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The improper application of pesticides in cultivating vegetables has resulted in the buildup of pesticide residues on vegetables. This study evaluated organophosphate pesticide residue levels in cabbage with specific objectives of investigating the varieties of organophosphate pesticides employed by farmers and their awareness, assessing residue levels on cabbage using semi-structured questionnaires, and determining the distribution of pesticide residues within the layers of the cabbage head using 50 cabbage samples randomly collected from farmers from 14 cabbage-producing communities. The findings indicated that 98 % of the farmers applied pesticides in the morning, whereas 24 % preferred evening application. Meanwhile, 22 % applied pesticides twice in a day. Also, 18 % combined pesticides, 40 % applied 20 ml during the application, 72 % chose a particular pesticide based on the expected efficiency, 46 % applied pesticides between 1 and 5 times in a season and 66 % sprayed between 7 and 14 days. Pyrinex 48 EC and Perferthion emerged as the predominant organophosphates, with usage rates of 10 % and 12 % respectively. Also, eleven (11) organophosphate pesticide residues were identified in the cabbage samples. Profenofos and chlorpyrifos exhibited the highest concentrations of pesticide residues, with levels reaching 0.02 mg/kg, with 56.6 % of the samples containing chlorpyrifos pesticide residue. Nevertheless, all the identified pesticide residues did not exceed the maximum residue limits for cabbage. The study analysis disclosed the presence of various organophosphate pesticide residues in the first 10 layers of cabbage. However, it was noted that the innermost layers might not contain any detectable pesticide residues. The findings highlight the need for farmers to use pesticides judiciously and follow recommended application practices to minimize vegetable residues.

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Different sound levels are encountered by pastors, ministers, and the whole congregation during church services, which may extend for hours, and also by people living close to these churches. This can have an adverse effect on their health. The maximum allowable noise level in worship places is 65 dB (A), according to the Ghana Standards Authority (GSA). The aim of the study was to quantify the noise pollution levels of the churches in Kpone Katamanso Municipal Assembly (KKMA) and assess the equivalent noise levels of the churches' indoor and outdoor spaces. This investigation is being conducted due to the high number of churches and the noise emanating from these churches in the Kpone Katamanso Municipality and the possible impact on human health. Thirty churches were chosen at random for the study; on Sundays between the hours of 7.30 and 12.0 pm, sound levels in churches were measured using a portable General Class 1 Meter type DSM403SD with a data logging system. MS Excel was used to evaluate the data and determine characteristics including noise exposure levels (NEL), background noise level (L 90), severe noise level (L 10), and equivalent noise level (L eq). The indoor equivalent noise level ranges from 74.5 dB (A) to 104.1 dB (A), and the outdoor equivalent noise level ranges from 52.6 dB (A) to 85.3 dB (A). All of the noise levels found indoors of the churches were greater than the 65 dB (A) safe allowable limit, putting the congregants and residents at risk for a variety of physiological and psychological problems.

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Fish is an excellent source of low-fat protein. Fish contains a lot of omega-3 fatty acids, as well as vitamins D and B2 (riboflavin). The daily consumption of contaminated food, especially fish, is among the primary cause of heavy metals pollution to human health. The aim of the research was to determine the concentration of heavy metals in selected species of fish from the Gulf of Guinea at James Town in Ghana. In tandem with the study's objective, samples of different forms of fish, Cassava fish, Flatfish, Redfish, Kingfish, and Silverfish, and sediment were obtained and analyzed for the presence of heavy metals using atomic absorption spectrometer (PerkinElmer®, PinAAcle 900T). The analysis indicated a high concentration of Pb, Cd, and Cr concentrations in fish gills, muscles, and sediment. High lead concentration in Silverfish gills (5.9 mg/kg) and Flatfish gills (2.29 mg/kg) above WHO levels. Cadmium was found in all fish species and sediment except Kingfish. Chromium concentrations were high n Cassava fish (3.10 mg/kg) and Silverfish (4.01 mg/kg) and copper concentrations were absent in the fish species. Arsenic and mercury were also not detected in all fish species and sediment. Manganese concentrations were found in fish and sediment. High cadmium target hazard quotient (0.17-11.60 for adults and 0.24 to 16.24 for children) and cancer risk (0.00-0.04) values in fish samples indicated potential health concerns. The Hazard Index (HI) for the analyzed samples ranged from 0.00 to 12.48 for adults and 0.00 to 17.47 for children. The study suggests that eliminating pollution and other sources of waterbody pollution is crucial to protecting the marine environment and the health of seafood consumers.

