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1.
Sci Rep ; 14(1): 13032, 2024 06 06.
Artículo en Inglés | MEDLINE | ID: mdl-38844676

RESUMEN

Green products such as plant tints are becoming more and more well-known worldwide due to their superior biological and ayurvedic properties. In this work, colorant from Amba Haldi (Curcuma aromatica) was isolated using microwave (MW), and bio-mordants were added to produce colorfast shades. Response surface methodology was used to develop a central composite design (CCD), which maximizes coloring variables statistically. The findings from 32 series of experiments show that excellent color depth (K/S = 12.595) was established onto MW-treated silk fabric (RS = 4 min) by employing 65 mL of radiated aqueous extract (RE = 4 min) of 5 pH cutting-edge the existence of 1.5 g/100 mL used sodium chloride at 75 °C for 45 min. It was discovered that acacia (keekar) extract (1%), pomegranate extract (2%), and pistachio extract (1.5%) were present before coloring by the use of bio-mordants. On the other hand, upon dyeing, acacia extract (1.5%), pomegranate extract (1.5%), and pistachio extract (2%) have all shown extremely strong colorfast colors. Comparatively, before dyeing, salts of Al3+ (1.5%), Fe2+ (2%), and TA (1.5%) gave good results; after dyeing, salts of Al3+ (1%) and Fe2+ (1.5%) and TA (2%) gave good results. When applied to silk fabric, MW radiation has increased the production of dyes recovered from rhizomes. Additionally, the right amount of chemical and biological mordants have been added, resulting in color fastness ratings ranging from outstanding to good. Therefore, the natural color extracted from Amba Haldi can be a sustainable option for the dyeing of silk fabric in the textile dyeing and finishing industries.


Asunto(s)
Colorantes , Curcuma , Extractos Vegetales , Rizoma , Seda , Curcuma/química , Rizoma/química , Colorantes/química , Extractos Vegetales/química , Seda/química , Microondas , Color , Tecnología Química Verde/métodos
2.
Sci Prog ; 106(3): 368504231188610, 2023.
Artículo en Inglés | MEDLINE | ID: mdl-37469182

RESUMEN

The purpose of this research is to evaluate the colouring performance of Amba Haldi-based natural extracted yellowish colour for the dyeing of wool fabric using ultrasonic (US) treatments. Before and after the US treatment, the colourant was separated in aqueous and acidic solutions for up to 60 min. Scanning electron microscopy and Fourier-transform infrared spectroscopy were used to investigate the surface morphology and chemical changes in the cloth before and after radiation. On the wool fabric that was ultrasonically treated at 75°C for 45 min, an acidic extract of Amba Haldi powder after US treatment for 20 min showed good colour depth (K/S). Acacia extract (2%), pomegranate extract (1.5%) and pistachio extract (1%), when used as pre-biomordants, were shown to have excellent colour strength. Acacia (1.5%) extract, pomegranate (2%) extract and pistachio (1.5%) extract were also used as post-biomordants. As pre-chemical mordants, Al salts (1%), Fe salts (1.5%) and tannic acid salts (2%), whereas Al salts (2%), Fe salts (1%) and tannic acid salts (2%), have produced successful results as post-chemical mordants. Overall, it was discovered that pomegranate extract (2%), used as a post-bio-mordant, and salt of Fe (1.5%), used as a post-chemical mordant, both exhibit exceptional colour strength. Ultrasonic treatment, a procedure that is harmless for the environment, has only served to increase the colour strength of dye on wool fabric, and the addition of bio-mordants has made the process more sustainable.

