nanoparticles synthesis offers the benefits of ecofriendliness and amenability for large-scale production.