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Anthropogenic factors such as leakages from fuel storage facilities contribute to the release of petroleum hydrocarbons into groundwater. Following the proliferation of fuel stations in residential areas, this research assessed physicochemical parameters, salinity, and levels of total petroleum hydrocarbons (TPH) in groundwater sources within selected residential areas. From the study, mean values of temperature (30.5 °C), pH (5.8), EC (181.5 µs/cm), TDS (90.7 mg/L), and salinity (0.1 ppm) were recorded. The highest mean concentration of TPH (9.5 mg/L) was recorded at location A, while three sampling points (J, L, and M) exhibited 0.0 mg/L. Notably, TPH concentrations exceeding permissible limits were observed at three sampling points (A, B, and R). Strong positive correlations were observed between EC and TDS (r = 0.9), as well as salinity and EC (r = 0.9) and TDS (r = 0.9). Matrix plots demonstrated non-linear relationships, except for TDS and EC, although TPH and temperature exhibited a slightly linear pattern. The distance from USTs to the groundwater sources varied in the area. At location H, this distance (25 m) was measured as the shortest, where the mean TPH concentration was 3.71 mg/L. However, site Q exhibited the longest distance of 535 m, accompanied by a mean TPH concentration of 1.1 mg/L. Though the proximity of USTs to groundwater sources exerted some level of influence on the groundwater system, multiple linear regression, ANOVA, and cluster analysis showed that this did not pose direct and major impacts on the concentrations of TPH. However, approaches are needed to remediate the affected groundwater sources.

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The surge in mining operations to meet the global demand for mineral resources adversely impacts ecosystem services and dependent households, but the issue barely attracts attention. This study evaluated the dynamics of mining-induced changes in the value of ecosystem services (ES) and the consequent economic and relational cost to rural households in the Ahafo region of Ghana. Face-to-face structured interviews with 200 householders were conducted in three mining communities. We determined relational values in the landscape through focus group discussion and the economic cost of the ecosystem services lost by applying replacement and contingency cost estimations. Old-growth forests, degraded forests, teak plantations, cultivated land, wetlands, and grassland were ecosystems identified in the mining landscape. The most valued ecosystem was old-growth forest, while the least was grassland. Provisioning service was the most valued ES, while supporting service was the least. Provisioning ES was rated the most impacted by the mine, whereas cultural services were the least affected. Mining activities caused a significant loss of 14 ecosystem services (including crops, livestock, capture fisheries, wild food, bush meat, biomass fuel, and freshwater) that were of priority to the communities. The affected households experienced relatively high monthly economic costs, approximating $300 per household, from the loss of priority ecosystem services. Canonical correspondence analysis revealed connections between ecosystem services valuation and the socio-demographic characteristics of the respondents. There was a perceived mine-adverse effect on the relational values of the people relating to cultural identity, sovereignty, symbolic value, security, subsistence and livelihood, sense of place, social cohesion, social memory, female emotional/mental health, and womanhood training opportunities. Actors in the mining industry should consider policies and management interventions that will limit ecosystem services loss, widely ascertain ecosystem benefits, and comprehensively mitigate the impact of their loss on households.

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The extensive use of face masks has raised concerns about environmental pollution through improper disposal of used face masks after the emergence of COVID-19. The increasing use of PPEs to preventing the spread of COVID-19 has resulted in several environmental hazards, creating a new environmental barrier for solid waste management and worsened plastic pollution. This study aimed at assessing the occurrence and distribution of face masks in a metropolitan (Adum - Kumasi), municipal (Ejisu), community (Abenase) and an institution (KNUST) in Ghana. The study showed that a total of 535 face masks were numerated along a stretch of 1,720 m with a density ranging from 0.04 m to 0.42 m. A no significant relationship (P = 0.602) was established between the observation distances and the number of waste face masks numerated. The study also showed that for a 1% increase in the number of face masks on working days, there would be a 0.775% increase in non-working days. A review of literature showed that the disposal of used face masks results in the release of micro- and nano-plastics, Pb, Cu, Sb, Zn, Mn, Ti, Fe and Ca into environmental media. Plastic pollution may be a concern to ecosystems due to its persistence in the environment, lack of environmental awareness, sensitization and education, and poor waste management systems. To ensure a sustainable management of waste face masks, significant efforts are needed. These may include proper disposal, redesigning and producing masks from biodegradable materials, incorporating waste face masks into construction materials, and recycling PPE by pyrolyzing are suggested options for the effective management of face masks.

