RESUMEN
Transition metal chalcogenides (TMX) have attracted energy researchers due to their role as high-performance electrode materials for energy storage devices. A facile one-pot hydrothermal technique was adopted to synthesize a molybdenum disulfide/cadmium sulfide (MoS2/CdS) (MCS) composite. The as-prepared samples were subjected to characterization techniques such as XRD, FT-IR, SEM, TEM, and XPS to assess their structure, morphology, and oxidation states. The MoS2/CdS (MCS) composites were prepared in three different ratios of molybdenum and cadmium metals. Among them, the MCS 1:2 (Mo:Cd) ratio showed better electrochemical performance with a high specific capacitance of 1336 F g-1 (high specific capacity of 185.83 mAh g-1) at a specific current of 1 A g-1 for half-cell studies. Later, a hybrid supercapacitor (HSC) device was fabricated with N-doped graphene (NG) as an anode and MCS (1:2) as a cathode, delivering a high specific energy of 34 Wh kg-1 and a specific power of 7500 W kg-1. The high nitrogen content in the MoS2 structure in MCS composites alters the device's performance, where CdS supports the composite structure through its conductivity and encourages the easy accessibility of ions. The device withstands up to 10 000 cycles with a higher Coulombic efficiency of 97% and a capacitance retention of 90.25%. The high-performance NG//MCS (1:2) HSC may be a potential candidate alternative to the existing conventional material.
RESUMEN
NiSe and NG-NiSe (triethanolamine functionalized and NiSe embedded rGO), as electrode materials for supercapacitor application, were prepared by a hydrothermal technique. XRD confirmed the formation of pure NiSe and NG-NiSe nanocomposites, which showed a hexagonal crystalline structure of NiSe. The structural morphology and particle size of NiSe and NG-NiSe were measured using FESEM and HRTEM analysis, respectively. The oxidation states and elemental compositions of NG-NiSe were investigated by XPS. The electrochemical behaviours of the materials were studied using CV, GCD, and EIS spectra. NG-NiSe showed higher capacitance performance compared to pure NiSe, due to the synergetic effects on the rGO/TEA/NiSe nanocomposite during one-pot synthesis. The energy density and power density of a N-rGO//NG-NiSe asymmetric cell were 28.25 W h kg-1 and 700 W kg-1, respectively.