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1.
Entropy (Basel) ; 25(4)2023 Mar 31.
Artículo en Inglés | MEDLINE | ID: mdl-37190386

RESUMEN

Typical human-scaled considerations of thermodynamic states depend primarily on the core of associated speed or other relevant distributions, because the wings of those distributions are so improbable that they cannot contribute significantly to averages. However, for long timescale regimes (slow time), previous papers have shown otherwise. Fluctuating local equilibrium systems have been proven to have distributions with non-Gaussian tails demanding more careful treatment. That has not been needed in traditional statistical mechanics. The resulting non-Gaussian distributions do not admit notions such as temperature; that is, a global temperature is not defined even if local regimes have meaningful temperatures. A fluctuating local thermodynamic equilibrium implies that any local detector is exposed to sequences of local states which collectively induce the non-Gaussian forms. This paper shows why tail behavior is observationally challenging, how the convolutions that produce non-Gaussian behavior are directly linked to time-coarse graining, how a fluctuating local equilibrium system does not need to have a collective temperature, and how truncating the tails in the convolution probability density function (PDF) produces even more non-Gaussian behaviors.

2.
Entropy (Basel) ; 23(4)2021 Apr 13.
Artículo en Inglés | MEDLINE | ID: mdl-33924722

RESUMEN

Proxy temperature data records featuring local time series, regional averages from areas all around the globe, as well as global averages, are analyzed using the Slow Feature Analysis (SFA) method. As explained in the paper, SFA is much more effective than the traditional Fourier analysis in identifying slow-varying (low-frequency) signals in data sets of a limited length. We find the existence of a striking gap from ~1000 to about ~20,000 years, which separates intrinsic climatic oscillations with periods ranging from ~60 years to ~1000 years, from the longer time-scale periodicities (20,000 year+) involving external forcing associated with Milankovitch cycles. The absence of natural oscillations with periods within the gap is consistent with cumulative evidence based on past data analyses, as well as with earlier theoretical and modeling studies.

3.
Entropy (Basel) ; 22(10)2020 Sep 28.
Artículo en Inglés | MEDLINE | ID: mdl-33286860

RESUMEN

Any observation, and hence concept, is limited by the time and length scale of the observer and his instruments. Originally, we lived on a timescale of minutes and a length scale of meters, give or take an order of magnitude or two. Therefore, we devloped laboratory sized concepts, like volume, pressure, and temperature of continuous media. The past 150 years we managed to observe on the molecular scale and similarly nanoseconds timescale, leading to atomic physics that requires new concepts. In this paper, we are moving in the opposite direction, to extremely large time and length scales. We call this regime "slow time". Here, we explore which laboratory concepts still apply in slow time and which new ones may emerge. E.g., we find that temperature no longer exists and that a new component of entropy emerges from long time averaging of other quantities. Just as finite-time thermodynamics developed from the small additional constraint of a finite process duration, here we add a small new condition, the very long timescale that results in a loss of temporal resolution, and again look for new structure.

4.
Entropy (Basel) ; 22(10)2020 Oct 14.
Artículo en Inglés | MEDLINE | ID: mdl-33286922

RESUMEN

Dissimilar flows can be compared by exploiting the fact that all flux densities divided by their conjugate volume densities form velocity fields, which have been described as generalized winds. These winds are an extension of the classical notion of wind in fluids which puts these distinct processes on a common footing, leading to thermodynamical implications. This paper extends this notion from fluids to radiative transfer in the context of a classical two-stream atmosphere, leading to such velocities for radiative energy and entropy. These are shown in this paper to exhibit properties for radiation previously only thought of in terms of fluids, such as the matching of velocity fields where entropy production stops.

5.
Entropy (Basel) ; 20(11)2018 Nov 16.
Artículo en Inglés | MEDLINE | ID: mdl-33266605

RESUMEN

The entropy production rate is a well established measure for the extent of irreversibility in a process. For irreversible processes, one thus usually expects that the entropy production rate approaches zero in the reversible limit. Fractional diffusion equations provide a fascinating testbed for that intuition in that they build a bridge connecting the fully irreversible diffusion equation with the fully reversible wave equation by a one-parameter family of processes. The entropy production paradox describes the very non-intuitive increase of the entropy production rate as that bridge is passed from irreversible diffusion to reversible waves. This paradox has been established for time- and space-fractional diffusion equations on one-dimensional continuous space and for the Shannon, Tsallis and Renyi entropies. After a brief review of the known results, we generalize it to time-fractional diffusion on a finite chain of points described by a fractional master equation.

6.
Phys Rev E Stat Nonlin Soft Matter Phys ; 69(6 Pt 2): 066121, 2004 Jun.
Artículo en Inglés | MEDLINE | ID: mdl-15244681

RESUMEN

Many techniques have been developed to measure the difficulty of forecasting data from an observed time series. This paper introduces a measure which we call the "forecast entropy" designed to measure the predictability of a time series. We use attractors reconstructed from the time series and the distributions in the regular and tangent spaces of the data which comprise the attractor. We then consider these distributions on different scales. We present a formula for calculating the forecast entropy. To provide a standard of predictability, we define an idealized random system whose forecast entropy will be maximal; we then use this measure to rescale the forecast entropy to lie in the range [0,1]. The time series obtained from several chaotic systems as well as from a pseudorandom system are studied using this measure. We present evidence that the forecast entropy can be used as a tool for determining optimal delays and embedding dimensions used for reconstructing better attractors. We also show that the forecast entropy of a random system has completely different characteristics from that of a deterministic one.


Asunto(s)
Biofisica/métodos , Estadística como Asunto/métodos , Entropía , Fractales , Modelos Estadísticos , Distribución Aleatoria , Factores de Tiempo
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