RESUMEN

Agallochaexcoerin A (1), a seco-manoyl oxide diterpenoid was metabolised by pathogenic fungus, Aspergillus flavus, in growth media to yield a new metabolite, termed agallochaexcoerin G (2). It was confirmed by using IR, UV, (1)H NMR and HR-ESI-MS techniques. This microbial bioconversion was achieved by unusual dehydration at C-4 position.

Asunto(s)

Aspergillus flavus/metabolismo , Diterpenos/metabolismo , Biotransformación , Diterpenos/química , Estructura Molecular