RESUMEN

Organic amendments often reduce the bioaccessibility of soil lead (Pb) but not that of soil arsenic (As). The effect of Pb on As bioaccessibility is rarely studied in co-contaminated soils. In a field study, we assessed the effect of mushroom compost, leaf compost, noncomposted biosolids, and composted biosolids amendments on As speciation in a co-contaminated (As and Pb) soil at 7, 349, and 642 days after amending soils and the change of As speciation during an in vitro bioaccessibility extraction (gastric solution, pH 2.5) using bulk X-ray absorption near-edge structure spectroscopy. Soil was contaminated by coal combustion and other diffuse sources and had low As bioaccessibility (7%-12%). Unamended soil had As(III) sorbed onto pyrite (As(III)-pyrite; ∼60%) and As(V) adsorbed onto Fe oxy(hydr)oxides (As(V)-Fh; ∼40%). In amended soils, except in composted biosolids-amended soils, at 7 days, As(V)-Fh decreased to 15%-26% and redistributed into As(III)-Fh and/or As(III)-pyrite. This transformation was most pronounced in mushroom compost amended soil resulting in a significant (46%) increase of As bioaccessibility compared to the unamended soil. Composted biosolids-amended soils had relatively stable As(V)-Fh. Lead arsenate formed during the in vitro extraction in amended soils, except in composted biosolids-amended soils. Arsenic speciation and bioaccessibility were similar in 349- and 642-day in all the amended and unamended soils. Reduction of As(V)-Fh to As(III) forms in the short term in three of the amended soils showed the potential to increase As bioaccessibility. The formation of stable lead arsenate during the in vitro extraction would counteract the short-term increase of As bioaccessibility in those amended soils.

Asunto(s)

RESUMEN

Snowmelt runoff is a dominant pathway of phosphorus (P) losses from agricultural lands in cold climatic regions. Soil amendments effectively reduce P losses from soils by converting P to less soluble forms; however, changes in P speciation in cold climatic regions with fall-applied amendments have not been investigated. This study evaluated P composition in soils from a manured field with fall-amended alum (Al2(SO4)3·18H2O), gypsum (CaSO4·2H2O), or Epsom salt (MgSO4·7H2O) using three complementary methods: sequential P fractionation, scanning electron microscopy with energy-dispersive X-rays (SEM-EDX) spectroscopy, and P K-edge X-ray absorption near-edge structure spectroscopy (XANES). Plots were established in an annual crop field in southern Manitoba, Canada, with unamended and amended (2.5 Mg ha-1) treatments having four replicates in 2020 fall. Soil samples (0-10 cm) taken from each plot soon after spring snowmelt in 2021 were subjected to P fractionation. A composite soil sample for each treatment was analyzed using SEM-EDX and XANES. Alum- and Epsom salt-treated soils had significantly greater residual P fraction with a higher proportion of apatite-like P and a correspondingly lower proportion of P sorbed to calcite (CaCO3) than unamended and gypsum-amended soils. Backscattered electron imaging of SEM-EDX revealed that alum- and Epsom salt-amended treatments had P-enriched microsites frequently associated with aluminum (Al), iron (Fe), magnesium (Mg), and calcium (Ca), which was not observed in other treatments. Induced precipitation of apatite-like species may have been responsible for reduced P loss to snowmelt previously reported with fall application of amendments.

