RESUMEN
A innovative 5-Cl-8-oxyquinolinepropoxycalix[4]arene ligand (2) have been prepared, exhibiting, at room temperature, blue fluorescent light emission and resulting in shift band to green fluorescent light (fluorescence mode) in the presence of coordinated Eu(III) and Tb(III) ions. Terbium complex presented phosphorescence emission as noted by typical bands at 490 nm, 545 nm and 585 nm. TG/DTG data exhibited typical thermal behavior for these compounds, however DSC curves showed the melting temperature near 300 °C for the samples, demonstrating an unusual thermal stability when quinoline derivatives are attached to calix[4]arene matrix. This fact strongly suggests an effective approach to preparing the photoluminescent compound associating high chemical and thermal stability.
Asunto(s)
Calixarenos/química , Cloroquinolinoles/química , Luminiscencia , Temperatura , Acetonitrilos/química , Rastreo Diferencial de Calorimetría , Europio/química , Ligandos , Espectroscopía de Resonancia Magnética , Espectrometría de Fluorescencia , Espectrofotometría Infrarroja , Espectrofotometría Ultravioleta , Terbio/química , TermogravimetríaRESUMEN
O Parque Nacional da Serra do Divisor (PNSD), localizado a noroeste do Estado do Acre, é considerado uma das áreas de maior diversidade da Amazônia. A importância de se considerar insetos em programas de conservação tem sido muito enfatizada. Vespas solitárias e sociais são componentes muito importantes dos ecossistemas, devido à posição que ocupam nas redes alimentares. Esse trabalho teve como objetivo realizar uma avaliação ecológica rápida da fauna de vespas do PNSD, para subsidiar a elaboração de um plano de manejo do referido parque. A amostragem foi realizada em 12 sítios de coleta, situados no interior de oito tipologias de vegetação. Os insetos foram coletados através de armadilhas Malaise, as quais foram expostas em todos os sítios por 24 horas, totalizando 288 horas de amostragem. Foram consideradas nas análises vespas das famílias Chalcididae, Eucharitidae, Evaniidae, Mutillidae, Pompilidae, Crabronidae e Vespidae. Ao todo, foram coletados 366 indivíduos distribuídos em 40 gêneros e 85 espécies. Os gêneros Ephuta (Mutillidae), Trypoxylon (Crabronidae) e Conura (Chalcididae) foram os mais ricos em espécies. Os sítios localizados na região norte do PNSD, considerada zona intangível e zona primitiva, foram os mais ricos em espécies. Cerca de 65 por cento das espécies foram exclusivas a um único sítio, o que significa que as amostras possuem pequena similaridade faunística. Algumas espécies coletadas são consideradas raras.
The Serra do Divisor National Park (PNSD), located at the northwest of Acre State, Amazonia, is considered an area of great biodiversity. The question of considering insects in conservation programs. Solitary and social wasps are important components of the terrestrial ecosystems due to their position in trophic webs. The present study aimed at making a rapid ecological assessment of the wasps from the PNSD in order to support the elaboration of a conservation and management plan for that park. The insects were sampled in 12 sites located in eight forest types by Malaise traps that operated in each for 24 hours, totaling 288 hours of sampling. The results on the families Chalcididae, Eucharitidae, Evaniidae, Mutillidae, Pompilidae, Crabronidae and Vespidae are presented here. On the whole, 366 wasps were collected representing 40 genera and 85 species. The genera Ephuta (Mutillidae), Trypoxylon (Crabronidae) and Conura (Chalcididae) were the most specious. The sites situated at the northern region of the PNSD, the intangible and primitive zones, were the most species rich. Some collected species were considered rare and about 65 percent of species were exclusive to only one site. This means that the samples have little faunal similarity.
Asunto(s)
Avispas , HimenópterosRESUMEN
Guilds of Aculeate solitary wasps and bees that nest in preexisting cavities in wood are important components of terrestrial ecosystems because they engage in several ecological interactions (e.g. predation and pollination) with other species of plants and animals. Spatial and temporal variations in richness and abundance of solitary wasps and bees can be related to changes in environmental structure and in the diversity of other groups of organisms. The nesting period of these Aculeata is their most critical life cycle stage. Females of solitary wasp and bee species invest relatively more time constructing and provisioning their nests than do females of social species. Differently from species that nest in the soil or construct exposed nests, the main factors affecting the reproductive success of solitary species nesting in preexisting wood holes are still unknown. Our objective is to provide an overview of the role of proximate causes of nesting failure or success among solitary wasps and bees (Aculeata), for designing effective conservation and management strategies for these Hymenoptera.
