RESUMEN

"Man-made" or unconventional freshwater, like desalinated seawater or reclaimed effluents, is increasingly introduced into regional water cycles in arid or semi-arid countries. We show that the breakthrough of reverse osmosis-derived freshwater in the largely engineered water cycle of the greater Tel Aviv region (Dan Region) has profoundly changed previous isotope fingerprints. This new component can be traced throughout the system, from the drinking water supply, through sewage, treated effluents, and artificially recharged groundwater at the largest Soil-Aquifer Treatment system in the Middle East (Shafdan) collecting all the Dan region sewage. The arrival of the new water type (desalinated seawater) in 2007 and its predominance since 2010 constitutes an unplanned, large-scale, long-term tracer test and the monitoring of the breakthrough of desalination-specific fingerprints in the aquifer system of Shafdan allowed to get new insights on the water and solute flow and behavior in engineered groundwater systems. Our approach provides an investigation tool for the urban water cycle, allowing estimating the contribution of diverse freshwater sources, and an environmental tracing method for better constraining the long-term behavior and confinement of aquifer systems with managed recharge.

RESUMEN

The identification of the sources of contaminants present in groundwater at industrial sites is primordial to address environmental and industrial issues. However, available tools are often inadequate or expensive. Here, we present the data of stable isotopes (δ18O and δ2H) of the water molecule at an industrial site where electrochemistry plant occurs impacting the groundwater quality. High ClO3 and ClO4 contents and 2H enrichment have been measured in groundwater. Recharge of aquifer relates to infiltration of rainwater and by subsurface inflow. On-site, industrial products are generated by electrolysis. We show that the electrolysis process leads to a large 2H enrichment (+425‰) in solutions. In the absence of hydrothermal water input containing H2S, we demonstrate that the relationship between δ18O and δ2H can be easily used in a way to trace the origin of the ClO3 and ClO4 in groundwater. Isotopes evidenced first a leakage from end-product storage tanks or during the production process itself. Then, an accumulation and release of ClO3 and ClO4 from soil is demonstrated. Our study successfully shows that stable isotopes are a powerful and low cost tool for tracing pollutant plumes in an industrial context using electrolysis process.

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RESUMEN

The Roussillon sedimentary Basin (South France) is a complex multi-layered aquifer, close to the Mediterranean Sea facing seasonally increases of water abstraction and salinization issues. We report geochemical and isotopic vertical variability in this aquifer using groundwater sampled with a Westbay System® at two coastal monitoring sites: Barcarès and Canet. The Westbay sampling allows pointing out and explaining the variation of water quality along vertical profiles, both in productive layers and in the less permeable ones where most of the chemical processes are susceptible to take place. The aquifer layers are not equally impacted by salinization, with electrical conductivity ranging from 460 to 43,000µS·cm(-1). The δ(2)H-δ(18)O signatures show mixing between seawater and freshwater components with long water residence time as evidenced by the lack of contribution from modern water using (3)H, (14)C and CFCs/SF6. S(SO4) isotopes also evidence seawater contribution but some signatures can be related to oxidation of pyrite and/or organically bounded S. In the upper layers (87)Sr/(86)Sr ratios are close to that of seawater and then increase with depth, reflecting water-rock interaction with argillaceous formations while punctual low values reflect interaction with carbonate. Boron isotopes highlight secondary processes such as adsorption/desorption onto clays in addition to mixings. At the Barcarès site (120m deep), the high salinity in some layers appear to be related neither to present day seawater intrusion, nor to Salses-Leucate lagoonwater intrusion. Groundwater chemical composition thus highlights binary mixing between fresh groundwater and inherited salty water together with cation exchange processes, water-rock interactions and, locally, sedimentary organic matter mineralisation probably enhanced by pyrite oxidation. Finally, combining the results of this study and those of Caballero and Ladouche (2015), we discuss the possible future evolution of this aquifer system under global change, as well as the potential management strategies needed to preserve quantitatively and qualitatively this water resource.