Asunto(s)

RESUMEN

Current child blood lead (Pb) screening guidelines assume that blood lead levels (BLLs) are relatively stable over time, and that only youngest children are vulnerable to the damaging effects of lower-range BLLs. This study aimed to test the stability of lower-range (≤ 10 µg/dL) child BLLs over time, and whether lower-range BLLs diminished with age among children aged 6 months to 16 years living in a lower-income neighborhood with a density of pre-1986 housing and legacy contamination. Age, sex, family income, age of residence, and/or residence proximity to point sources of Pb, were tested as potential additional factors. Capillary blood samples from 193 children were analyzed by inductively coupled plasma mass spectrometry (ICPMS). Multiple imputation was used to simulate missing data for 3 blood tests for each child. Integrated Growth Curve models with Test Wave as a random effect were used to test BLL variability over time. Among N = 193 children tested, at Time 1 testing, 8.7% had the BLLs ≥ 5 µg/dL (CDC "elevated" BLL reference value at the time of data collection) and 16.8% had BLLs ≥ 3.5 µg/dL (2021 CDC "elevated" BLL reference value). Modeling with time as a random effect showed that the variability of BLLs were attributable to changes within children. Moreover, time was not a significant predictor of child BLLs over 18 months. A sex by age interaction suggested that BLLs diminished with age only among males. Of the additional environmental factors tested, only proximity to a major source of industrial or vehicle exhaust pollution predicted child BLL variability, and was associated with a small, but significant BLL increase (0.22 µg/dL). These findings suggest that one or two BLL tests for only infants or toddlers are insufficient for identifying children with Pb poisoning.

Asunto(s)

RESUMEN

Established methods for using standardized dust wipes to collect and measure total lead in household dust are readily available but the use of dust wipes to measure bioaccessible lead (BaPb) is less clear. This study compared two in vitro methods for estimating the proportion of BaPb in dust collected into dust wipes including the US-EPA's in-vitro bioaccessible assay (IVBA) method at two pH (1.5 and 2.5) values; and the physiologically based extraction test (PBET 2.5 pH). Two types of simulated household dust samples (Pb-soil contaminated and Pb-paint contaminated) each with three Pb concentrations were created. Equal amounts of simulated dust were applied to a smooth surface and collected following the standard EPA dust wipe protocol and were analyzed for BaPb and total Pb (ASTM-E1644-17, ICP-OES). Estimated BaPb levels differed significantly by the method of extraction. Mean percent BaPb were IVBA pH 1.5, > 90% (Pb-paint) and 59-63% (Pb-soil); IVBA pH 2.5 78-86% (Pb-paint) and 45-50% (Pb-soil); PBET pH 2.5 56 to 61% (Pb-paint) and 41-50% Pb-soil). Particularly for lead-paint contaminated dust, PBET showed significantly greater discrimination as suggested by the broader range of BaPb values and closer approximation to total lead concentrations in simulated household dust samples.

Asunto(s)

RESUMEN

Phosphorus (P) losses from flooded soils and subsequent transport to waterways contribute to eutrophication of surface waters. This study evaluated the effectiveness of MnO2 and a zeolite Y amendment in reducing P release from flooded soils and explored the underlying mechanisms controlling P release. Unamended and amended (MnO2 or zeolite, surface-amended at 5 Mg ha-1) soil monoliths from four clayey-alkaline soils were flooded at 22 ± 2 °C for 56 days. Soil redox potential and dissolved reactive P (DRP), pH, and concentrations of major cations and anions in porewater and floodwater were analyzed periodically. Soil P speciation was simulated using Visual MINTEQ at 1, 28, and 56 days after flooding (DAF) and P K-edge X-ray absorption near-edge structure spectroscopy and sequential fractionation at 56 DAF. Porewater DRP increased with DAF and correlated negatively with pe+pH and positively with dissolved Fe. Reductive dissolution of Fe-associated P was the dominant mechanism of flooding-induced P release. The MnO2 amendment reduced porewater DRP by 30%-50% by favoring calcium phosphates (Ca-P) precipitation and delaying the reductive dissolution reactions. In three soils, the zeolite amendment at some DAF increased porewater and/or floodwater DRP through dissolution of Ca-P and thus was not effective in reducing P release from flooded soils.