3.
Environ Sci Pollut Res Int ; 30(14): 42246-42254, 2023 Mar.
Artículo en Inglés | MEDLINE | ID: mdl-36645587

RESUMEN

During current times, the use of bio-colorants attained public acceptance as a sustainable alternative to synthetic ones which in turn reduced the environmental contamination. The present study focused on the green, safe, and clean technology for the resurgence of natural colorant from cocklebur (Xanthium strumarium L.) leaves and their application to cotton fabric. Natural colorants were extracted by employing an eco-friendly microwave-assisted extraction process using an aqueous and alkaline medium. Dyeing of cotton fabric was carried out using irradiated and unirradiated cotton fabric with irradiated and unirradiated natural dyes of cocklebur leaves. The results of extraction experiments revealed that 4 min microwave-assisted alkaline extract exhibited significantly outstanding color strength onto microwave-treated cotton fabric compared to aqueous one. Further to investigate the optimum dyeing conditions for cotton fabric, various dyeing variables such as dyeing time, dyeing temperature, dye concentration, and exhausting agent were monitored and found a superior result using a dye concentration of 45 ml, for dyeing cotton fabric at 75 °C for 50 min in the presence of 4 g/100 ml of table salt. For improvement in color strength and color fastness properties, the effects of various bio-mordants, such as eucalyptus bark, acacia bark, turmeric rhizome, and onion shells, and chemical mordants (aluminum and copper) on dyed cotton fabric were also evaluated. It was also observed that cotton fabric dyed with alkaline extract of cocklebur leaves using bio-mordants as pre-mordants (4% acacia, 4% eucalyptus, 2% onion) and post-mordants (3% onion, 3% eucalyptus, 4% acacia) exhibited the highest color strength and various hues with acceptable colorfastness properties against light, washing, and rubbing in comparison to chemical mordants. The ISO standard for fastness also revealed that bio-mordanting has enhanced the rating from good to excellent in comparison to chemical mordants. The results provide ample scope for the extraction of yellow natural dye from the cocklebur leaves for eco-friendly coloration of fabrics using bio-mordants.


Asunto(s)
Colorantes , Xanthium , Colorantes/química , Microondas , Hojas de la Planta , Extractos Vegetales
4.
Environ Sci Pollut Res Int ; 30(5): 12453-12465, 2023 Jan.
Artículo en Inglés | MEDLINE | ID: mdl-36112291

RESUMEN

The world's move towards revival of eco-labelled products has created a huge urge to explore new means which are healthier for the global community. Among such means, plant-based bio-pigments for coloration of matrix are gaining worldwide fame, particularly in the textile sector. For the purpose of appraising new source of eco-friendly dyes, using microwave irradiation techniques, Coral Jasmine flowers have been explored for the bio-dyeing of wool. The colorant was extracted in acidic medium owing to nature of fabric, and both stuffs have been exposed to microwave treatment up to 5 min. Bio-coloration of MW irradiated and unirradiated wool was done using MW irradiated and unirradiated extract for observing high yield. Central composite design (CCD) as statistical method was utilized to see the significance of dyeing parameters chosen for mordanting to develop colorfast shades. Different concentrations of sustainable chemicals and bio-mordants as per weight of fabric were employed to introduce new shades with improved colorfastness properties. International standard textile methods determining shade permanency (fastness) have been employed onto selected dyed-mordanted fabrics. Good yield of colorant was observed when MW irradiated wool fabric was dyed at 75 °C for 45 min with extract of 7 pH, having 1.5g/100 mL of salt solution; the promising color yield was observed. As per gray scale ratings observed after ISO standard methods, pine nut as bio-mordant and iron salt as chemical mordant have developed colorfast shades. Conclusively, it can be recommended that methods for the isolation of colorants from new dye yielding plants, MW heating method as suitable clean technology and medicinal-based bio-mordants should be employed for getting permanent gamutes.


