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1.
Artículo en Inglés | MEDLINE | ID: mdl-39235527

RESUMEN

Biopriming seeds with beneficial bacteria has potential to enhance seed germination. Therefore, in this investigation, five sulphur-oxidizing bacterial cultures, viz., Pantoea dispersa SOB2, Bacillus velezensis SN06, Bacillus cereus SN20, Bacillus tropicus SN16, and Bacillus megaterium SN11, were evaluated for different plant growth-promoting traits and their impact on Vigna radiata L. (mung bean) and Brassica juncea L. (mustard) seed germination. Among these, three bacterial cultures Pantoea dispersa SOB2, Bacillus velezensis SN06, and Bacillus megaterium SN11 evinced potential for mineral solubilization on solid medium where Pantoea dispersa SOB2 had the maximum solubilization indices-3.06, 5.14, and 2.48 for phosphate, zinc, and potassium respectively. The culture also displayed higher indole acetic acid (113.12 µg/mL), gibberellic acid (162.66 µg/mL), ammonia (5.23 µg/mL), and siderophore (69.53%) production than other bacterial cultures whereas Bacillus cereus SN20 showed maximum exopolysaccharide production (9.26 g/L). Bacterial culture Pantoea dispersa SOB2 significantly ameliorated the germination rate (3.73 no./day) and relative seed germination (208%) of Brassica juncea L., while Bacillus velezensis SN06 and Bacillus cereus SN20 followed with germination rate and relative seed germination of 2.86 no./day and 207%, respectively. Pantoea dispersa SOB2 displayed lowest mean germination time 2.91 days followed by Bacillus megaterium SN11 with 3.19 days. Biopriming with sulphur-oxidizing bacterial cultures, germination parameters of Vigna radiata L. were also markedly improved. Pantoea dispersa SOB2 demonstrated the highest germination rate (6.72 no./day), relative seed germination (115.56%), and minimum mean generation time (1.73 days). Bacillus velezensis SN06 inoculation had a beneficial effect on the seedling growth of Vigna radiata L., whereas Pantoea dispersa SOB2 greatly aided the seedling growth of Brassica juncea L. Results corroborated a prominent positive correlation between seed germination and plant growth-promoting traits. This is the first study on Pantoea dispersa as sulphur oxidizer, displaying plant growth promoting traits and seed germination potential. The potent sulphur-oxidizing bacterial cultures possessing plant growth promoting activities enhanced seed germination under in vitro conditions that could be further explored in field as biofertilizers to enhance the growth and yield of Brassica juncea L. and Vigna radiata L. crop.

2.
Sci Rep ; 13(1): 21322, 2023 Dec 03.
Artículo en Inglés | MEDLINE | ID: mdl-38044367

RESUMEN

The low glass-forming ability of aluminium-based metallic glasses significantly limits their development and preparation. This paper updates the current state of knowledge by presenting the results of structural studies of two newly-developed Al79Ni5Fe5Y11 and Al79Ni11Fe5Y5 alloys with a reduced aluminium content (< 80 at.%). The alloys were produced by conventional casting (ingots) and melt-spinning (ribbons). Structural characterization was carried out for bulk ingots first, and then for the melt-spun ribbons. The ingots possessed a multiphase crystalline structure, as confirmed by X-ray diffraction and scanning electron microscopy observations. The amorphous structure of the melt-spun ribbons was determined by X-ray diffraction and transmission electron microscopy. SEM observations and EDX element maps of the cross-section of melt-spun ribbons indicated a homogeneous elemental composition. Neutron diffraction revealed the presence of nanocrystals in the amorphous matrix of the melt-spun ribbons. DSC data of the melt-spun ribbons showed exothermic events corresponding to the first crystallization at temperatures of 408 °C and 387 °C for Al79Ni5Fe5Y11 and Al79Ni11Fe5Y5, respectively.

3.
Sci Rep ; 8(1): 17637, 2018 Dec 05.
Artículo en Inglés | MEDLINE | ID: mdl-30518966

RESUMEN

We study the spontaneous crystallization of an assembly of highly monodisperse steel spheres under shaking, as it evolves from localized icosahedral ordering towards a packing reaching crystalline ordering. Towards this end, real space neutron tomography measurements on the granular assembly are carried out, as it is systematically subjected to a variation of frequency and amplitude. As expected, we see a presence of localized icosahedral ordering in the disordered initial state (packing fraction ≈ 0.62). As the frequency is increased for both the shaking amplitudes (0.2 and 0.6 mm) studied here, there is a rise in packing fraction, accompanied by an evolution to crystallinity. The extent of crystallinity is found to depend on both the amplitude and frequency of shaking. We find that the icosahedral ordering remains localized and its extent does not grow significantly, while the crystalline ordering grows rapidly as an ordering transition point is approached. In the ordered state, crystalline clusters of both face centered cubic (FCC) and hexagonal close packed (HCP) types are identified, the latter of which grows from stacking faults. Our study shows that an earlier domination of FCC gives way to HCP ordering at higher shaking frequencies, suggesting that despite their coexistence, there is a subtle dynamical competition at play. This competition depends on both shaking amplitude and frequency, as our results as well as those of earlier theoretical simulations demonstrate. It is likely that this involves the very small free energy difference between the two structures.