Asunto(s)

RESUMEN

Fifty years ago, the Journal of Environmental Quality (JEQ) was launched to provide an outlet for publication of research on the impacts of agriculture on the environment, and vice versa. A core concept of JEQ is advancement of environmental science, with emphasis on understanding factors that affect the fate, risks, and quality of soil, water, and atmospheric systems, and how these system processes affect plants, microbes, and animals. Trace elements are a focus area of JEQ because when present at higher than natural concentrations, they may pose risks to environmental quality and ecosystem health, depending on their bioavailability. Trace element biogeochemical cycling is affected by anthropogenic influences on land, air, and water, including land management practices such as agriculture and mining. The Journal of Environmental Quality has published a prolific catalog of scientific research publications on trace elements and their risks to humans, soil health, water quality, and the environment. In this review, research on trace elements and their impacts on environmental quality is presented, with a special focus on work published in JEQ.

Asunto(s)

RESUMEN

Military activities can contaminate productive land with potentially toxic substances. The most common trace metal contaminant on military bases is lead (Pb). A field experiment was begun in 2016 at Fort Riley, KS, in an area with total soil Pb concentrations ranging from 900 to 1,500 mg kg-1 and near-neutral pH. The main objectives were to test the potential of Miscanthus sp. for phytostabilization of the site and to evaluate the effects of soil amendments on Miscanthus growth, soil-plant Pb transfer, bioaccessibility of soil Pb, and soil health. The experimental design was a randomized complete block, with five treatments and four replications. Treatments were (a) existing vegetation; (b) Miscanthus planted in untilled soil, no amendments; (c) Miscanthus planted in tilled soil; (d) Miscanthus planted in tilled soil amended with inorganic P (triple superphosphate applied at 5:3 Pb:P); and (e) Miscanthus planted in tilled soil amended with organic P (Class B biosolids applied at 45 Mg ha-1 ). Tilling and soil amendments increased dry matter yields only in the establishment year. Total Pb uptake, plant tissue Pb concentration, and soil Pb bioaccessibility were significantly less in the Miscanthus plots amended with biosolids than the Miscanthus plots with no added P across all 3 yr. Enzyme activities, organic carbon, and microbial biomass were also greater in biosolids-treated plots. Results show that planting-time addition of soil amendments to Pb-contaminated soil supported Miscanthus establishment, stabilized and reduced bioaccessibility of soil Pb, reduced concentration and uptake of Pb by Miscanthus, and enhanced soil health parameters.

Asunto(s)

RESUMEN

Anaerobic membrane bioreactors (AnMBRs) represent an emerging environmental biotechnology platform with the potential to simultaneously recover water, energy, and nutrients from concentrated wastewaters. The removal and beneficial capture of nutrients from AnMBR permeate has yet to be fully explored, therefore this study sought to foster iron phosphate recovery through a tertiary coagulation process, as well as characterize the recovered nutrient product (RNP) and assess its net phosphorus release, diffusion, and availability for plant uptake. One of the primary goals of this study was to optimize the dose of the coagulant, ferric chloride, and coagulant aid, aluminum chlorohydrate (ACH), for continuous application to the coagulation-flocculation-sedimentation (CFS) unit of an AnMBR pilot plant treating municipal wastewater, through controlled bench-scale jar tests. Anaerobic systems present unique challenges for nutrient capture, including high, dissolved hydrogen sulfide concentrations, along with settleability issues. The addition of the coagulant aid increases settleability, while enhancing phosphorus removal by up to 20%, decreasing iron demand. Water quality analysis indicated that a variety of factors affect nutrient capture, including the COD (chemical oxygen demand) concentration of the permeate and the limiting coagulant dose. COD >200 mg/L was shown to decrease the phosphorus removal efficiency by up to 15%. A combination of inductively coupled plasma optical emission spectrometer (ICP-OES) elemental analysis, inductively coupled plasma mass spectrometer (ICP-MS) elemental analysis, scanning electron microscopy (SEM), X-ray diffraction (XRD), and X-ray absorption near-edge structure (XANES) spectroscopy analysis was used to characterize the P-rich RNP which revealed a 2.58% w/w phosphorus content and the lack of a well-defined crystalline structure. Detailed studies on resin extractable phosphorus to assess the plant uptake potential also demonstrated that iron-based P-rich RNPs may not be an effective fertilizer product, as they can act as a phosphorus sink in some agricultural systems instead of a source.