Asunto(s)
Jasminum , Lana , Animales , Lana/química , Colorantes/química , Flores , Extractos Vegetales/química
5.
Environ Sci Pollut Res Int ; 30(2): 4570-4581, 2023 Jan.
Artículo en Inglés | MEDLINE | ID: mdl-35972657

RESUMEN

The current study has been designed to observe the coloring efficacy of wild turmeric-based natural yellowish colorant for wool dyeing under microwave (MW) treatments. Extracts and fabrics have been exposed to MW treatment for up to 10 min. Surface morphology and changes in the fabric's chemical nature before and after radiation have been studied through SEM and FTIR, respectively. The results obtained after a series of experiments show that using 45 mL of aqueous extract (pH = 5) in the presence of 1.5g/100mL of table salt as an exhausting agent at 75°C for 45 min has displayed outstanding color depth (K/S) onto microwave-treated wool fabric. On applying biomordants, it has been found that acacia extract (1.5%), pomegranate (2%), and pistachio extracts (1.5%) before dyeing, whereas acacia (1%), pomegranate (1%), and pistachio extracts (2%) after dyeing, have shown colorfast shades of high strength. Comparatively, salts of Al (1.5%) and Fe (1%), and T.A (2%) before dyeing, while salts of Al (1%) and Fe (1.5%) and T.A (1.5%) after dyeing, have given the best results. Generally, it has been originated that salt of Fe (1.5%) as a post-chemical mordant and pomegranate extract (1.5%) as a post-bio-mordant have displayed wonderful color strength. It very well may be inferred that MW treatment, being naturally protected, has just superior the varying strength of colorants on wool fabric. Adding biomordants has transformed the strategy into a more sustainable one.


Asunto(s)
Colorantes , Curcumina , Animales , Curcuma , Fibra de Lana , Sales (Química) , Lana
6.
Environ Sci Pollut Res Int ; 29(23): 35048-35060, 2022 May.
Artículo en Inglés | MEDLINE | ID: mdl-35044603

RESUMEN

The present study aims to extract a natural reddish brown colorant from Peepal (Ficus religiosa) for silk dyeing using the microwave radiation process (MW). The colorant was isolated in aqueous and acidic media, and MW treatment for 1, 2, 3, 4, and 5 min has been given to both fabric and extract to observe changes in color intensity. The dye variables have been optimized, and for sustainable shade making process with good fastness, 1.0-5.0 g/100 mL of sustainable chemical and bio-mordants has been employed. It has been found that after microwave treatment for 3 min, under selected conditions, the irradiated aqueous extract has given high color intensity onto silk fabric. The utilization of 3% of Al, 4% of Fe, and 2% of tannic acid (T.A.) as pre chemical mordant whereas 4% of Al, 4% of Fe, and 3% of tannic acid as post chemical mordant have given good color characteristics. In comparison, 4% of acacia and 3% of turmeric and pomegranate while 3% of acacia and turmeric and 4% of pomegranate extracts as post-bio-mordant have given excellent color characteristics. It is concluded that MW treatment has an excellent sustainable efficacy to isolate colorant from Peepal bark for silk dyeing, whereas the inclusion of bio-mordants has not only made the process more sustainable and environmental friendly but also best K/S, and L*a*b* values have been acquired.


Asunto(s)
Ficus , Seda , Benzopiranos , Colorantes , Corteza de la Planta , Taninos , Textiles
7.
Environ Sci Pollut Res Int ; 29(9): 13523-13533, 2022 Feb.
Artículo en Inglés | MEDLINE | ID: mdl-34595716

RESUMEN

Sustainability in all applied fields particularly in textiles is to protect our globe, environment, and community, where green dyed products are playing their role. For the current study, Esfand (Peganum harmala) has been explored using a green isolation tool, i.e., ultrasonic (U.S.) rays, and applied onto fabric. Different dyeing parameters have been explored statistically through response surface methodology by employing temperature (50-80°C), time (25-65 min), extract volume (15-55 mL), salt (1-5 g/100 mL), and dye bath pH (4-7) through series of experiments. For developing new shades, green mordants such as elaichi, neem, turmeric, and zeera have been utilized. It has been found that exposure of 35 mL extract of 7 pH containing 3 g/100 mL of salt as exhausting agent to U.S. rays for 30 min for the dyeing of silk at 70°C for 45 min has given maximum color strength with reddish-yellow shades. Color characteristics obtained in the CIE Lab system reveal that 5% of turmeric as meta bio-mordant has given good quality reddish-yellow shades. It is found that U.S. rays have not only good potential to isolate colorant followed by dyeing of silk under reduced condition but also the application of bio-mordants have made the process more greener, sustainable, and cleaner.


