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Chemistry ; 24(42): 10606-10611, 2018 Jul 25.
Artículo en Inglés | MEDLINE | ID: mdl-28975674

RESUMEN

A cofacial iron porphyrin heterodimer, Fe2 TPFPP-TMP showed high electrocatalytic activity, selectivity, and stability for O2 reduction to H2 O both in homogeneous non-aqueous and heterogeneous neutral aqueous solutions. When it is integrated to FTO/p-CuBi2 O4 (FTO=fluorine doped tin oxide) photocathode prepared by a simple novel method, a remarkable efficient solar-assisted O2 reduction is achieved in neutral potassium phosphate (KPi) or basic NaOH solutions saturated with O2 .

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