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During groundwater evaporation discharge, a series of carbon-related water-rock interactions potentially impact the terrestrial carbon cycle significantly. However, the migration and transformation of carbon in groundwater evaporation discharge area remain inadequately understood. Using the Tumochuan Plain in Inner Mongolia as a case study, this paper constructs a carbon balance equation for groundwater evaporation discharge area by employing mass balance principles and hydrogeochemical simulation methods, thereby analyzing the mechanisms of carbon diversion during groundwater evaporation. The result showed that evaporation discharge area of Tumochuan Plain was a 'carbon sink'. Carbon emission rate to atmosphere in study area was 7.35 g/(m2·a), while carbon fixation rate by calcite precipitation and dissolved inorganic carbon (DIC) into groundwater was 37.15 g/(m2·a). The precipitation of calcite and the dissolution of dolomite were the main water-rock interactions controlling the migration and transformation of DIC. The carbon absorbed by dolomite dissolution reached 21,698.02 t/a (30.56 g/(m2·a)), offsetting a significant portion of the CO2 emitted during calcite precipitation. In addition, the calcium released by the dissolution of dolomite and anorthite effectively promoted the precipitation of calcite, which was the primary factor for groundwater to become a carbon sink in this area.

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The highway greenbelt, vigorously promoted in arid and semi-arid areas, has obvious impacts on beautifying the environment, absorbing dust, reducing noise, and maintaining soil and water. Moreover, it affects the characteristics of how water resources are distributed and the regional groundwater cycle. However, the impact of highway greenbelt construction on groundwater flow in semi-arid areas is unknown. The Hubao Highway greenbelt in the north part of the Tumochuan Plain was studied as an example. The paper combines field investigation, remote sensing and mathematical modeling to quantify the impact of highway green space construction on regional groundwater circulation. The results showed that: Trees, shrubs and grasses were the dominant vegetation types in the landscaped area, accounting for 42.17% of the studied area. The total evapotranspiration water consumption of the green belt during the growing season was 471.35 × 104m3. The groundwater recharge in the study area was mainly derived from the lateral recharge in front of the mountain, and the main discharge was the evapotranspiration water consumption of the green belt. This evapotranspiration accounts for 3.31% of the total groundwater recharge. Under the condition that the recharge in front of the mountain remains constant, the evapotranspiration water consumption of the green belt will still have an increasing trend in the future. Appropriate planting of poplar and other high water-consuming trees may be the best way to mitigate the adverse effects of greenbelt evapotranspiration on groundwater resources. The results of this study provide valuable insights for environmental protection and infrastructure development in similar areas.

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Coal mine in arid and semi-arid area is one of the most severely degraded ecosystems on the earth. The continuous decrease in groundwater level caused by coal mining will inevitably affect biogeochemical environment of the vadose zone, and then lead to the replacement of surface vegetation. Yimin open-pit coal mine was taken as an example to reveal the relationship between the groundwater depth and soil water content (SWC), soil salt content, soil electrical conductivity (SEC), soil organic matter (SOM), soil available potassium (SAK), soil available nitrogen (SAN), vegetation coverage, aboveground biomass and species richness. The results show that, the change of groundwater depth can affect soil properties and then change the characteristics of surface vegetation, and the change of surface vegetation can also react on soil properties. Vegetation coverage and aboveground biomass are negatively correlated with groundwater depth, and positively correlated with SWC, SEC, SOM and SAK. The shallow groundwater table is conducive to the accumulation of SOM, so that the surface biomass and vegetation coverage are high. The higher the surface biomass, the more the SAN is absorbed. Under natural conditions, the relative strength of biological nitrogen fixation and plant absorption determine the content of SAN. In the research area, when the depth of groundwater is less than 0.4 m will cause soil salinization, then lead to low species richness; Species richness is exponentially correlated with groundwater depth and decreases with the increase in groundwater depth.

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Hydro-biogeochemical processes control the formation and evolution of high arsenic (As) groundwater. However, the effects of nitrogen and sulfur cycles in groundwater on As migration and transformation are not well understood. Thus, twenty-one groundwater samples were collected from the Hasuhai basin. Hydrochemistry and geochemical modeling were used to analyze the geochemical processes associated with nitrogen and sulfur cycles. An arsenic speciation model (AM) and a sulfide-As model (SAM) were constructed to verify the existence of As species and the formation mechanism of thioarsenate. A hydrous ferric oxide (Hfo)-As adsorption model (HAM) and a competitive adsorption model (CAM) were used to reveal the adsorption and desorption mechanisms of As. The results showed that high arsenic groundwater (As > 10 µg/L) was mainly distributed under reductive conditions, and the highest concentration was 231.5 µg/L. The modeling results revealed that sulfides were widely involved in the geochemical cycle of As, with H3AsO3 and H2AsO3- accounting for >70 % of the total As, and thioarsenate accounting for 30 %. S/As < 2.5 and S/Fe < l control the formation of thioarsenate. With the high correlation of NH4+, TFe, sulfide, and TAs, the co-mobilization of N and S cycles may facilitate As enrichment in groundwater. A weak alkaline reduction environment triggered by the decomposition of organic matter was the main factor leading to the transfer of As from the aquifer to the groundwater. This research contributes to the development of high-As groundwater, and the findings are of general significance for drinking water in the Hasuhai Basin.