Asunto(s)
Azadirachta , Peganum , Colorantes , Seda , Textiles
8.
Environ Sci Pollut Res Int ; 29(1): 564-572, 2022 Jan.
Artículo en Inglés | MEDLINE | ID: mdl-34331230

RESUMEN

The worldwide resurgence of natural dyes in all fields is due to the carcinogenic effects of effluent loads shed by synthetic industries. Coconut coir (Cocos nucifera) containing tannin as a source of natural colorants has been selected for coloration of bio-mordanted silk under the influence of ultrasonic radiations at various dyeing conditions. For extraction of tannin dye from cocos powder, different media were employed, and dyeing variables such as dyeing time, dye bath pH, dyeing bath temperature, and the effect of salts on dyeing were optimized. For achieving new shades with excellent color characteristics, bio-mordants in comparison with chemical mordants were employed. It has been found that acid-solubilized extract after ultrasonic treatment for 45 min has yielded high color strength, when coconut coir extract of 4 pH from 6g of cocos powder, containing 5g/100mL salt solution as exhaust agent, was used to dye silk at 75°C for 65 min. Among bio-mordants turmeric (K/S=13.828) and among chemical mordants iron has shown excellent results (K/S=2.0856). Physiochemical analysis of fabric before and after US treatment shows that there is no change in the chemical structure of the fabric. It is found that ultrasonic waves have excellent potential to isolate the colorant followed by dyeing and environmental friendly mordanting at optimal conditions, but also the usage of herbal-based plant anchors, i.e., bio-mordants, has made the natural dyeing process more sustainable and clean.


Asunto(s)
Colorantes , Seda , Cocos , Lignina/análogos & derivados , Extractos Vegetales
9.
Environ Sci Pollut Res Int ; 28(38): 54041-54047, 2021 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-34043165

RESUMEN

Ecofriendly exploration of Arjun bark (Terminalia arjuna) is a herbal natural colorant for cotton dyeing. This is because the demand for natural dyes has been increased worldwide due to their therapeutic usage and other food, textiles, agriculture, engineering, and medical applications. Therefore, this study has been carried out due to the isolation of colorant from Arjun bark in an acidified methanolic medium after exposure to ultrasonic rays up to 60 min. Additionally, using bio-mordants, it has been found that the application of 10% of Zeera (Cuminum cyminum) extract as meta-bio-mordant, 3% of Ilaichi (Elettaria cardamomum) extract as meta-bio-mordant, and10 % of Harmal (Peganum harmala) and Neem (Azadirachta indica) extract as meta-bio-mordants has given excellent color strength. These bio-mordants have not only made the coloration process more eco-friendly, viable, and greener, but also improved color strength with various tonal effects from red to reddish brown shades. Thus, it has been found that ultrasonic treatment as an environment-friendly tool has not only enhanced the color strength of natural colorant isolated from Arjun bark onto the cotton fabric under mild conditions.


Asunto(s)
Azadirachta , Peganum , Colorantes , Corteza de la Planta , Textiles
10.
Plants (Basel) ; 9(2)2020 Feb 22.
Artículo en Inglés | MEDLINE | ID: mdl-32098385

