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The main objective of this article is to provide new information on the effects of mechanical pretreatment of AZ80 magnesium alloy ground with SiC emery papers of different grain sizes on the plasma electrolytic oxidation (PEO) process and corrosion properties of AZ80 in 0.1 M NaCl solution. Then, the roughness of the coated samples was measured by confocal microscopy. The corrosion properties of the ground and coated surfaces were determined by potentiodynamic polarization (PDP) within 1 h of exposure, and electrochemical impedance spectroscopy (EIS) was performed during 168 h of exposure at laboratory temperature. Consequently, the obtained results of the PDP measurements were evaluated by the Tafel analysis and the EIS evaluation was performed by the equivalent circuit analysis through Nyquist diagrams. The morphology and structure of PEO coatings were observed by scanning electron microscopy (SEM) through the secondary imaging technology, and the presence of certain elements in PEO coatings was analyzed by EDS analysis.

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Two aspects of various steels' weldability are considered in this article. The theoretical part presents general concepts related to steel's weldability and the application of the most important methods for its determination. In the experimental section, results of the hard-facing application to several samples are presented, and consist of hardness measurements in the different zones of the welded samples, with the evaluation of those zones' microstructures. The tested materials included two carbon steels and two alloyed steels, with hard-facing layers deposited by various filler metals. Experimental results were compared to results obtained by calculations; using both, authors were able to conclude which combination of filler metal, welding procedure and, if necessary, heat treatment, would achieve the optimal improvement of weldability in welding/hard-facing of each of the tested base metals.

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Numerous phenomena that occur during the process of machine parts' regeneration have a significant impact on the loss of their working ability. Therefore, the properties of the working surfaces of the teeth flanks of repaired gears were analyzed in this research. The hereditary properties of the gear teeth are expressed by the interdependence of their geometric and physical-mechanical-metallurgical parameters created during the technological operations of regeneration of worn teeth by welding/hard-facing. The hard-facing was executed with three filler metal types, namely: combination Inox 18/8/6 + EDur 600, Castolin 2 and UTP 670. The tested properties included geometrical accuracy, microstructure and microhardness. Evaluation of the executed regeneration procedures was done by comparing the mentioned parameters of the regenerated gears and the new ones. The tested gears were not withdrawn from production due to damage, but they were newly manufactured and intentionally damaged gears, made of the same materials, subjected to the same manufacturing process. In this way, all influences except for the considered filler metal type were eliminated. Based on results of the conducted experiments, it was possible to establish the influence of the filler metal type on the surface characteristics of the regenerated gears' teeth flanks.

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This paper presents the results of voluminous experimental investigations conducted to analyze the influence of the welding procedure on the performance of regenerated gears. Cylindrical spur gears were tested, both newly manufactured and regenerated, in two fundamentally different ways: by hard facing (surfacing) with the "hard" filler metal (DUR 600-IG) and with the "soft" filler metal (EVB2CrMo) with subsequent cementation and quenching. The regeneration procedures were defined and executed, while, subsequently, the microstructure and microhardness of the hard-faced layers were established and measured, followed by checking the durability of the hard-faced teeth flanks. Finally, techno-economic analysis was performed to establish the rationality of the conducted regenerations, i.e., the costs of regenerated and newly manufactured teeth were compared. Based on the results of the conducted investigations, it was possible to establish the influence of the welding type on the performance characteristics (primarily the service life) of the regenerated gears. For individual reparatory hard facing, the procedure with the "hard" filler metal exhibited better characteristics, while for batch reparation of numerous damaged gears, the reparation with the "soft" filler metal, followed by cementation and heat treatment, might be more convenient.

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Impact based surface treatments with adequate kinetic energy have favorable effects on promoting cell-substrate interactions, reducing bacterial adhesion, and enhancing fatigue performance of metallic biomaterials. Here, we used both numerical and experimental approaches to evaluate the potential of these treatments for addressing the major issue associated with the application of pure iron in biomedical implants, i.e. its low corrosion rate. Despite the efficiency of impact based surface treatments in modulating the degradation rate of pure iron, the maximum reported depth of the affected surface layer is still limited, even when extreme process parameters are used. To address this issue, herein, two impact based treatments were adjusted to trigger the dislocation activities that facilitate grain refinement in pure iron using multi-directional inclined impacts. An alternative approach of severe shot peening (SSP) was developed and compared with ultrasonic shot peening (USP). The effect of both treatments and variations of their key parameters were analyzed considering the significant role of shear bands and dislocation cells in the grain refinement mechanism of pure α-iron. Microstructural, mechanical and electrochemical properties of the treated material were analyzed. The observations showed extension of the grain refined layers for the specimens subjected to multidirectional oblique impacts compared to the ones treated in the classic manner using normal impacts. The results imply that by adapting peening parameters, it would be possible to effectively create a thick surface layer with properties that can accelerate the biodegradation of pure iron boosting its potential to meet clinical requirements for temporary hard tissue implants.