4.
J Glaucoma ; 25(4): 343-7, 2016 Apr.
Artículo en Inglés | MEDLINE | ID: mdl-25651206

RESUMEN

PURPOSE: The aim of our study was to analyze the epidemiological profile and outcome of steroid-induced ocular hypertension in children below 12 years of age in a tertiary eye center. METHODS: Hospital records of patients attending the pediatric glaucoma clinic from July 2005 to December 2012 at our center were retrospectively reviewed. Steroid-induced ocular hypertension was defined as intraocular pressures (IOP)>21 mm Hg (or an increase of>6 mm from baseline) with or without associated glaucomatous optic neuropathy after intake of steroids in any form. Demographic data, management details and IOP, anterior segment, and posterior segment findings were recorded. The main outcome measure was the control of IOP after treatment. RESULTS: Of the acquired pediatric glaucoma patients, 24% were steroid-induced ocular hypertensives (36 of 150 patients) (mean age group 9.2 ± 2.4 y). We studied 57 eyes of 36 patients that had an IOP>21 mm Hg after steroid intake. Of the 36 patients, 22 had bilateral steroid hypertensive response. Of all the patients, 15 (41.6%) received steroids because of vernal conjunctivitis, 16 (22 eyes) could be managed by withdrawing steroids only, 13 (25 eyes) were controlled by medical therapy, and 7 (10 eyes) needed surgery. Favorable outcome (defined as<21 mm of Hg with/without topical antiglaucoma medications) was achieved in 80.5% at the last follow-up (mean 17.4 ± 23.47 mo; range 4 mo to 8 y). CONCLUSIONS: Our paper emphasizes on the ocular hypertensive side effects of steroids in children. There are many instances where one can avoid the use of steroids and consider nonsteroidal/anti-inflammatory alternatives. Withdrawal of steroids and antiglaucoma medicines are effective in controlling IOP in majority (80.5%).


Asunto(s)
Betametasona/efectos adversos , Dexametasona/efectos adversos , Glucocorticoides/efectos adversos , Presión Intraocular/efectos de los fármacos , Hipertensión Ocular/inducido químicamente , Administración Oral , Administración Tópica , Antihipertensivos/uso terapéutico , Niño , Preescolar , Conjuntivitis Alérgica/tratamiento farmacológico , Fibrosis Quística/tratamiento farmacológico , Femenino , Cirugía Filtrante , Gonioscopía , Humanos , Hepatopatías/tratamiento farmacológico , Masculino , Síndrome Nefrótico/tratamiento farmacológico , Hipertensión Ocular/diagnóstico , Hipertensión Ocular/terapia , Soluciones Oftálmicas , Estudios Retrospectivos , Tonometría Ocular , Resultado del Tratamiento , Uveítis/tratamiento farmacológico
5.
J Phys Condens Matter ; 23(24): 246006, 2011 Jun 22.
Artículo en Inglés | MEDLINE | ID: mdl-21628788

RESUMEN

We have investigated the influence of B-site doping on the crystal and magnetic structure in La(0.5)Ca(0.5)Mn(1 - x)B(x)O(3) (B = Fe, Ru, Al and Ga) compounds using neutron diffraction, small angle neutron scattering, magnetization and resistivity techniques. The B-site doped samples are isostructural and possess an orthorhombic structure in the Pnma space group at 300 K. A structural transition from orthorhombic to monoclinic is found to precede the magnetic transition to the CE-type antiferromagnetic state in a few of these samples. On doping with Fe, the charge and orbitally ordered CE-type antiferromagnetic state is suppressed, followed by growth of the ferromagnetic insulating phase in 0.02 ≤ x ≤ 0.06 compounds. At higher Fe doping in x > 0.06, the ferromagnetic state is also suppressed and no evidence of long range magnetic ordering is observed. In Ru doped samples (0.01 ≤ x ≤ 0.05), the ferromagnetic metallic state is favored at T(C)≈200 K and T(MI)≈125 K and no significant change in T(C) and T(MI) as a function of Ru doping is found. In contrast, with non-magnetic Al substitution for 0.01 ≤ x ≤ 0.03, the charge ordered CE-type antiferromagnetic state coexists with the ferromagnetic metallic phase. With further increase in Al doping (0.05 ≤ x ≤ 0.07), both CE-type antiferromagnetic and ferromagnetic phases are gradually suppressed. This behavior is accompanied by the evolution of an A-type antiferromagnetic insulating state. Eventually, at higher Al doping (0.10 ≤ x ≤ 0.13), this phase is also suppressed and the signature of a spin glass like transition is evident in M(T). Likewise, substitution with Ga is observed to induce similar effects to those described for Al doped samples. The presence of short ranged ferromagnetic ordering has been further explored using small angle neutron scattering measurements in a few of the selected samples.


Asunto(s)
Lantano/química , Campos Electromagnéticos , Ensayo de Materiales
6.
J Phys Condens Matter ; 21(38): 386002, 2009 Sep 23.
Artículo en Inglés | MEDLINE | ID: mdl-21832380

RESUMEN

We report a structural, magnetic and transport study in La(0.5)Ca(0.5-x)Ba(x)MnO(3) (0

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