Asunto(s)

RESUMEN

Urban gardening has been experiencing increased popularity around the world. Many urban gardens are located on sites that may be contaminated by trace elements or organic compounds due to previous use. The three main exposure pathways to the human body for soil contaminants are (a) ingestion of soil directly, (b) consumption of produce containing or superficially contaminated with a contaminant, (c) and inhalation of soil dust. The first two modes have received much attention; however, the contribution of the inhalation route has not been investigated adequately. Two inhalation risk studies were carried out in urban gardens located in Kansas City, MO, by collecting dust while 25-m2 plots were rototilled. Microclimatic variables were monitored, and total inhalable dust mass was determined using a personal sampling train including a small pump and air filter. Soil lead (Pb) concentration was assessed at both sites. For Study 1, particle size distribution of collected particles was estimated through analysis of scanning electron microscope images of filters. Little dust was collected at either site. Most particles captured, however, appeared to be <4 µm in diameter. The amount of dust emitted was correlated with soil moisture. Tilling reduced soil aggregate size and blended soil, resulting in a more homogeneous distribution of Pb. Dust inhalation while tilling is likely not a major Pb exposure risk for gardeners, but given the preponderance of very small particles in what was captured, care should be taken to prevent dust from entering the respiratory system.

Asunto(s)

RESUMEN

Research on Soils in Urban, Industrial, Traffic, Mining and Military Areas (SUITMA) has been presented at biennial SUITMA conferences held in cities around the world. Soils from these areas often present environmental, ecological, and health risks and can limit ecological functions and ecosystem services. However, as with all soils, they are an integral part of the local ecosystem. In urban areas in particular, soil is a critical resource and can play a key role in the long-term sustainability and resiliency of cities. This special section contains five papers from the SUITMA 10 conference held in Seoul, South Korea, in 2019. They cover diverse topics that include urban soil properties, risk from contaminated soils, biological indicators for ecological functions, air deposition in urban gardens, and international summer field school opportunities. This section highlights research on anthropogenic soils conducted by the SUITMA community to promote better understanding and management of these soils.

Asunto(s)

RESUMEN

Humic substances (HS) and humic acids (HA) are proven to enhance nutrient uptake and growth in plants. Foliar application of urea combined with HS and HA offers an alternative strategy to increase nitrogen use efficiency (NUE). The objective of this study was to understand the effects of foliar application of HA and HS along with urea on NUE and response of different biometric, biochemical and physiological traits of sugarcane with respect to cultivar, mode of foliar application, geographic location and intervals of foliar application. To study this, two different independent Experiments were conducted in green house facilities at two different agro-climatic zones (USA and Brazil) using two different predominant varieties, modes and intervals of foliar applications. The three different foliar applications used in this study were (1) urea (U), (2) mixture of urea and HS (U+HS) and (3) HA (U+HA). In both Experiments, 15N (nitrogen isotope) recovery or NUE was higher in U+HS followed by U+HA. However, magnitude of NUE changed according to the differences in two Experiments. Results showed that foliar application of U+HS and U+HA was rapidly absorbed and stored in the form of protein and starch. Also induced changes in photosynthesis, intrinsic water use efficiency, protein, total soluble sugars and starch signifying a synergistic effect of U+HS and U+HA on carbon and nitrogen metabolism. These results showed promising use of HS and HA with urea to improve NUE in sugarcane compared to using the urea alone. Simultaneously, mode, quantity, and interval of foliar application should be standardized based on the geographic locations and varieties to optimize the NUE.

