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1.
ACS Appl Mater Interfaces ; 10(21): 18066-18072, 2018 May 30.
Artículo en Inglés | MEDLINE | ID: mdl-29727165

RESUMEN

Eu3+ ion can be effectively sensitized by Ce3+ ion through an energy-transfer chain of Ce3+-(Tb3+) n-Eu3+, which has contributed to the development of white light-emitting diodes (WLEDs) as it can favor more efficient red phosphors. However, simply serving for WLEDs as one of the multicomponents, the design of the Ce3+-(Tb3+) n-Eu3+ energy transfer is undoubtedly underused. Theoretically, white light can be achieved with extra blue and green emissions released from Ce3+ and Tb3+. Herein, the design of the white light based on these three multicolor luminescence centers has been realized in GdBO3. It is the first time that white light is generated via accurate controls on the Ce3+-(Tb3+) n-Eu3+ energy transfer in such a widely studied host material. Because the thermal quenching rates of blue, green, and red emissions from Ce3+, Tb3+, and Eu3+, respectively, are well-matched in the host, this novel white light exhibits superior color stability and potential application prospect.

2.
Inorg Chem ; 56(15): 8829-8836, 2017 Aug 07.
Artículo en Inglés | MEDLINE | ID: mdl-28714676

RESUMEN

The dimeric molecule [Dy2(acac)6(MeOH)2(bpe)]·bpe·2MeOH (1, acac = acetylacetonate, bpe = 1,2-bis(4-pyridyl)ethylene) undergoes a solid-state ligand substitution reaction upon heating, leading to the one-dimensional chain [Dy(acac)3(bpe)]n (2). This structural transformation takes advantage of the potential coordination of the guest bpe molecules present in 1. In both complexes the Dy(III) ions adopt similar octacoordinated D4d geometries. However, the different arrangement of the negatively charged and neutral ligands alters the direction of magnetic anisotropy axis and the energy states, thus resulting in largely distinct magnetization dynamics, as revealed by the CASSCF/RASSI calculations.

3.
Chinese Medical Journal ; (24): 790-792, 2011.
Artículo en Inglés | WPRIM (Pacífico Occidental) | ID: wpr-321417

RESUMEN

Migration of metallic foreign body into the cerebral circulation is rarely seen. Most of the cases reported were due to gunshot wounds and shotgun wounds to the neck and face. When the foreign body is near the great vessel, it must be removed immediately or will cause complications. This study reported a case of delayed metallic foreign body embolus to the ophthalmic artery resulting from an injury to the right neck, which arose from the presence of metallic emboli to the cerebral circulation.


Asunto(s)
Adulto , Humanos , Masculino , Embolia , Diagnóstico , Cirugía General , Cuerpos Extraños , Diagnóstico , Cirugía General , Traumatismos del Cuello , Cirugía General , Arteria Oftálmica , Heridas y Lesiones , Patología , Cirugía General , Heridas Penetrantes
4.
Artículo en Coreano | WPRIM (Pacífico Occidental) | ID: wpr-58684

RESUMEN

Rhino-orbito-cerebral mucormycosis (ROCM) is an uncommon, acute, and aggressive fungal infection occurring in several immunocompromised states including poorly controlled diabetes. ROCM causes a very high residual morbidity and mortality due to the angioinvasion property of the fungus. Acromegaly is a chronic condition resulting from the excessive secretion of growth hormone, generally from pituitary adenoma. Although it has been demonstrated that acromegalic patients have an increased risk of neoplasm, gastric cancer with acromegaly is very rare. We experienced a case of pituitary mucormycosis in the diabetic patient with acromegaly and gastric cancer. The patient was treated successfully with subtotal gastrectomy for early gastric cancer, transsphenoidal surgery for pituitary adenoma, and a systemic application of amphotericin B for the mucormycosis.


Asunto(s)
Humanos , Acromegalia , Anfotericina B , Hongos , Gastrectomía , Hormona del Crecimiento , Mortalidad , Mucormicosis , Neoplasias Hipofisarias , Neoplasias Gástricas
5.
Artículo en Chino | WPRIM (Pacífico Occidental) | ID: wpr-683137

RESUMEN

20(Z= -2.117, P=0.034), and between the patients with OD and without OD (Z=-3.089, P=0.002), but PCT was not so between the non-surviror and survivor (Z=-1.307, P=0.191). The serum PCT level correlated with the incidence of organ dysfunction (x~2=14.82, P=0.033) and APACHEII (x~2=12.83, P

6.
Chinese Journal of Traumatology ; (6): 105-110, 2005.
Artículo en Inglés | WPRIM (Pacífico Occidental) | ID: wpr-338633

RESUMEN

<p><b>OBJECTIVE</b>To study the mechanical properties and the clinical results of minimum-contact plate in the treatment of fractures.</p><p><b>METHODS</b>Four-point bending and torsion tests were conducted to compare the new minimum contact plate (MCP) with dynamic compression plate (DCP) and limited contact dynamic compression plate (LC-DCP). The fracture healing time and growth of bony callus were observed in 29 cases of long bone fracture fixed with MCP to evaluate the advantages of this kind of plate.</p><p><b>RESULTS</b>The 29 patients who underwent MCP were followed up from 6 to 14 months. The average healing time for femoral, tibial and humeral fractures was 12, 13 and 10 weeks, respectively. All fractures were healed. No displacement of fracture, screw pullout, deformation or break of the plate were found.</p><p><b>CONCLUSIONS</b>The bending stiffness of MCP is significantly greater than that of DCP and LC-DCP (P<0.05). MCP can protect the periosteal blood supply against avascular osseous necrosis and accelerate bone healing. It is a kind of reliable and effective plate in treatment of fractures.</p>


Asunto(s)
Adolescente , Adulto , Anciano , Niño , Femenino , Humanos , Masculino , Persona de Mediana Edad , Fenómenos Biomecánicos , Placas Óseas , Fracturas del Fémur , Cirugía General , Estudios de Seguimiento , Fijación Interna de Fracturas , Métodos , Curación de Fractura , Fracturas Cerradas , Cirugía General , Fracturas Abiertas , Cirugía General , Fracturas del Húmero , Cirugía General , Fracturas de la Tibia , Cirugía General , Anomalía Torsional , Resultado del Tratamiento
7.
Artículo en Chino | WPRIM (Pacífico Occidental) | ID: wpr-676214

RESUMEN

Objective To study the changes of serum level of high mobility group box-1(HMGB- 1)in patients with multiple trauma in order to forecast organ dysfunction(OD)and deaths.Methods The optical densities of HMGB-1 in serum of 35 patients with multiple trauma were determined on 1st,3rd, and 7th days after trauma,and the incidence of organ dysfunction and deaths were evaluated,then analyzed statistically to learn the relation between the serum levels of HMGB-1 and deaths with an attempt of predic- ting the incident of organ dysfunction and deaths.Results (1)As OD was concerned,there was a statis- tically significant difference in optical density of HMGB-1 on 1st and 3rd days between the two groups of multiple injury patients(t=4.411,P

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