RESUMEN
Arsenic is a major drinking water contaminant in many countries causing serious health hazards, and therefore, attempts are being made to remove it so that people have safe drinking water supplies. The effectiveness of arsenic removal from As(V) solutions using granular activated carbon (GAC) (zero point of charge (ZPC) pH 3.2) and iron incorporated GAC (GAC-Fe) (ZPC pH 8.0) was studied at 25⯱â¯1⯰C. The batch study confirmed that GAC-Fe had higher Langmuir adsorption capacity at pH 6 (1.43â¯mg As/g) than GAC (1.01â¯mg As/g). Adsorption data of GAC-Fe fitted the Freundlich model better than the Langmuir model, thus indicating the presence of heterogeneous adsorption sites. Weber and Morris plots of the kinetic adsorption data suggested intra-particle diffusion into meso and micro pores in GAC. The column adsorption study revealed that 2-4 times larger water volumes can be treated by GAC-Fe than GAC, reducing the arsenic concentration from 100⯵g/L to the WHO guideline of 10⯵g/L. The volume of water treated increased with a decrease in flow velocity and influent arsenic concentration. The study indicates the high potential of GAC-Fe to remove arsenic from contaminated drinking waters in practical column filters.
Asunto(s)
Arsénico , Contaminantes Químicos del Agua , Purificación del Agua , Adsorción , Carbón Orgánico , HierroRESUMEN
Elevated concentrations of heavy metals in water can be toxic to humans, animals, and aquatic organisms. A study was conducted on the removal of Cu, Pb, and Zn by a commonly used water treatment adsorbent, granular activated carbon (GAC), from three single, three binary (Cu-Pb, Cu-Zn, Pb-Zn), and one ternary (Cu-Pb-Zn) combination of metals. It also investigated seven mathematical models on their suitability to predict the metals adsorption capacities. Adsorption of Cu, Pb, and Zn increased with pH with an abrupt increase in adsorption at around pH 5.5, 4.5, and 6.0, respectively. At all pHs tested (2.5-7.0), the adsorption capacity followed the order Pb > Cu > Zn. The Langmuir and Sips models fitted better than the Freundlich model to the data in the single-metal system at pH 5. The Langmuir maximum adsorption capacities of Pb, Cu, and Zn (mmol/g) obtained from the model's fits were 0.142, 0.094, and 0.058, respectively. The adsorption capacities (mmol/g) for these metals at 0.01 mmol/L equilibrium liquid concentration were 0.130, 0.085, and 0.040, respectively. Ideal Adsorbed Solution (IAS)-Langmuir and IAS-Sips models fitted well to the binary and ternary metals adsorption data, whereas the Extended Langmuir and Extended Sips models' fits to the data were poor. The selectivity of adsorption followed the same order as the metals' capacities and affinities of adsorption in the single-metal systems.
Asunto(s)
Carbón Orgánico/química , Cobre/química , Plomo/química , Metales Pesados/química , Zinc/química , Adsorción , Agua , Purificación del AguaRESUMEN
Polycyclic aromatic hydrocarbons (PAHs) constitute a group of highly persistent, toxic and widespread environmental micropollutants that are increasingly found in water. A study was conducted in removing five PAHs, specifically naphthalene, acenaphthylene, acenaphthene, fluorene and phenanthrene, from water by adsorption onto granular activated carbon (GAC). The pseudo-first-order (PFO) model satisfactorily described the kinetics of adsorption of the PAHs. The Weber and Morris diffusion model's fit to the data showed that there were faster and slower rates of intra-particle diffusion probably into the mesopores and micropores of the GAC, respectively. These rates were negatively related to the molar volumes of the PAHs. Batch equilibrium adsorption data fitted well to the Langmuir, Freundlich and Dubinin-Radushkevich models, of which the Freundlich model exhibited the best fit. The adsorption affinities were related to the hydrophobicity of the PAHs as determined by the log Kow values. Free energies of adsorption calculated from the Dubinin-Radushkevich model and the satisfactory kinetic data fitting to the PFO model suggested physical adsorption of the PAHs. Adsorption of naphthalene, acenaphthylene and acenaphthene in fixed-bed columns containing a mixture of GAC (0.5 g) + sand (24.5 g) was satisfactorily simulated by the Thomas model.
Asunto(s)
Carbón Orgánico/química , Hidrocarburos Policíclicos Aromáticos/aislamiento & purificación , Contaminantes Químicos del Agua/aislamiento & purificación , Purificación del Agua/métodos , Agua/química , Adsorción , Difusión , Cinética , Modelos Químicos , Hidrocarburos Policíclicos Aromáticos/química , Contaminantes Químicos del Agua/químicaRESUMEN
Nitrate contamination of ground and surface waters causes environmental pollution and human health problems in many parts of the world. This study tests the nitrate removal efficiencies of two ion exchange resins (Dowex 21K XLT and iron-modified Dowex 21K XLT (Dowex-Fe)) and two chemically modified bio-adsorbents (amine-grafted corn cob (AG corn cob) and amine-grafted coconut copra (AG coconut copra)) using a dynamic adsorption treatment system. A submerged membrane (microfiltration) adsorption hybrid system (SMAHS) was used for the continuous removal of nitrate with a minimal amount of adsorbents. The efficiency of membrane filtration flux and replacement rate of adsorbent were studied to determine suitable operating conditions to maintain the effluent nitrate concentration below the WHO drinking standard limit of 11.3 mg N/L. The volume of water treated and the amount of nitrate adsorbed per gramme of adsorbent for all four flux tested were in the order Dowex-Fe > Dowex > AG coconut copra > AG corn cob. The volumes of water treated (L/g adsorbent) were 0.91 and 1.85, and the amount of nitrate removed (mg N/g adsorbent) were 9.8 and 22.2 for AG corn cob and Dowex-Fe, respectively, at a flux of 15 L/(m2/h).
Asunto(s)
Filtración/métodos , Resinas de Intercambio Iónico/química , Nitratos/química , Óxidos de Nitrógeno/química , Estructuras de las Plantas/química , Resinas Sintéticas/química , Purificación del Agua/métodos , Adsorción , Aminas , Cocos , Humanos , Hierro , Contaminantes Químicos del Agua/química , Zea maysRESUMEN
Adsorption using low-cost adsorbents is a favourable water treatment method for the removal of water contaminants. In this study the enhanced removal of nitrate, a contaminant at elevated concentration affecting human health and causing eutrophication of water, was tested using chemically modified agricultural wastes as adsorbents. Batch and fixed-bed adsorption studies were performed on corn cob and coconut copra that were surface modified by amine-grafting to increase the surface positive charges. The Langmuir nitrate adsorption capacities (mgN/g) were 49.9 and 59.0 for the amine-grafted (AG) corn cob and coconut copra, respectively at pH6.5 and ionic strength 1×10(-3)M NaCl. These values are higher than those of many commercially available anion exchange resins. Fixed-bed (15-cm height) adsorption capacities (mgN/g) calculated from the breakthrough curves were 15.3 and 18.6 for AG corn cob and AG coconut copra, respectively, for an influent nitrate concentration 20mg N/L at a flow velocity 5m/h. Nitrate adsorption decreased in the presence of sulphate, phosphate and chloride, with sulphate being the most competitive anion. The Thomas model fitted well to the fixed-bed adsorption data from four repeated adsorption/desorption cycles. Plug-flow model fitted well to the data from only the first cycle.