RESUMEN
Naturally-occurring surface topographies abound in nature and endow diverse properties, i.e., superhydrophobicity, adhesion, anti-fouling, self-cleaning, anti-glare, anti-bacterial, and many others. Researchers have attempted to replicate such topographies to create human-made surfaces with desired functionalities. For example, combining the surface topography with judicial chemical composition could provide an effective, non-toxic solution to combat non-specific biofouling. A systematic look at the effect of geometry, modulus, and chemistry on adhesion is warranted. In this work, we use a model system that comprises silica (SiO x ) beads interacting with a substrate made of a commercial polydimethylsiloxane kit (PDMS, Sylgard 184) featuring a sinusoidal topography. To examine the impact of interactions on particle settlement, we functionalize the surfaces of both the PDMS substrate and the SiO x beads with polyacrylic acid (PAA) and polyethyleneimine (PEI), respectively. We also use the PDMS commercial kit coated with liquid glass (LG) to study the effect of the substrate modulus on particle settlement. Substrates with a higher aspect ratio (i.e., amplitude/periodicity) encourage adsorption of particles along the sides of the channel compared with substrates with lower aspect ratio. We employ colloidal probe microscopy to demonstrate the effect of interaction between the substrate and the particle. The interplay among the surface modulus, geometry, and interactions between the surface and the particle governs particle settlement on sinusoidally-corrugated substrates.
RESUMEN
Surface topographies of various sizes, shapes, and spatial organization abound in nature. They endow properties such as super-hydrophobicity, reversible adhesion, anti-fouling, self-cleaning, anti-glare, and anti-bacterial, just to mention a few. Researchers have long attempted to replicate these structures to create artificial surfaces with the functionalities found in nature. In this review, we decompose the attributes of surface topographies into their constituents, namely feature dimensions, geometry, and stiffness, and examine how they contribute (individually or collectively) to settlement and adhesion of natural organisms and synthetic particles on the surface. The size of features that comprise the topography affects the contact area between the particle and surface as well as its adhesion and contributes to the observed adsorptive properties of the surface. The geometry of surface perturbations can also affect the contact area and gives rise to anisotropic particle settlement. Surface topography also affects the local stiffness of the surface and governs the adhesion strength on the surface. Overall, systematically studying attributes of surface topography and elucidating how each of them affects adhesion and settlement of particles will facilitate the design of topographically-corrugated surfaces with desired adsorption characteristics.