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To date, numerous investigations have shown the beneficial effect of ultrasonic vibration-assisted forming technology due to its influence on the forming load, flow stress, friction condition reduction and the increase of the metal forming limit. Although the immediate occurring force and mean stress reduction are known phenomena, the underlying effects of ultrasonic-based material softening remain an object of current research. Therefore, in this article, we investigate the effect of upsetting with and without the ultrasonic vibrations (USV) on the evolution of the microstructure, stress relaxation and hardness of the AlMg3 aluminum alloy. To understand the process physics, after the UAC (ultrasonic assisted compression), the microstructures of the samples were analyzed by light and electron microscopy, including the orientation imaging via electron backscatter diffraction. According to the test result, it is found that ultrasonic vibration can reduce flow stress during the ultrasonic-assisted compression (UAC) process for the investigated aluminum-magnesium alloy due to the acoustic softening effect. By comparing the microstructures of samples compressed with and without simultaneous application of ultrasonic vibrations, the enhanced shear banding and grain rotation were found to be responsible for grain refinement enhancement. The coupled action of the ultrasonic vibrations and plastic deformation decreased the grains of AlMg3 alloy from ~270 µm to ~1.52 µm, which has resulted in a hardness enhancement of UAC processed sample to about 117 HV.

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In the automotive industry, spot-welding is the most common method of joining components. Thus, determining the service life of spot-welds is of great importance in designing assemblies or structures. It is well-known that lately there has been a trend in the industry toward reducing the fuel consumption and harmful gasses emissions, as well as the weight of structures with the application of the lightweight materials, like aluminum alloys. In this paper, research is presented on the behavior of a spot-weld between the plates made of the two dissimilar materials-aluminum alloy and steel. In addition, the influence of the plates' thickness and the weld nugget's diameter on welds' service life is presented. In this analysis, a concept of the interface crack between the two linear elastic materials was applied. Obtained results show that the plates' thickness and the nugget's size, as well as the working load, impose significant influences on the service life of a spot-weld between the two dissimilar materials.

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Pure iron and its biocompatible and biodegradable alloys have a high potential to be used for temporary load bearing medical implants. Nevertheless, the formation of passive iron oxide and hydroxide layers, which lead to a considerably low degradation rate at the physiological environment, has highly restricted their application. Herein we used numerical and experimental methods to evaluate the effect of severe shot peening, as a scalable mechanical surface treatment, on adjusting the performance of pure iron for biomedical applications. The developed numerical model was used to identify the range of peening parameters that would promote grain refinement on the pure iron surface. Experimental tests were then performed to analyze the gradient structure and the characteristics of the interface free surface layer created on peened samples. The results indicated that severe shot peening could notably increase the surface roughness and wettability, induce remarkable surface deformation and grain refinement, enhance surface hardness and generate high in-depth compressive residual stresses. The increased surface roughness besides the high concentration of micro cracks and dislocation density in the grain refined top layer promoted pure iron's degradation in the biologically simulated environment. STATEMENT OF SIGNIFICANCE: Biodegradable metallic materials with resorbable degradation products have a high potential to be used for temporary implants such as screws, pins, staples, etc. They can eliminate the need for implant retrieval surgery after the damaged tissue is healed, and result in reduced patient suffering besides lowered hospitalization costs. Pure iron is biodegradable and is an essential nutrient in human body; however, its application as biomedical implant is highly restricted by its slow degradation rate in physiological environment. We applied a scalable surface treatment able to induce grain refinement and increase surface roughness. This treatment enhances mechanical performance of pure iron and accelerates its degradation rate, paving the way for its broader applications for biomedical implants.