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Non-thermal plasma (NTP) is a promising technology for the improvement of indoor air quality (IAQ) by removing volatile organic compounds (VOCs) through advanced oxidation process (AOP). In this paper, authors developed a laboratory scale dielectric barrier discharge (DBD) reactor which generates atmospheric NTP to study the removal of low-concentration formaldehyde (HCHO), a typical indoor air VOC in the built environment associated with cancer and leukemia, under different processing conditions. Strong ionization NTP was generated between the DBD electrodes by a pulse power zero-voltage switching flyback transformer (ZVS-FBT), which caused ionization of air molecules leading to active species formation to convert HCHO into carbon dioxide (CO2) and water vapor (H2O). The impact of key electrical and physical processing parameters i.e. discharge power (P), initial concentration (Cin), flow rate (F), and relative humidity (RH) which affect the formaldehyde removal efficiency (ɳ) were studied to determine optimum conditions. Results show that, the correlation coefficient (R2) of removal efficiency dependence on the processing parameters follow the order R2 (F) = 0.99 > R2 (RH) = 0.96, > R2 (Cin) = 0.94 > R2 (P) = 0.93. The removal efficiency reached 99% under the optimum conditions of P = 0.6 W, Cin = 0.1 ppm, F = 0.2 m3/h, and RH = 65% with no secondary pollution. The study provided a theoretical and experimental basis for the application of DBD plasma for air purification in the built environment.

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Appreciable levels of trace metals have been reported in the Tano basin, but data on the corresponding levels in fish and the risk they pose to consumers are limited. The levels of 7 trace metals in 18 fish muscles were assessed between November 2016 and October 2017 using acid digestion and PerkinElmer (PinAACle 900T) Atomic Absorption Spectrophotometry. Apart from Cu, all the metals studied were detected in all fish samples. The levels of Cr, As, and Hg were higher than the acceptable levels of fish muscles. Cr concentration ranged from 16.10 ± 0.2 mg/kg in Clarias gariepinus to 57.9 ± 4.2 mg/kg in Sarotherodon galilaeus. The levels of As ranged from 1.01 ± 0.08 in Clarias gariepinus to 3.00 ± 0.01 mg/kg in Mormyrus rume. Hg level was 0.58 ± 0.69 mg/kg in Oreochromis niloticus and 2.52 ± 0.70 mg/kg in Ctenopoma kingsleyae. However, Pb, Zn, and Cd concentrations were below the Food and Agriculture Organization limits with low target hazard quotients in all fish samples, suggesting no possible noncarcinogenic risks to adult consumers. Possible noncarcinogenic and carcinogenic health risks were recorded for As, Hg, and Cr in all fish species. Strong associations were observed between Hg, As, Zn, and Cr and between Pb and Cd suggesting a possible common source. Mormyrus rume fish species was under stress in the river, but the remaining species were in good condition. Periodic monitoring of trace metal concentrations in fish and enforcement of the buffer zone policy are recommended.

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Municipal solid waste constitutes significant quantities of waste generated in markets. Markets produce substantial quantities of fruit and vegetable waste, a source of nuisance in landfills. In Ghana, market waste (MW) appears to be unexplored and has limited data available. The need for MW valorization in the face of a circular economy requires reliable knowledge of MW properties. The study determined the waste compositions of selected major markets from two different classes of settlement in Kumasi and the seasonal effect on the compositions. The chemical properties of organics were determined via proximate and ultimate analyses and the theoretical biomethane potential, with the Buswell equation. From the results, MW composition in the wet season is 59.6% organic, 11.4% plastics, 8.3% paper, 5.3% textiles, 4.7% inert, 4.1% miscellaneous, 2.1% metal, 1.8% glass and 2.8% leather. The dry season values are 45.8% organic, 14.6% plastics, 12.7% paper, 7.3% textiles, 6.4% inert, 4.3% miscellaneous, 2.3% metal, 2.6% glass and 3.9% leather. An ANOVA indicates significant differences between the two seasons and some waste components; organics, plastics, paper and cardboard, leather, and inert. The high calorific values recorded ranged from 14.8 MJ kg-1 to 16.6 MJ kg-1. The biogas potential and biomethane content ranged from 775.3 l/kgVS to 828.9 L/kgVS and 50% to 57% respectively.Implications: Market waste (MW) in Ghana appears to be an unchartered area and there is limited data on market generation and composition. The need for MW valorization requires reliable knowledge on MW properties. This study explores MW characteristics of six major market from two different classes of settlements in a developing country. Study findings suggest that the quantities of market organics are higher than household waste. Again, MW composition can be influenced by season and geographical location. Furthermore, the study establishes the potential of MW in considerable quantities of biogas and methane generation, in comparison with household waste.