Espécies de vespas e abelhas solitárias que nidificam em cavidades pré-existentes no lenho de plantas integram uma guilda de nidificação e são importantes componentes da maioria dos ecossistemas terrestres. Isso se deve, em parte, ao grande número de interações (e.g. predação e polinização) que mantêm com outras espécies de organismos. Variações espaciais e temporais em sua abundância e riqueza podem estar correlacionadas a alterações na estrutura do ambiente. Uma fase crítica no ciclo de vida de vespas e abelhas solitárias é o período de nidificação. As fêmeas dessas espécies investem a maior parte de seu tempo de vida em construir e aprovisionar seus ninhos. Ao contrário do que ocorre para espécies que nidificam no solo ou fazem seus ninhos expostos, até o momento não houve tentativa alguma de discutir o conjunto de fatores que influenciam o sucesso de nidificação das espécies que nidificam em cavidades pré-existentes no lenho de plantas. Este artigo revê aspectos que afetam a nidificação desses Aculeata, com ênfase em fatores proximais, tais como a disponibilidade e características de cavidades no lenho. Compreender como esses fatores agem sobre a sobrevivência e o sucesso reprodutivo é de grande importância para a conservação e manejo dessas espécies.
Asunto(s)
Himenópteros/clasificación , Himenópteros/crecimiento & desarrollo , Himenópteros/embriología , Abejas , AvispasRESUMEN
Guilds of Aculeate solitary wasps and bees that nest in preexisting cavities in wood are important components of terrestrial ecosystems because they engage in several ecological interactions (e.g. predation and pollination) with other species of plants and animals. Spatial and temporal variations in richness and abundance of solitary wasps and bees can be related to changes in environmental structure and in the diversity of other groups of organisms. The nesting period of these Aculeata is their most critical life cycle stage. Females of solitary wasp and bee species invest relatively more time constructing and provisioning their nests than do females of social species. Differently from species that nest in the soil or construct exposed nests, the main factors affecting the reproductive success of solitary species nesting in preexisting wood holes are still unknown. Our objective is to provide an overview of the role of proximate causes of nesting failure or success among solitary wasps and bees (Aculeata), for designing effective conservation and management strategies for these Hymenoptera.
Asunto(s)
Abejas , Comportamiento de Nidificación , Avispas , Madera , AnimalesRESUMEN
An infant had clinical signs suggestive of Hirschsprung disease as the initial manifestation of leukocyte adhesion deficiency. Chromosome studies showed a deletion of the distal third of the long arm of one chromosome 21, and flow cytometric studies confirmed the defective expression of CD18.
Asunto(s)
Enfermedad de Hirschsprung/diagnóstico , Síndrome de Deficiencia de Adhesión del Leucocito/diagnóstico , Antígenos CD11/sangre , Antígenos CD18/sangre , Deleción Cromosómica , Cromosomas Humanos Par 21 , Diagnóstico Diferencial , Resultado Fatal , Enfermedad de Hirschsprung/genética , Humanos , Lactante , Síndrome de Deficiencia de Adhesión del Leucocito/genética , MasculinoAsunto(s)
Agranulocitosis/patología , Quimiotaxis de Leucocito , Neutropenia/patología , Neutrófilos/ultraestructura , Adolescente , Médula Ósea/patología , Núcleo Celular/ultraestructura , Ensayo de Unidades Formadoras de Colonias , Granulocitos/inmunología , Humanos , Cariotipificación , Masculino , Monocitos/inmunología , Neutropenia/genética , Neutropenia/inmunología , PloidiasRESUMEN
G-banded and C-banded karyotypes of three closely related and morphologically similar species of cotton rats, Sigmodon hispidus (2n=52; 52 autosomal arms), S. mascotensis (2n=28; 28 autosomal arms), and S. arizonae (2n=22,24; 38 autosomal arms) are presented and compared. Despite the enormous difference between the higher diploid number of hispidus and the lower diploid numbers of mascotensis and arizonae, a great deal of G-band homology is retained. If the karyotype of hispidus is considered ancestral in the group, then chromosome evolution toward lower diploid numbers has proceeded through the fixation of a large number of both tandem and centric fusions. Centromeric heterochromatin has not, however, persisted as intetstitial C-band material on the tandem fusion products. The karyotypes of mascotensis and arizonae share several tandem fusion products of hispidus chromosomes indicating a common origin of the former two species from an ancestor of intermediate diploid number. Chromosome evolution from the ancestral hispidus-like karyotype to the karyotype of the common ancestor of arizonae and mascotensis proceeded almost exclusively by tandem fusion. This orthokaryotypic trend continued in the evolution of the karyotype of modern mascotensis. In the line leading from the arizonae-mascotensis ancestor to modern arizonae a trend of centric fusion predominated.