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This paper reports on an investigation treating a hard-milled surface as a surface undergoing severe plastic deformation at elevated temperatures. This surface exhibits remarkable magnetic anisotropy (expressed in term of Barkhausen noise). This paper also shows that Barkhausen noise emission in a hard-milled surface is a function of tool wear and the corresponding microstructure transformations initiated in the tool/machined surface interface. The paper discusses the specific character of Barkhausen noise bursts and the unusually high magnitude of Barkhausen noise pulses, especially at a low degree of tool wear. The main causes can be seen in specific structures and the corresponding domain configurations formed during rapid cooling following surface heating. Domains are not randomly but preferentially oriented in the direction of the cutting speed. Barkhausen noise signals (measured in two perpendicular directions such as cutting speed and feed direction) indicate that the mechanism of Bloch wall motion during cyclic magnetization in hard-milled surfaces differs from surfaces produced by grinding cycles or the raw surface after heat treatment.

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Effect of processing by equal channel angular pressing (ECAP) on the degradation behaviour of extruded LAE442 magnesium alloy was investigated in a 0.1M NaCl solution, Kirkland's biocorrosion medium (KBM) and Minimum Essential Medium (MEM), both with and without 10% of foetal bovine serum (FBS). Uniform degradation of as extruded and ECAP processed samples in NaCl solution was observed, nevertheless higher corrosion resistance was found in the latter material. The increase of corrosion resistance due to ECAP was observed also after 14-days immersion in all media used. Higher compactness of the corrosion layer formed on the samples after ECAP was responsible for the observed decrease of corrosion resistance, which was proven by scanning electron microscope investigation. Lower corrosion rate in media with FBS was observed and was explained by additional effect of protein incorporation on the corrosion layer stability. A cytotoxicity test using L929 cells was carried out to investigate possible effect of processing on the cell viability. Sufficient cytocompatibility of the extruded samples was observed with no adverse effects of the subsequent ECAP processing. In conclusion, this in vitro study proved that the degradation behaviour of the LAE442 alloy could be improved by subsequent ECAP processing and this material is a good candidate for future in vivo investigation.

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Magnesium alloys are promising materials for biomedical applications because of many outstanding properties like biodegradation, bioactivity and their specific density and Young's modulus are closer to bone than the commonly used metallic implant materials. Unfortunately their fatigue properties and low corrosion resistance negatively influenced their application possibilities in the field of biomedicine. These problems could be diminished through appropriate surface treatments. This study evaluates the influence of a surface pre-treatment by shot peening and shot peening+coating on the corrosion properties of magnesium alloy AZ31. The dicalcium phosphate dihydrate coating (DCPD) was electrochemically deposited in a solution containing 0.1M Ca(NO3)2, 0.06M NH4H2PO4 and 10mL/L of H2O2. The effect of shot peening on the surface properties of magnesium alloy was evaluated by microhardness and surface roughness measurements. The influence of the shot peening and dicalcium phosphate dihydrate layer on the electrochemical characteristics of AZ31 magnesium alloy was evaluated by potentiodynamic measurements and electrochemical impedance spectroscopy in 0.9% NaCl solution at a temperature of 22±1°C. The obtained results were analyzed by the Tafel-extrapolation method and equivalent circuit method. The results showed that the application of shot peening process followed by DCPD coating improves the properties of the AZ31 surface from corrosion and mechanical point of view.

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Magnesium alloys suffer from their high reactivity in common environments. Protective layers are widely created on the surface of magnesium alloys to improve their corrosion resistance. This article evaluates the influence of a calcium-phosphate layer on the electrochemical characteristics of AZ31 magnesium alloy in 0.9 % NaCl solution. The calcium phosphate (CaP) layer was electrochemically deposited in a solution containing 0.1 M Ca(NO3)2, 0.06 M NH4H2PO4 and 10 ml l(-1) of H2O2. The formed surface layer was composed mainly of brushite [(dicalcium phosphate dihidrate (DCPD)] as proved by energy-dispersive X-ray analysis. The surface morphology was observed by scanning electron microscopy. Immersion test was performed in order to observe degradation of the calcium phosphatized surfaces. The influence of the phosphate layer on the electrochemical characteristics of AZ31, in 0.9 % NaCl solution, was evaluated by potentiodynamic measurements and electrochemical impedance spectroscopy. The obtained results were analysed by the Tafel-extrapolation method and equivalent circuits method. The results showed that the polarization resistance of the DCPD-coated surface is about 25 times higher than that of non-coated surface. The CaP electro-deposition process increased the activation energy of corrosion process.

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