1.
Chem Commun (Camb)
; 60(54): 6929-6932, 2024 Jul 02.
Artículo
en Inglés
| MEDLINE
| ID: mdl-38884327
RESUMEN
We demonstrate (1) detectable halogen bonding is not critical for enabling light-driven radical generation from diaryliodonium salts and (2) radicals generated by this route can be captured by transition-metals for C-H arylation reactions. These results are the first step toward developing new metal-catalyzed aryl radical couplings without exogenous photocatalysts.