RESUMEN
The development of bioactive ceramics still poses challenges in finding a good compromise between bioactivity and mechanical robustness. Moreover, a facile, low-cost and energy-saving synthesis technique is still needed. This study concerns the synthesis of a bioactive material by growing a bioactive Na-Ca-Mg-Si-based ceramic matrix produced using the alkali-activation method on silicon nitride (Si3N4) particles. This technique simultaneously forms the matrix precursor and functionalizes the Si3N4 particles' surface. The optimal strength-bioactivity compromise was found for the composition containing 60 wt.% Si3N4 and 40 wt.% of the matrix exhibiting good compressive strength of up to 110 MPa and extensive precipitation of hydroxyapatite on the sample surface after 7 days of soaking in simulated body fluid. This innovative approach merging strong non-oxide binary ceramics with the versatile and low-cost alkali-activation method holds great expectations for the future in biomaterials.
RESUMEN
The paper reports on the experimental results obtained from the production of glassy slag by the plasma smelting of a mixture of two different wastes. The combination of two wastes with different chemical compositions is a promising way to optimise the energy consumption in the disposal process. Asbestos-cement roof tiles (ACRTs) and fly ash from fluidised-bed boilers (with a weight ratio of 1:1) were used for the preparation of glassy (vitrified) slag. The thermal process facilitated a 14.4% reduction of the weight of the original mixture and a 72% volume reduction of the waste. The glassy slag is then adopted as a raw material in the production of porous materials intended for various architectural applications, thus eliminating the necessity for its further disposal. The formation of a porous glass-ceramic matrix, using the vitrified slag containing CaSO4 as the pore-forming agent, is described in detail. A glass-ceramic foam with 66% porosity is formed by the rapid heating of the mixture of glassy slag and a 1â¯wt% of CaSO4, consisting of crystallised calcium aluminosilicate (Ca2Al2SiO7, Ca0.88Al1.77Si2.23O8). The thermal conductivity of the prepared porous material, measured by a laser flash thermal analysis, is 0.22â¯W·m-1·K-1.