RESUMEN

Tungsten (W) occurrence and speciation was investigated in sediments collected from Fallon, Nevada where previous studies have linked elevated W levels in human body fluids to an unusual cluster of childhood leukemia cases. The speciation of sedimentary W was determined by µ-XRF mapping and µ-XANES. The W content of the analyzed surface sediments ranged between 81 and 25,908 mg/kg, which is significantly higher than the W content in deeper sediments which ranged from 37 to 373 mg/kg at 30 cm depth. The µ-XANES findings reveal that approximately 20-50% of the total W in the shallow sediment occurs in the metallic form (W0); the rest occurs in the oxide form (WVIO3). Because W0 does not occur naturally, its elevated concentrations in surface sediments point toward a possible local anthropogenic origin. The oxidation of metallic W0 with meteoric waters likely leads to the formation of WVIO3. The chief water-soluble W species was identified as WO42- by chromatographic separation and speciation modeling. These results led us to postulate that W0 particles from a currently unknown but local source(s) is (are) deposited onto the soils and/or surface sediments. The W0 in interaction with meteoric water is oxidized to WVIO3, and as these sediment-water interactions progress, WO42- is formed in the water at pH ∼7. Under pH < 7, and sufficient W concentrations, tungstate tends to polymerize, and polymerized species are less likely to adsorb onto sediments. Polymerized species have lower affinity than monomers, which leads to enhanced mobility of W.

Asunto(s)

RESUMEN

The development of highly concentrated phosphorus (P) fertilizers, such as triple superphosphate, by the Tennessee Valley Authority helped mark the beginning of a revolution in the way we manage food crop nutrition. Since then, scientists, with the help of farmers, have made great advancements in the understanding of P fate and transport across many environments but largely have failed to produce a new generation of products and/or application techniques that are widely accepted and that vastly improve plant acquisition efficiency. Under certain conditions, important advancements have been made. For example, applying liquid formulations of phosphates in lieu of dry granules in some highly calcareous soils has dramatically reduced precipitation as sparingly soluble calcium phosphate minerals, but other attempts, such as the co-application of humic substances, sorption to layered double hydroxides, or use of nanoparticles, have not generated the kind of results necessary to continue economically increasing crop yields without further environmental cost. New sources of fertility will need to be affordable to produce, transport, and furnish P to soil solution in a manner well synchronized with crop demand. This paper provides a review of recent literature on cutting-edge phosphorus fertilizer technology. The goal is that this synthesis will be used as a starting point from which a larger discussion on responsible nutrient management and increased P use efficiency research can be built.

Asunto(s)

RESUMEN

Population growth and technical and social changes have always exerted pressure on environmental quality. However, we are experiencing unprecedented change in the rate and scale of human impacts on the environment. The One Health Initiative recognizes that improving the quality of life for humans and other animal species requires a holistic and integrated framework to seek multidisciplinary solutions to global environmental quality challenges. This special section is designed to elucidate the connections among soil health, environmental quality, food safety and security, and human health. Soil chemistry is defined as the field of soil science that deals with the chemical constituents, properties, and reactions of soils. Soil chemistry plays a central role in food production and the protection of human health. Chemical reactions between nutrients or contaminants and soil solids, and the composition of the soil solution and the atmosphere, influence crop growth as well as the quality of our food, air, and water. This collection of nine papers brings together studies that highlight how soil chemical constituents, properties, and reactions can be examined or managed using a multidisciplinary approach to move toward a more efficient, sustainable, nutrient-rich, and low-contaminant food production system that affords protection of soil, water, and human and animal health. We believe that studies such as these are needed to maintain and enhance environmental quality through interdisciplinary scientific approaches for human, animal, and environmental health outcomes.