RESUMEN

The present experiment was carried out to study the influences of exogenously-applied nitric oxide (NO) donor sodium nitroprusside (SNP) and hydrogen peroxide (H2O2) as seed primers on growth and yield in relation with different physio-biochemical parameters, antioxidant activities, and osmolyte accumulation in wheat plants grown under control (100% field capacity) and water stress (60% field capacity) conditions. During soaking, the seeds were covered and kept in completely dark. Drought stress markedly reduced the plant growth, grain yield, leaf photosynthetic pigments, total phenolic content (TPC), total soluble proteins (TSP), leaf water potential (Ψw), leaf turgor potential (Ψp), osmotic potential (Ψs), and leaf relative water content (LRWC), while it increased the activities of enzymatic antioxidants and the accumulation of leaf ascorbic acid (AsA), proline (Pro), glycine betaine (GB), malondialdehyde (MDA), and H2O2. However, seed priming with SNP and H2O2 alone and in combination mitigated the deleterious effects of water stress on growth and yield by improving the Ψw, Ψs, Ψp, photosynthetic pigments, osmolytes accumulation (GB and Pro), TSP, and the antioxidative defense mechanism. Furthermore, the application of NO and H2O2 as seed primers also reduced the accumulation of H2O2 and MDA contents. The effectiveness was treatment-specific and the combined application was also found to be effective. The results revealed that exogenous application of NO and H2O2 was effective in increasing the tolerance of wheat plants under drought stress in terms of growth and grain yield by regulating plant-water relations, the antioxidative defense mechanism, and accumulation of osmolytes, and by reducing the membrane lipid peroxidation.

11.
Environ Sci Pollut Res Int ; 26(33): 34633-34644, 2019 Nov.
Artículo en Inglés | MEDLINE | ID: mdl-31654306

RESUMEN

Lead (Pb) is highly toxic to plants because it severely affects physiological processes by altering nutrient solution pH. The current study elucidated Pb-induced changes in nutrient solution pH and its effect on physiology of two Solanum melongena L. cultivars (cv. Chuttu and cv. VRIB-13). Plants were grown in black plastic containers having 0, 15, 20, and 25 mg L-1 PbCl2 in nutrient solutions with starting pH of 6.0. pH changes by roots of S. melongena were continuously monitored for 8 days, and harvested plants were analyzed for physiological and biochemical attributes. Time scale studies revealed that cv. Chuttu and cv. VRIB-13 responded to Pb stress by causing acidification and alkalinization of growth medium during the first 48 h, respectively. Both cultivars increased nutrient solution pH, and maximum pH rise of 1.21 units was culminated by cv. VRIB-13 at 15 mg L-1 Pb and 0.8 units by cv. Chuttu at 25 mg L-1 Pb treatment during the 8-day period. Plant biomass, photosynthetic pigments, ascorbic acid, total amino acid, and total protein contents were significantly reduced by Pb stress predominantly in cv. Chuttu than cv. VRIB-13. Interestingly, chlorophyll contents of cv. VRIB-13 increased with increasing Pb levels. Pb contents of roots and shoots of both cultivars increased with applied Pb levels while nutrient (Ca, Mg, K, and Fe) contents decreased predominately in cv. Chuttu. Negative correlations were identified among Pb contents of eggplant roots and shoots and plant biomasses, leaf area, and free anthocyanin. Taken together, growth medium alkalinization, lower root to shoot Pb translocation, and optimum balance of nutrients (Mg and Fe) conferred growth enhancement, ultimately making cv. VRIB-13 auspicious for tolerating Pb toxicity as compared with cv. Chuttu. The research outcomes are important for devising metallicolous plant-associated strategies based on plant pH modulation response and associated metal uptake to remediate Pb-polluted soil.


Asunto(s)
Plomo/toxicidad , Contaminantes del Suelo/toxicidad , Solanum melongena/fisiología , Transporte Biológico/efectos de los fármacos , Biomasa , Contaminación Ambiental , Homeostasis , Concentración de Iones de Hidrógeno , Plomo/metabolismo , Nutrientes , Hojas de la Planta/metabolismo , Fenómenos Fisiológicos de las Plantas , Raíces de Plantas/metabolismo , Contaminantes del Suelo/metabolismo , Solanum melongena/efectos de los fármacos
12.
Environ Sci Pollut Res Int ; 25(3): 2958-2971, 2018 Jan.
Artículo en Inglés | MEDLINE | ID: mdl-29147985

