1.
J Environ Sci (China)
; 27: 87-96, 2015 Jan 01.
Artículo
en Inglés
| MEDLINE
| ID: mdl-25597666
RESUMEN
The catalytic activity of Pd catalysts supported on Ce0.73Tb0.27Ox/SiO2, Ce0.6Zr0.4Ox/SiO2, Ce0.73Tb0.27Ox/La2O3-Al2O3 and Ce0.6Zr0.4Ox/La2O3-Al2O3 was studied using the reduction of NO by CO. The catalysts were characterized by X-ray fluorescence, surface area, X-ray diffraction, temperature-programmed reduction, CO chemisorption and oxygen storage capacity. Temperature-programmed reduction results indicated that Tb or Zr incorporation improves the reducibility and oxygen storage capacity. CO chemisorption data suggested the presence of large PdO particles due to the low CO/Pd ratio. No significant differences were obtained in light off temperatures (TLight off) for all Pd catalysts and the most active was 1.5%Pd/Ce0.6Zr0.4Ox/SiO2.