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J Org Chem ; 81(6): 2364-71, 2016 Mar 18.
Artículo en Inglés | MEDLINE | ID: mdl-26926714

RESUMEN

A new strategy for the synthesis of acyl ß-C-glycosides is described. The reactivity of glyconitriles toward organometallic reagents such as organomagnesium or organolithium derivatives was studied, affording acyl ß-C-glycosides in moderate to good yields. In this study, glycal formation was efficiently prevented by deprotonating the hydroxyl group in position 2 of the glyconitriles during the process.

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