RESUMEN
Titanium dioxide (TiO2) is one of the most widely used photocatalysts due to its physical and chemical properties. In this study, hydrogen energy production using TiO2- and titanate-based photocatalysts is discussed along with the pros and cons. The mechanism of the photocatalysis has been elaborated to pinpoint the photocatalyst for better performance. The chief characteristics and limitations of the TiO2 photocatalysts have been assessed. Further, TiO2-based photocatalysts modified with a transition metal, transition metal oxide, noble metal, graphitic carbon nitride, graphene, etc. have been reviewed. This study will provide a basic understanding to beginners and detailed knowledge to experts in the field to optimize the TiO2-based photocatalysts for hydrogen production.
RESUMEN
The world is facing environmental pollution and is in an alarming situation due to industrialization and urbanization. Especially, industrial wastewater discharge is causing serious pollution in the environment (water, soil, and air) and has become a challenge for researchers and scientists. Wastewater contains heavy metals like Cu, Ni, Cr, Pb, and Ar and causes toxicity in living beings and the environment. In this review, the sources of heavy metals and their toxicological effects on the environment have been reviewed. Various remediation techniques such as reverse osmosis, chemical precipitation, and ultrafiltration are being used for the treatment of wastewater, but still are limited in their efficiencies, residues, cost, and versatility. In this study, the most promising wastewater treatment technique, the physic-chemical technique, has been reviewed along with its working mechanism and efficiency. Further, the pros and cons of this technique and sub-techniques have also been reviewed to provide a basic understanding to beginners and a pathway to experts in the selection of better techniques.