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Phys Chem Chem Phys ; 13(26): 12254-60, 2011 Jul 14.
Artículo en Inglés | MEDLINE | ID: mdl-21633734

RESUMEN

Single crystal silver wires can be grown at the nitrobenzene|water interface when silver ions dissolved in the aqueous phase are reduced by decamethyl ferrocene dissolved in the nitrobenzene phase. The successful growth of these wires depends on a number of experimental conditions, most prominently on the concentration ratio of reactants, nucleation rates, shape of formed nuclei, and wettability of nuclei. The size-time dependence can be modeled on the basis of microelectrode behavior of the silver nuclei and wire. AFM, SEM, light microscopy and single crystal X-ray diffraction has been applied to study the morphology of the silver nuclei and wires.


Asunto(s)
Cristalización/métodos , Nitrobencenos/química , Plata/química , Cristalografía por Rayos X , Compuestos Ferrosos/química , Metalocenos , Oxidación-Reducción , Agua/química , Humectabilidad
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