1.
Chem Commun (Camb)
; 49(75): 8356-8, 2013 Sep 28.
Artículo
en Inglés
| MEDLINE
| ID: mdl-23929258
RESUMEN
The first example of monooxygenation by a high-valent Mn(IV) complex with a peroxide is described. A key Mn(IV) acylperoxo intermediate, which uses m-chloroperoxybenzoic acid as the oxygen donor, is directly observed by electro-spray ionization mass spectrometry and resonance Raman spectroscopy.