RESUMEN
Gold nanoparticles (AuNPs) have been extensively utilized in various fields such as sensors, life sciences, and catalysis. In this study, AuNPs were synthesized using a reduction method and subsequently treated with thiourea in an ethanol-water environment to prepare AuNPs film using a centrifugal deposition method for first time, resulting in the aggregation of the initial small-sized AuNPs into larger microsphere-like structures. The addition of thiourea facilitated the interconnection between AuNPs, ultimately leading to the formation of large stable gold microspheres. The sheet resistance of the AuNP films transitioned from being non-conductive to exhibiting a sheet resistance of 42.6 Ω/sq following thiourea treatment. The transformation from a flat surface to tightly connected particles resembling microspheres was observed from SEM images. The thiourea treatment not only altered the morphological characteristic of the AuNPs films but also significantly increased the number of scattering sites on their surface, leading to a substantial enhancement in the Raman scattering effect for methylene blue. This structural configuration also improved the electronic conduction and stability of the treated AuNPs films. Consequently, these findings suggest that AuNPs have promising application prospects in surface-enhanced Raman scatting (SERS), as well as in flexible electronics, catalysis, adsorption, and energy fields.
RESUMEN
Herein, a novel method is presented for the in situ growth of gold nanofilms with branched structures in the presence of organosulfur. The key feature in this approach is the Rayleigh instability of ultrathin gold nanowires (AuNWs) without oleylamine (OAm), which allows the ultrathin AuNWs to decompose into gold nanoparticles (AuNPs) and the AuNPs to in situ grow into branched structures for high-performance stability and electrical conductivity. The sheet resistance of the gold nanofilms initially sharply decreased, whereas it subsequently slightly increased with the concentration of CS(NH2)2 until it exceeded the optimal range. After undergoing a 10 min heat treatment at 150 °C, the sheet resistance of the nanofilms was further reduced to 18 Ω/sq, which could be maintained for more than five months. The internal structure becomes fully grown and denser, forming a branched structure after heat treatment. Only certain organosulfurs can improve the electrical properties of the gold nanofilms, and the mechanism of organosulfur in the in situ growth of gold nanofilms with branched structures has also been presented. Overall, this novel method provides a straightforward and convenient approach to obtaining gold nanomaterials with branched structures, holding great potential promise for applications in flexible electronics, catalysis, and energy fields.