RESUMEN
In this data article, natural (NL) and manganese oxide-modified LECA (MML) adsorbents were applied for adsorptive removal of Tetracycline (TC) from aqueous solution. The used adsorbents was characterized using fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), X-ray diffraction (XRD) and X-ray fluorescence spectroscopy (XRF). The chemical analysis of XRF data revealed increased chemical composition of Mn as MnO to 8.96â¯wt%. The SEM patterns were illustrated the extent of surface and enhanced porosity in MML with Mn. In optimum operational conditions, maximum removal percentage of TC was achieved at 51.5 and 99.4% using NL and MML, respectively. The maximum adsorption capacities obtained from Langmuir modeling were 6.89 and 9.24 for NL and MML, respectively. The modeling of the adsorption kinetics revealed that TC adsorption by both NL and MML adsorbents was best-fitted with a pseudo-first-order model (R 2 = 0.978). The isotherm studies of TC adsorption by MML showed that the Freundlich isotherm was the most appropriate model, with a higher coefficient of determination. The obtained data was illustrated that high competitive capacity of chloride and hardness ions compared with other ions against TC adsorption.
RESUMEN
Introduction of fuel hydrocarbons and inorganic compounds (heavy metals) into the soil, resulting in a change of the soil quality, which is likely to affect use of the soil or endangering public health and ground water. This study aimed to determine a series of parameters to remediation of TPH and heavy metals contaminated soil by non-ionic surfactants- chelating agents washing process. In this experimental study, the effects of soil washing time, agitation speed, concentration of surfactant, chelating agent and pH on the removal efficiency were studied. The results showed that TPH removal by nonionic surfactants (Tween 80, Brij 35) in optimal condition were 70-80% and 60-65%, respectively. Addition of chelating agent (EDTA) significantly increases Cd and Pb removal. The washing of soil by non- ionic surfactants and EDTA was effective in remediation of TPH and heavy metals from contaminated soil, thus it can be recommended for remediation of contaminated soil.