RESUMEN

Lead (Pb) stress adversely affects in planta nutrient homeostasis and metabolism when present at elevated concentration in the surrounding media. The present study was aimed at investigation of organic acid exudations, elemental contents, growth, and lipid peroxidation in two wild plants (Amaranthus viridis L. and Portulaca oleracea L.), exhibiting differential root to shoot Pb translocation, under Pb stress. Plants were placed in soil spiked with lead chloride (PbCl2) concentrations of 0, 15, 30, 45, or 60 mg Pb/kg soil, in rhizoboxes supplied with nylon nets around the roots. The plant mucilage taken from root surfaces, mirroring the rhizospheric solution, was analyzed for various organic acids. Lead stress resulted in a release of basified root exudates from both plants. Exudates of P. oleracea roots showed a higher pH. In both plants, the pH rising effect was diminished at the highest Pb treatment level. The exudation of citric acid, glutamic acid (in both plants), and fumaric acid (in P. oleracea only) was significantly increased with applied Pb levels. In both plant species, root and shoot Pb contents increased while nutrients (Ca, Mg, and K) decreased with increasing Pb treatment levels, predominantly in A. viridis. At 60 mg Pb/kg soil, shoot Na content of A. viridis was significantly higher as compared to untreated control. Higher Pb treatment levels decreased plant fresh and dry masses as well as the quantity of photosynthetic pigments due to enhanced levels of plant H2O2 and thiobarbituric acid reactive substances in both species. Photosynthetic, growth, and oxidative stress parameters were grouped into three distinct dendrogram sections depending on their similarities under Pb stress. A positive correlation was identified between Pb contents of studied plants and secretion of different organic acids. It is concluded that Pb stress significantly impaired the growth of A. viridis and P. oleracea as a result of nutritional ion imbalance, and the response was cultivar-specific and dependent on exogenous applied Pb levels. Differential lipid oxidation, uptake of nutrients (Ca, Mg, and K) and exudation of citric acid, fumaric acid, and glutamic acid could serve as suitable physiological indicators for adaptations of P. oleracea to Pb enriched environment. The findings may help in devising strategies for Pb stabilization to soil colloids.


Asunto(s)
Amaranthus/efectos de los fármacos , Ácidos Carboxílicos/metabolismo , Homeostasis/efectos de los fármacos , Plomo/toxicidad , Exudados de Plantas/metabolismo , Portulaca/efectos de los fármacos , Contaminantes del Suelo/toxicidad , Amaranthus/crecimiento & desarrollo , Transporte Biológico , Relación Dosis-Respuesta a Droga , Plomo/metabolismo , Modelos Teóricos , Estrés Oxidativo/efectos de los fármacos , Portulaca/crecimiento & desarrollo , Contaminantes del Suelo/metabolismo
13.
J Exp Bot ; 66(1): 37-46, 2015 Jan.
Artículo en Inglés | MEDLINE | ID: mdl-25294918

RESUMEN

The hydroxyl radical (OH(•)) is the most potent yet short-lived of the reactive oxygen species (ROS) radicals. Just as hydrogen peroxide was once considered to be simply a deleterious by-product of oxidative metabolism but is now acknowledged to have signalling roles in plant cells, so evidence is mounting for the hydroxyl radical as being more than merely an agent of destruction. Its oxidative power is harnessed to facilitate germination, growth, stomatal closure, reproduction, the immune response, and adaptation to stress. It features in plant cell death and is a key tool in microbial degradation of plant matter for recycling. Production of the hydroxyl radical in the wall, at the plasma membrane, and intracellularly is facilitated by a range of peroxidases, superoxide dismutases, NADPH oxidases, and transition metal catalysts. The spatio-temporal activity of these must be tightly regulated to target substrates precisely to the site of radical production, both to prevent damage and to accommodate the short half life and diffusive capacity of the hydroxyl radical. Whilst research has focussed mainly on the hydroxyl radical's mode of action in wall loosening, studies now extend to elucidating which proteins are targets in signalling systems. Despite the difficulties in detecting and manipulating this ROS, there is sufficient evidence now to acknowledge the hydroxyl radical as a potent regulator in plant cell biology.


Asunto(s)
Radical Hidroxilo/metabolismo , Fenómenos Fisiológicos de las Plantas , Semillas/metabolismo
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