1.
Chem Commun (Camb)
; 58(72): 10091-10094, 2022 Sep 08.
Artículo
en Inglés
| MEDLINE
| ID: mdl-35997148
RESUMEN
The reaction of compounds containing Al-Mg and Al-Zn bonds with N2O enabled isolation of the corresponding Al(µ-O)M complexes. Electronic structure analysis identified largely ionic Al-O and O-M bonds, featuring an anionic µ-oxo centre. Reaction with CO2 confirmed that these species correspond to the proposed intermediates in the formation of µ-carbonate compounds.