RESUMEN
For the first time, we demonstrate the use of a microemulsion reaction to synthesize different nanostructures of LiCoO2 cathode material. By varying the annealing temperature and time, porous nanowires and nanoparticles of LiCoO2 are obtained. The electrochemical performances of these different nanostructures obtained under the respective annealing conditions are evaluated. It is shown that nanoparticles formed under the annealing condition of 700 °C, 1.5 h perform the best, delivering an initial capacity of around 135 mA h g(-1), which is close to the theoretical capacity of LiCoO2, 140 mA h g(-1). They also exhibit a capacity retention of around 93% by 100 cycles at 0.1 C. Comparisons are made between our LiCoO2 material obtained under different annealing conditions and those in the literature.
RESUMEN
The output and particle size distribution of several series of aqueous solutions were measured to define quantitatively the practical limits of the solution properties acceptable for aerosol production by the aeroneb micropump nebulizer. Aerosol output measurements were made gravimetrically and the particle size distributions were obtained by laser diffractometry. Solution properties were obtained from the literature by interpolation of the best-fit curve of the property plotted as a function of composition. For nonionic solutes, addition of sodium chloride dramatically increased the output rate and also decreased the droplet size at low solute concentrations. Increasing viscosity also caused a significant decrease in output. Cesium chloride displayed increased output rate with concentration due to the rising density. Based on calculations with the number of apertures and oscillatory frequency, low output rates appeared to be a consequence of apertures failing to produce a droplet with each oscillation. Overall, ionic strength, density, surface tension, and viscosity affected the output rate in a manner that can be now empirically predicted.