RESUMEN
Metals discharged from abandoned mines are a major source of pollution in many parts of the world. As a result, there is a growing need for suitable low-cost remediation methods. While a large literature base exists demonstrating the efficacy of biochar to remove metals from solution, most studies are confined to the laboratory. This study examines the effects on the biochar quality when scaling up production from laboratory to pilot scale. Pilot scale biochars were produced using a 600 kg batch pyrolysis reactor, these chars were then deployed in the field using a series of 100 mm × 1200 mm cylindrical treatment cells installed at the point of discharge from an abandoned mine site. Most biochars produced at a pilot removed more zinc under laboratory conditions, however all of the biochars showed a reduced performance when tested in the field, this ranged from a 14% to an 85% reduction depending on the biochar.
Asunto(s)
Carbón Orgánico , Pirólisis , Adsorción , Metales , Minería , SueloRESUMEN
Two energy grass species, switch grass, a North American tuft grass, and reed canary grass, a European native, are likely to be important sources of biomass in Western Europe for the production of biorenewable energy. Matching chemical composition to conversion efficiency is a primary goal for improvement programmes and for determining the quality of biomass feed-stocks prior to use and there is a need for methods which allow cost effective characterisation of chemical composition at high rates of sample through-put. In this paper we demonstrate that nitrogen content and alkali index, parameters greatly influencing thermal conversion efficiency, can be accurately predicted in dried samples of these species grown under a range of agronomic conditions by partial least square regression of Fourier transform infrared spectra (R(2) values for plots of predicted vs. measured values of 0.938 and 0.937, respectively). We also discuss the prediction of carbon and ash content in these samples and the application of infrared based predictive methods for the breeding improvement of energy grasses.
Asunto(s)
Fuentes de Energía Bioeléctrica , Poaceae/química , Álcalis/análisis , Carbono/análisis , Fertilizantes , Análisis de los Mínimos Cuadrados , Nitrógeno/análisis , Análisis de Componente Principal , Espectroscopía Infrarroja por Transformada de FourierRESUMEN
Mankind's spacefaring future demands the ability to work freely and frequently in space. Traditional spacesuit systems burden both the spacefarer and the mission, limiting the extent to which this is possible. The spacefarer is burdened by a pressure suit designed for isolation from the environment and a life support system designed to replace everything our environment normally provides. The space mission is burdened by this equipment and the expendable materials to operate and maintain it. We aren't free to work in space as frequently, as long, or in all of the locations envisioned. The NASA Institute for Advanced Concepts (NIAC) has sponsored research on an alternative concept, the "Chameleon Suit", that seeks to liberate future explorers and missions from these limitations. The Chameleon Suit system works with the environment in an adaptive fashion to minimize hardware and expendable materials. To achieve this, functions of the life support system are integrated with the pressure suit using emerging materials and design technology. Technologies under study include shape change polymers and electroemissive materials to modify heat transfer characteristics of the spacesuit "skin" achieving thermoregulation analogous to that in natural biological systems. This approach was shown to be feasible for many space missions during the Phase 1 study program. The current Phase 2 program is investigating more aggressive concepts aimed at eliminating most of the hardware currently included in the spacesuit's life support backpack. This paper describes the concept, study results to date, and possible impacts on future human space exploration.