Asunto(s)

RESUMEN

Direct evidence-based approaches are vital to evaluating newly proposed theories on the persistence of soil organic carbon and establishing the contributions of abiotic and biotic controls. Our primary goal was to directly identify the mechanisms of organic carbon stabilization in native-state, free soil microaggregates without disrupting the aggregate microstructure using scanning transmission x-ray microscopy coupled with near edge x-ray absorption fine structure spectroscopy (STXM-NEXAFS). The influence of soil management practices on microaggregate associated-carbon was also assessed. Free, stable soil microaggregates were collected from a tropical agro-ecosystem in Cruz Alta, Brazil. The long-term experimental plots (>25 years) comparing two tillage systems: no-till and till with a complex crop rotation. Based on simultaneously collected multi-elemental associations and speciation, STXM-NEXAFS successfully provided submicron level information on organo-mineral associations. Simple organic carbon sources were found preserved within microaggregates; some still possessing original morphology, suggesting that their stabilization was not entirely governed by the substrate chemistry. Bulk analysis showed higher and younger organic carbon in microaggregates from no-till systems than tilled systems. These results provide direct submicron level evidence that the surrounding environment is involved in stabilizing organic carbon, thus favoring newly proposed concepts on the persistence of soil organic carbon.

RESUMEN

The soil material in constructed wetlands is effective in retaining Se from flue-gas desulfurization (FGD) wastewater (WW), but reducing conditions can enhance native-soil As mobility. A laboratory-based soil column experiment was performed to assess the effectiveness of ferrihydrite (Fh) in minimizing the mobility of native-soil As in water-saturated soil material. A saline FGD WW mixture (i.e., influent) was delivered to columns of untreated and Fh-treated soil for 60 d. One untreated column and one Fh-treated column were then subjected to drying, followed by an additional 30 d of influent delivery. Although the influent was low in As (∼1 µg L) and the soil As level was normal, the total dissolved As concentration of effluent from the untreated columns increased with time, from ∼1 µg L to a maximum of ∼27 µg L. In contrast, effluent from the Fh-treated columns remained low in As (i.e., <5 µg L). The strong correlation between total dissolved Fe and As in the effluent suggested that reductive dissolution of native-soil Fe minerals was responsible for releasing As into solution. Results from X-ray absorption spectroscopy showed newly precipitated Fe minerals in the Fh-treated soil, and the remaining As was mainly As(V) species in both the untreated and Fh-treated soils. Thus, native-soil As mobilized under saturated conditions can be sequestered by adding poorly crystalline Fe oxides to soil prior to saturation. Furthermore, results obtained by drying and rewetting the columns showed that saturated conditions must be maintained to minimize the remobilization of sequestered As and retained Se.

Asunto(s)

RESUMEN

Industrial wastewater from the flue gas desulfurization (FGD) process is characterized by the presence of trace elements of concern, such as selenium (Se) and boron (B) and relatively high salinity. To simulate treatment that FGD wastewater undergoes during transport through soils in subsurface treatment systems, a column study (140-d duration) was conducted with native Kansas soil and saline FGD wastewater, containing high Se and B concentrations (170 µg/L Se and 5.3 mg/L B) and negligible arsenic (As) concentration (∼1.2 µg/L As). Se, B, and As, and dissolved organic carbon concentrations and organic matter spectroscopic properties were measured in the influent and outflow. Influent Se concentrations were reduced by only ∼half in all treatments, and results suggest that Se sorption was inhibited by high salinity of the FGD wastewater. By contrast, relative concentrations (C/Co) of B in the outflow were typically <10%, suggesting that B sequestration may have been enhanced by higher salinity. Unexpected elevated As concentrations in the outflow (at >150 µg/L in the treatment with labile organic carbon addition) suggest that soils not previously known to be geogenic arsenic sources have the potential to release As to groundwater in the presence of high salinity wastewater and under reducing conditions.