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The study focused on levels of selected heavy metals (Pb, Zn, and Cu) in sewage sludge, soil, and in lettuce and cabbage grown on sewage sludge amended soil. Also, the effect of sewage sludge on soil properties (pH, soil organic matter, and soil conductivity) was studied. Three treatments were used based on nitrogen application rates of the sewage sludge: 100, 150, and 200 kg N/ha for lettuce while 160, 210, and 260 kg N/ha for cabbage. A pot experiment was conducted with pots arranged in a completely randomized design and under local climatic conditions. The study revealed that soil organic matter content and conductivity increased significantly with increasing nitrogen application rates. Levels of heavy metals in the soil increased significantly with increasing application rates. The controls for both plants recorded the lowest heavy metal uptake. Cabbage had an uptake of 0.48 ± 0.13, 1.36 ± 0.23, and 2.60 ± 0.29 mg/kg for Pb, Zn, and Cu, respectively, while lettuce had 0.34 ± 0.19, 1.35 ± 0.31, and 2.30 ± 0.14 mg/kg uptake for Pb, Zn, and Cu, respectively. Highest metal uptake was recorded at the highest application rate in both plants (0.66 ± 0.17, 2.66 ± 0.09, and 4.33 ± 0.14 mg/kg for Pb, Zn, and Cu, respectively, for cabbage and 0.54 ± 0.01, 2.24 ± 0.17, and 3.88 ± 0.19 mg/kg of Pb, Zn, and Cu, respectively, for lettuce). The uptake of Zn and Cu was significant, while Pb uptake was insignificant for both plants. Yields increased significantly with increasing application rates. The study provides information on yield enhancement resulting from cultivating plants on soil amended with sewage sludge and the associated health risk implication.

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High generation of fecal sludge without proper treatment is a major sanitation problem. A key step in curbing this problem is producing value-added resources such as vermicompost from fecal sludge through substrate enrichment. Substrate enrichment is a vermicomposting technique that involves augmenting vermibed substrates with organic rich materials to provide additional nutrients, as well as underlying layers needed for microcosm development to produce desirable vermicompost. The aim of this study was to investigate effects of substrate enrichment with organic soils (black soil, red laterite soil and sandy soil) combined with coconut coir as bulking material, on the fecal sludge vermicomposting process and quality of the end-product. The purpose of the study was to promote the development of highly nutritive vermicompost from fecal sludge using substrate enrichment as a low-cost innovative vermicomposting technique. The enriched substrates were prepared with 160g of coconut coir, 120g of fecal matter (65-70% dry matter) and 80g of organic soil. The treatments were labelled T1, T2 and T3 representing systems containing black soil, red laterite soil and sandy soil respectively. The control treatment (T4) contained no soil. Triplicate treatments were setup and about 20 3-week old clitellated earthworms of the species Eisenia. fetida with live weights ranging from 255 to 275mg, released into each system for vermicomposting over a period of 12 weeks. Physicochemical parameters such as pH, Organic Carbon (Corg), Total Nitrogen (Ntot), Available Phosphorus (Pavail), Exchangeable Calcium (Caexch), Iron (Fe), Lead (Pb) and Aluminium (Al) were determined for both the fecal sludge and the vermicompost. The vermicompost in the setup with black soil (T1) showed the highest Corg mineralization and Ntot, Pavail and Caexch enhancement followed by T2, T3 and T4. Treatment T1 also resulted in the lowest concentration of Fe, Pb and Al in the vermicompost. Concentrations of these heavy metals were found to be higher in the other treatments in increasing order of T2, T3 and T4. Less than 16% earthworm mortality was recorded in all treatments except T4, in which the mortality was about 38% (38.33 ± 13.74). The enriched substrates were therefore found to provide a more suitable microclimate for earthworm development and produced vermicompost with high nutrient content. However, a more comprehensive study on metal accumulation in the earthworm tissues as a potential metal contaminant is needed to establish a strong hypothesis in the safe use of earthworms for this vermicomposting technique.