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Globally, groundwater with high fluoride and arsenic receives extensive concern because of its wide distribution and great harm to human health caused by drinking water. In this paper, taking Tumochuan Plain in China as an example, based on hydrogeological investigation, groundwater flow system theory and hydro-chemical analysis methods were applied to reveal the mechanism of high fluoride and high arsenic in arid and semi-arid regions. In unconfined and confined groundwater of Tumochuan Plain, the highest concentration of fluoride is 7.2 and 11.2 mg/L respectively, and the highest concentration of total arsenic is 200.3 and 162.3 µg/L respectively. Fluoride in groundwater is mainly derived from the soluble fluoride in soil and aquifer medium. Because of the water-rock interaction, the alkaline environment caused by the hydrolysis of feldspar minerals in the central part of the plain has an important influence on the accumulation of F and As in this area. High fluoride water is formed in the alkaline environment (high pH values) of high concentration of Na+ and low concentration of Ca2+. The high arsenic groundwater is distributed in the alkaline reducing environment that the content of soluble salt in aquifer media is high (>200 mg/100 g dry soil). The reductive dissolution of iron and manganese oxides and competitive adsorption of HCO3- all contribute to a high level of arsenic in both unconfined and confined aquifers. The research results have important guiding significance for water supply safety and water quality improvement in arid-semiarid areas in the world with high fluoride and high arsenic groundwater distribution.

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Due to the drought climate and a large amount of groundwater drainage, there are widespread environmental geological problems in prairie open-pit coal mining areas, such as hydrological cycle imbalance, soil desertification and prairie degradation. This study takes the Hulunbeir Prairie Yimin Open-pit Coal Mine as the research object. Basing on the investigation of the groundwater-lake system in the mining area, data of hydrological, meteorological and remote sensing image, the mathematical model of groundwater level-lake area response mechanism in the mining area was constructed by using the principle of water balance. And the influence of mining area development on the lake area of Yimin basin had been predicted and analyzed. The results show that in the past 35 years of coal mining, the number of lake groups in Yimin basin has changed from 5 before mining (1982) to 2 (2018), and the total area of lakes has reduced from 6.94 km2 before mining to 1.43 km2 with an area reduction rate of 79%. The prairie lake-groundwater coupling model was constructed based on the principle of water balance, and the goodness-of-fit reached more than 0.83 after testing. Based on the model, it's predicted that when the Yimin Coal Mine is closed (2045), the area of Chaidaminol lake will shrink to 1.37 km2 under the condition of little fluctuation of climatic factors and stable mine development.

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The interactions between groundwater and its environment was investigated in prairie mining area in this study, through the groundwater system evolutions in mining area before and after the mining actions (from 1973 to 2016) of Yimin coal mine. The results showed that (1) the mining activities of the open-pit coal changed the original reduction environment into the oxidizing environment in the mining area. The pyrite and sulfur-bearing coal in the stratum oxidized, produced acid and triggered a series of subsequent reactions, resulting in the decrease in the pH value of the groundwater in the mining area. The concentration of SO42-, Fe2+, Fe3+, Ca2+ and Mg2+ and the total hardness increased. The regional hydrochemical type evolved from HCO3-Na·Ca·Mg type before mining to the type of HCO3·SO4-Na·Ca·Mg after mining. (2) Coal mining strongly draining underground water accelerated the regional groundwater circulation, and then made the groundwater desalination. The concentrations of TDS, COD and Na++K+ in the mining area all showed a decreasing trend. (3) The coal mining activities made the calcite and dolomite in saturated state under the natural condition of underground water to be unsaturated again. The hydro-geochemical action evolves from double control (water-rock interaction and evaporation-concentration) to water-rock interaction control.

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In the rubber dam's impact area, the groundwater total hardness (TH) has declined since 2000, ultimately dropping to 100-300 mg/L in 2012. pH levels have shown no obvious changes. NH4-N concentration in the groundwater remained stable from 2000 to 2006, but it increased from 2007 to 2012, with the largest increase up to 0.2 mg/L. NO3-N concentration in the groundwater generally declined in 2000-2006 and then increased from 2007; the largest increase was to 10 mg/L in 2012. Total dissolved solids (TDS) of the groundwater showed a general trend of decline from 2000 to 2009, but levels increased after 2010, especially along the south bank of the Luohe River where the largest increase recorded was approximately 100 mg/L. This study has shown that the increases in the concentrations of NH4-N and NO3-N were probably caused by changes in groundwater levels. Nitrates adsorbed by the silt clay of aeration zone appear to have entered the groundwater through physical and chemical reactions. TDS increased because of groundwater evaporation and some soluble ions entered the groundwater in the unsaturated zone. The distance of the contaminant to the surface of the aquifer became shorter due to the shallow depth of groundwater, resulting in the observed rise in pollutant concentrations more pronounced.

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AIM: To detect the distinct proteins in amniotic fluid (AF) between nervous system malformations fetuses and normal fetuses. MATERIAL AND METHODS: Surface-enhanced laser desorption-ionization/time-of-flight mass spectrometry was used to characterize AF peptides in AF between nervous system malformations fetuses and normal fetuses. WCX2 protein chips were used to characterize AF peptides in AF. Protein chips were examined in a PBSIIC protein reader, the protein profiling was collected by ProteinChip software version 3.1 (Ciphergen Biosystems, Fremont, CA, USA) and analyzed by Biomarker Wizard software (Ciphergen Biosystems). Nine distinct proteins were identified in AF between nervous system malformations fetuses and normal fetuses. RESULTS: Compared with the control group, three proteins with m/z 4967.5 Da, 5258.0 Da, and 11,717.0 Da were down-regulated, and six proteins with m/z 2540.4 Da, 3107.1 Da, 3396.8 Da, 4590.965 Da, 5589.2 Da and 6429.4 Da up-regulated in nervous system malformations fetuses. CONCLUSION: The results suggest that there are distinct proteins in protein profiling of AF between nervous system malformations fetuses and normal fetuses.

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