RESUMEN
Temperature, thermal history, and dynamics of Earth rely critically on the knowledge of the melting temperature of iron at the pressure conditions of the inner core boundary (ICB) where the geotherm crosses the melting curve. The literature on this subject is overwhelming, and no consensus has been reached, with a very large disagreement of the order of 2,000 K for the ICB temperature. Here we report new data on the melting temperature of iron in a laser-heated diamond anvil cell to 103 GPa obtained by X-ray absorption spectroscopy, a technique rarely used at such conditions. The modifications of the onset of the absorption spectra are used as a reliable melting criterion regardless of the solid phase from which the solid to liquid transition takes place. Our results show a melting temperature of iron in agreement with most previous studies up to 100 GPa, namely of 3,090 K at 103 GPa.
RESUMEN
A new method for measuring melting temperatures in the laser-heated diamond cell is described. This method circumvents previous problems associated with the sample instability, thermal runaway, and chemical reactions. Samples were heated with a single, 20 milliseconds rectangular pulse from a fiber laser, monitoring their thermal response with a fast photomultiplier while measuring the steady state temperature with a CCD spectrometer. The samples were recovered and analyzed using scanning electron microscopy. Focused ion beam milling allowed to examine both the lateral and the vertical solid-liquid boundaries. Ambient pressure tests reproducibly yielded the known melting temperatures of rhenium and molybdenum. Melting of Re was measured to 50 GPa, a 5-fold extension of previous data. The refractory character of Re is drastically enhanced by pressure, in contrast to Mo.