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Mater Sci Eng C Mater Biol Appl ; 70(Pt 1): 628-636, 2017 Jan 01.
Artículo en Inglés | MEDLINE | ID: mdl-27770936

RESUMEN

In this paper, FeS nanoparticles anchored on reduced graphene oxide (rGO) nanosheets are synthesized via a facile direct-precipitation method. For the first time, a novel electrochemical sensor is developed based on FeS/rGO nanosheets modified glassy carbon electrode (GCE). It has been proved that the resultant FeS/rGO/GCE sensor is very suitable for the individual and simultaneous measurement of dopamine (DA) and acetaminophen (AC) and delivers excellent anti-interference ability to ascorbic acid (AA) and uric acid (UA). Under optimum conditions with differential pulse voltammetry method, a broad linear response versus the concentrations of DA and AC has been observed in the ranges of 2.0 to 250.0µM and 5.0 to 300.0µM, respectively. The detection limits for DA and AC are 0.098µM and 0.18µM, respectively. Furthermore, the as-obtained sensor has been successfully utilized in real samples and satisfactory results have been achieved. Consequently, by virtue of its outstanding electrocatalytic activity, excellent sensitivity, and long time stability, the as-obtained FeS/rGO modified electrode can be considered as a new promising DA and AC sensor.


Asunto(s)
Acetaminofén/sangre , Dopamina/sangre , Técnicas Electroquímicas/métodos , Grafito/química , Nanocompuestos/química , Tampones (Química) , Catálisis , Electrodos , Compuestos Ferrosos/química , Vidrio/química , Humanos , Concentración de Iones de Hidrógeno , Nanocompuestos/ultraestructura , Oxidación-Reducción , Estándares de Referencia , Soluciones
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