RESUMEN
Studying the distribution of carbon, nitrogen and phosphorus of sediments on a whole-watershed scale is important to the research and management of water resources in the Haihe River Basin (HRB). In this study, total organic carbon (TOC), total nitrogen (TN), and total phosphorus (TP) of 163 samples were investigated in the HRB. Based on these data, the pollution le-vels of sediments were assessed by using different quantitative indices. The results showed that the concentrations of TOC, TN, and TP in the HRB were heterogeneous at different locations. A decreasing trend of concentrations was found from downstream plains (e.g., the Beisihe River and the Heilonggang River) to mountain areas (e.g., the Yongdinghe River, the Beisanhe River, and the Luanhe River). In addition, the concentration of TOC in river sediments was higher than that of reservoir sediments. The statistical analyses showed that TN was significantly (P<0.01) correlated to TOC and TP, with a correlation coefficient of 0.704 and 0.250, respectively. The pollution level based on organic indices was classified as the clean level in the HRB. However, the areas with a relatively high pollution level were still found in some spots, such as the Beisihe River, and the Heilonggang River. Sediments of rivers and reservoirs were similar in the pollution intensity. The average C/N value of sediments in the HRB was 12.71, indicating that the TOC was derived from algae, phytoplankton flora and fauna, followed by higher plants. The C/N value of reservoir sediments was higher than that of river sediments, indicating that the contribution of terrigenous material inputs to TOC was larger in reservoirs than in rivers.
Asunto(s)
Carbono/análisis , Monitoreo del Ambiente , Sedimentos Geológicos/química , Nitrógeno/análisis , Fósforo/análisis , Contaminantes Químicos del Agua/análisis , China , RíosRESUMEN
Based on different land use types, altitudes, soil and vegetation types etc, 171 representative topsoils (0-10 cm) were collected within the Yanghe watershed, China for determining the total concentrations, spatial distribution and influencing factors of selenium (Se). The results showed that the total selenium concentrations in soils within the watershed ranged from 0.02 to 3.24 mg x kg(-1) dry weight (dw). The geometric mean of Se in soils within the watershed was 0.30 mg x kg(-1), which was higher than those in Beijing plain (0.20 mg x kg(-1)), Hebei plain (0.19 mg x kg(-1)) and China (0.29 mg x kg(-1)). Soils which lacked Se (0.13-0.18 mg x kg(-1)) were mainly distributed in Huaian, Xuanhua, and Huailai counties. Se concentrations in most areas within the watershed were sufficient (0.18-0.45 mg x kg(-1)). In addition, Wanquan, Xinghe, Tianzhen and Yanggao counties also had some selenium-rich areas. Concentrations of Se were different under different land use types. They were of the following order: forest land > industrial and mining land > grassland > agricultural land. Agricultural land had the lowest concentrations of Se, with a mean concentration of 0.28 mg x kg(-1). We also found that parent materials and soil types had no significant effects on soil Se concentrations within the Yanghe Watershed. The results indicated that Se concentrations were positively and significantly correlated with clay contents and altitudes, but negatively and significantly with pH values. Furthermore, TOC, Fe and Al concentrations were also important factors influencing the Se concentrations in soils within the Yanghe Watershed.