Asunto(s)

RESUMEN

Constructed wetland treatment systems are used to remove selenium (Se) from flue-gas desulfurization (FGD) wastewater (WW). However, direct confirmation of the mechanism responsible for FGD WW Se retention in soil is lacking. A laboratory-based soil column study was performed to develop an evidence-based mechanism of Se retention and to study the behavior and the retention capacity of FGD WW constituents in water-saturated soil. A deoxygenated 1:1 mixture of FGD WW and raw water was delivered to the columns bottom-up at a flux of 1.68 cm d for 100 d. Some of the columns were flushed with the raw water at the same rate for an additional 100 d. Column effluent was analyzed for constituents of concern. Results showed a complete retention of FGD WW Se in the soil materials. Boron and fluorine were partially retained; however, sulfur, sodium, and chlorine retention was poor, agreeing with field observations. The FGD WW Se was retained in soil near the inlet end of the columns, indicating its limited mobility under reduced conditions. Sequential extraction procedure revealed that retained Se was mainly sequestered as stable/residual forms. Bulk- and micro-X-ray absorption near-edge structure spectroscopy confirmed that Se was mainly retained as reduced/stable species [Se(IV), organic Se, and Se(0)]. This study provides direct evidence for FGD WW Se retention in water-saturated soil via the transformation of oxidized Se into reduced/stable forms.

Asunto(s)

RESUMEN

In situ soil amendments can modify the Pb bioavailability by changing soil Pb speciation. Urban soils from three vegetable gardens containing different total Pb concentrations were used. The study evaluated how compost amendment and aging of soil-compost mixture in situ affected the following: (i) soil Pb speciation in the field and (ii) change of soil Pb speciation during an in vitro bioaccessibility extraction mimicking gastric phase dissolution at pH 2.5. X-ray absorption fine structure spectroscopy was used to determine Pb speciation in amended and nonamended soils and residues left after in vitro bioaccessibility extraction of those soils. Compost amendment and aging of compost in the field had a negligible effect on Pb bioaccessibility in the soils. Major Pb species in the soils were Pb sorbed to Fe oxy(hydr)oxide (Pb-Fh) and to soil organic C (Pb-Org). The fraction of Pb-Org was increased as soil-compost mixture aged in the field. During the in vitro extraction, the fraction of Pb-Fh was decreased, the fraction of Pb-Org was increased, and hydroxypyromorphite was formed in both amended and nonamended soils. Freshly incorporated compost enhanced the dissolution of Pb-Fh during the extraction. As soil-compost mixture aged in the field, the dissolution of Pb-Fh was low, demonstrating more stability of the Pb-Fh during the extraction. Compost amendment showed potential to contribute to reduced bioaccessibility of Pb as compost aged in the soil by increasing Pb-Org fraction in the field and stability of Pb-Fh during the in vitro bioaccessibility extraction.

Asunto(s)

RESUMEN

To understand the biogeochemistry of nutrients and contaminants in environmental media, their speciation and behavior under different conditions and at multiple scales must be determined. Synchrotron radiation-based X-ray techniques allow scientists to elucidate the underlying mechanisms responsible for nutrient and contaminant mobility, bioavailability, and behavior. The continuous improvement of synchrotron light sources and X-ray beamlines around the world has led to a profound transformation in the field of environmental biogeochemistry and, subsequently, to significant scientific breakthroughs. Following this introductory paper, this special collection includes 10 papers that either present targeted reviews of recent advancements in spectroscopic methods that are applicable to environmental biogeochemistry or describe original research studies conducted on complex environmental samples that have been significantly enhanced by incorporating synchrotron radiation-based X-ray technique(s). We believe that the current focus on improving the speciation of ultra-dilute elements in environmental media through the ongoing optimization of synchrotron technologies (e.g., brighter light sources, improved monochromators, more efficient detectors) will help to significantly push back the frontiers of environmental biogeochemistry research. As many of the relevant techniques produce extremely large datasets, we also identify ongoing improvements in data processing and analysis (e.g., software improvements and harmonization of analytical methods) as a significant requirement for environmental biogeochemists to maximize the information that can be gained using these powerful tools.

Asunto(s)