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1.
Soft Matter ; 11(24): 4742-55, 2015 Jun 28.
Artículo en Inglés | MEDLINE | ID: mdl-25892568

RESUMEN

The rheology of NFC suspensions that exhibited different microstructures and colloidal stability, namely TEMPO and enzymatic NFC suspensions, was investigated at the macro and mesoscales using a transparent Couette rheometer combined with optical observations and ultrasonic speckle velocimetry (USV). Both NFC suspensions showed a complex rheology, which was typical of yield stress, non-linear and thixotropic fluids. Hysteresis loops and erratic evolutions of the macroscale shear stress were also observed, thereby suggesting important mesostructural changes and/or inhomogeneous flow conditions. The in situ optical observations revealed drastic mesostructural changes for the enzymatic NFC suspensions, whereas the TEMPO NFC suspensions did not exhibit mesoscale heterogeneities. However, for both suspensions, USV measurements showed that the flow was heterogeneous and exhibited complex situations with the coexistence of multiple flow bands, wall slippage and possibly multidimensional effects. Using USV measurements, we also showed that the fluidization of these suspensions could presumably be attributed to a progressive and spatially heterogeneous transition from a solid-like to a liquid-like behavior. As the shear rate was increased, the multiple coexisting shear bands progressively enlarged and nearly completely spanned over the rheometer gap, whereas the plug-like flow bands were eroded.


Asunto(s)
Celulosa/química , Nanoestructuras/química , Reología , Fenómenos Biomecánicos , Resistencia al Corte , Suspensiones/química
2.
Artículo en Inglés | MEDLINE | ID: mdl-24580161

RESUMEN

The Taylor-Couette flow of a dilute micellar system known to generate shear-induced structures is investigated through simultaneous rheometry and ultrasonic imaging. We show that flow instabilities must be taken into account since both Reynolds and Weissenberg numbers may be large. Before nucleation of shear-induced structures, the flow can be inertially unstable, but once shear-induced structures are nucleated, the kinematics of the flow become chaotic, in a pattern reminiscent of the elastically dominated turbulence known in dilute polymer solutions. We outline a general framework for the interplay between flow instabilities and flow-induced structures.

3.
Soft Matter ; 10(20): 3523-35, 2014 May 28.
Artículo en Inglés | MEDLINE | ID: mdl-24651955

RESUMEN

The flow between concentric cylinders is routinely used in soft matter studies. In many cases, the purpose of the setup is rheometric: the idea is to relate macroscopic changes in material properties to microscopic changes in the structure of the material. The correspondence between the modifications of the microscopic structure and the macroscopic flow often relies on viscometric assumptions, which require the flow to be at least laminar. Flow instabilities are usually neglected because the viscosities of the materials are high and the geometries are small, such that the creeping flow approximation can be used. Nonetheless, the phenomenology of viscoelastic instabilities that emerged in the last twenty years warns us that flows can become turbulent without inertia, in particular flows between concentric cylinders. Given the strong similarities between inertial hydrodynamic instabilities and viscoelastic instabilities, a general knowledge of the former is advised for any researcher working on complex fluids. In this tutorial review, we focus on the inertial instability of isothermal and incompressible Newtonian fluids flowing between concentric cylinders. We highlight important aspects that can guide the study and control of instabilities in complex fluids in general.


Asunto(s)
Hidrodinámica , Reología , Viscosidad
4.
Eur Phys J E Soft Matter ; 35(9): 91, 2012 Sep.
Artículo en Inglés | MEDLINE | ID: mdl-23001785

RESUMEN

Shear-banding is ubiquitous in complex fluids. It is related to the organization of the flow into macroscopic bands bearing different viscosities and local shear rates and stacked along the velocity gradient direction. This flow-induced transition towards a heterogeneous flow state has been reported in a variety of systems, including wormlike micellar solutions, telechelic polymers, emulsions, clay suspensions, colloidal gels, star polymers, granular materials, or foams. In the past twenty years, shear-banding flows have been probed by various techniques, such as rheometry, velocimetry and flow birefringence. In wormlike micelle solutions, many of the data collected exhibit unexplained spatio-temporal fluctuations. Different candidates have been identified, the main ones being wall slip, interfacial instability between bands or bulk instability of one of the bands. In this review, we present experimental evidence for a purely elastic instability of the high shear rate band as the main origin for fluctuating shear-banding flows.

5.
Phys Rev Lett ; 104(17): 178303, 2010 Apr 30.
Artículo en Inglés | MEDLINE | ID: mdl-20482151

RESUMEN

We study the dynamics of the Taylor-Couette flow of shear banding wormlike micelles. We focus on the high shear rate branch of the flow curve and show that for sufficiently high Weissenberg numbers, this branch becomes unstable. This instability is strongly subcritical and is associated with a shear stress jump. We find that this increase of the flow resistance is related to the nucleation of turbulence. The flow pattern shows similarities with the elastic turbulence, so far only observed for polymer solutions. The unstable character of this branch led us to propose a scenario that could account for the recent observations of Taylor-like vortices during the shear banding flow of wormlike micelles.

6.
Soft Matter ; 6: 4788-4799, 2010 Aug 10.
Artículo en Inglés | MEDLINE | ID: mdl-23908673

RESUMEN

Many cell types have the ability to move themselves by crawling on extra-cellular matrices. Although cell motility is governed by actin and myosin filament assembly, the pattern of the movement follows the physical properties of the network ensemble average. The first step of motility, cell spreading on matrix substrates, involves a transition from round cells in suspension to polarized cells on substrates. Here we show that the spreading dynamics on 2D surfaces can be described as a hydrodynamic process. In particular, we show that the transition from isotropic spreading at early time to anisotropic spreading is reminiscent of the fingering instability observed in many spreading fluids. During cell spreading, the main driving force is the polymerization of actin filaments that push the membrane forward. From the equilibrium between the membrane force and the cytoskeleton, we derive a first order expression of the polymerization stress that reproduces the observed behavior. Our model also allows an interpretation of the effects of pharmacological agents altering the polymerization of actin. In particular we describe the influence of Cytochalasin D on the nucleation of the fingering instability.

7.
Phys Rev Lett ; 103(2): 028302, 2009 Jul 10.
Artículo en Inglés | MEDLINE | ID: mdl-19659252

RESUMEN

Using flow visualizations in Couette geometry, we demonstrate the existence of Taylor-like vortices in the shear-banding flow of a giant micelles system. We show that vortices stacked along the vorticity direction develop concomitantly with interfacial undulations. These cellular structures are mainly localized in the induced band and their dynamics is fully correlated with that of the interface. As the control parameter increases, we observe a transition from a steady vortex flow to a state where pairs of vortices are continuously created and destroyed. Normal stress effects are discussed as potential mechanisms driving the three-dimensional flow.

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