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Bioremediation has gained global prominence as an effective method for treating hydrocarbon-contaminated drill mud waste (HCDW). However, the problem of low nutrient content, bioavailability and microbial presence remain largely unresolved. In this study, the synergistic effects of compost, cow bile and bacterial culture on the degradation rate of HCDW was investigated. A homogenized HCDW sample (80 kg) obtained from 25 different drill mud tanks was divided into 20 portions (4 kg each) and each adjusted to 1.4% nitrogen content + 20 ml cow bile (i.e., basic treatment). Pure cultures of Brevibacterium casei (Bc) and Bacillus zhangzhouensi (Bz) and their mixture (BcBz) were subsequently added to 12 of the amended HCDW (basic) to undergo a 6-week incubation. A portion of the unamended HCDW (2 kg) was used as control. Initial pH, electrical conductivity and surface tension values of the HCDW were 8.83, 2.34 mS/cm and 36.5 mN/m, respectively. Corresponding values for total petroleum hydrocarbon (TPH), total nitrogen and total plate count bacteria were 165 g/kg, 0.04% and 4.4 × 102 cfu/ml. The treatments led to a substantial reduction in TPH (p < 0.05) while the control had no significant effect (p > 0.05). TPH reduction after the experimental period occurred in the order: basic + BcBz (99.7%) > basic + Bz (99.5%) > basic + Bc (99.2%) > basic (95.2%) > control (0.06%). Multiple regression analysis revealed significant effect of total plate count, pH, CN ratio and electrical conductivity (R2 = 0.87, p = 0.05) on the degradation of TPH in the HCDW. The study demonstrates strong interactive effects of compost, cow bile and bacteria culture on the remediation of HCDW, which can be applied to boost the efficiency of the bioremediation technique.

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Landfilling, which sits at the bottom of the waste management hierarchy, is the most employed option for managing waste in many emerging economies. In view of the numerous environmental and public health challenges associated with operation of landfills, proper siting would require inputs that overcome the challenges. This study sought to use Geographic Information System application through multi-criteria decision technique to spatially locate suitable sites that fulfill standard landfill guidelines, for waste disposal. Spatial Analyst extension within ArcGIS software was employed for the suitability analysis. Three processes were involved: (1) digitizing to determine boundaries around built up areas, (2) buffering for proximity analysis in order to generate zones around features such as roads, streams, etc. and (3) overlay analysis to determine areas suitable for landfilling. The findings from this study revealed that about 2.62% of the total area was considered as most suitable for landfilling, 2.74% deemed suitable and a large portion (94.64%), considered unsuitable. The study identified 6 most suitable sites that can be used for landfill development in the study area burdened with urbanization. GIS has been used to determine suitable sites for landfill development. Findings from the study serve as guideline for environmentally friendly landfill siting with efficient land-use planning.

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The increase in the quantity of municipal solid waste generated as a result of population growth in most urban areas has resulted in the difficulty of locating suitable land areas to be used as landfills. To curb this, waste transfer stations are used. The Kumasi Metropolitan Area, even though it has an engineered landfill, is faced with the problem of waste collection from the generation centres to the final disposal site. Thus in this study, multi-criteria decision analysis incorporated into a geographic information system was used to determine potential waste transfer station sites. The key result established 11 sites located within six different sub-metros. This result can be used by decision makers for site selection of the waste transfer stations after taking into account other relevant ecological and economic factors.

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Reliable national data on waste generation and composition that will inform effective planning on waste management in Ghana is absent. To help obtain this data on a regional basis, selected households in each region were recruited to obtain data on rate of waste generation, physical composition of waste, sorting and separation efficiency and per capita of waste. Results show that rate of waste generation in Ghana was 0.47 kg/person/day, which translates into about 12,710 tons of waste per day per the current population of 27,043,093. Nationally, biodegradable waste (organics and papers) was 0.318 kg/person/day and non-biodegradable or recyclables (metals, glass, textiles, leather and rubbers) was 0.096 kg/person/day. Inert and miscellaneous waste was 0.055 kg/person/day. The average household waste generation rate among the metropolitan cities, except Tamale, was high, 0.72 kg/person/day. Metropolises generated higher waste (average 0.63 kg/person/day) than the municipalities (0.40 kg/person/day) and the least in the districts (0.28 kg/person/day) which are less developed. The waste generation rate also varied across geographical locations, the coastal and forest zones generated higher waste than the northern savanna zone. Waste composition was 61% organics, 14% plastics, 6% inert, 5% miscellaneous, 5% paper, 3% metals, 3% glass, 1% leather and rubber, and 1% textiles. However, organics and plastics, the two major fractions of the household waste varied considerably across the geographical areas. In the coastal zone, the organic waste fraction was highest but decreased through the forest zone towards the northern savanna. However, through the same zones towards the north, plastic waste rather increased in percentage fraction. Households did separate their waste effectively averaging 80%. However, in terms of separating into the bin marked biodegradables, 84% effectiveness was obtained whiles 76% effectiveness for sorting into the bin labeled other waste was achieved.

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