RESUMEN
Amazon aquatic systems have been affected by organic pollution from urbanized regions. This study was conducted to determine the levels, sources, and distribution patterns of 16 polycyclic aromatic hydrocarbons (PAHs) and 6 steroid markers in surficial sediments from an important urbanized Amazon estuarine system (Belém, PA, Northern Brazil). Total PAH concentration (∑PAH) ranged from 878.2 to 9905.7 ng g-1, 3295.2 ng g-1 on average, suggesting a highly contaminated environment. PAH molecular ratios and statistical analysis indicated that PAH originated from a mixture of local sources emissions, mainly related to the combustion of fossil fuels and biomass. Coprostanol levels (maximum concentration = 292.52 ng g-1) could be compared to the mid-range reported in the literature. Studied stations, except for one, presented sterol ratio data indicating organic matter related to untreated sewage. Sterols indicative of sewage contamination showed a correlation with pyrogenic PAH amounts which are transported by the same channels where sewage is discharged.
Asunto(s)
Hidrocarburos Policíclicos Aromáticos , Contaminantes Químicos del Agua , Brasil , Estuarios , Sedimentos Geológicos/análisis , Contaminantes Químicos del Agua/análisis , Aguas del Alcantarillado/análisis , Monitoreo del Ambiente , Hidrocarburos Policíclicos Aromáticos/análisisRESUMEN
The individual concentrations and sources of sterols in sediments samples collected in two periods 2017 (dry period /March and rainy period/August) were determined along with the Sergipe-Poxim estuarine system, Aracaju, Brazil. The individual sterols concentration ranged from 135 to 21,746 ng g-1 (March) and 191 to 144,748 ng g-1 (August) and the distribution was mainly dominated by ß-sitosterol in both periods with 37.2% (March) and 70.8% (August) of the total sterols found. In all the sampling sites, the coprostanol levels were higher than 100 ng g1 (March) and 500 ng g-1 (August), indicating sewage contamination. Diagnostic ratios between sterols suggested the predominance of sewage sources. Pearson correlation assessed a correlation significant (March) and negligible (August) between coprostanol concentration levels and organic matter. The principal component analysis (PCA) showed that the sterols levels influenced strongly C1, as well as C2 distinguished between the plant sterols and from sewage.
Asunto(s)
Monitoreo del Ambiente , Contaminantes del Agua/análisis , Brasil , Colestanol , Heces , Sedimentos Geológicos , Aguas del Alcantarillado , EsterolesRESUMEN
The distribution, sources and potential ecological risk of priority polycyclic aromatic hydrocarbons (PAHs) in sediment from the Amazon River Estuary (Macapá and Santana, Amapá, Northern Brazil) were investigated. The total PAHs concentration (∑PAH) ranged from 22.2 to 158.9â¯ngâ¯g-1 dw (mean value 49.4â¯ngâ¯g-1 dw). PAHs levels in the study area were relatively low than those in nearby areas and other coastal zones worldwide, and could be considered as baseline for PAHs in Amazonic sediments. PAHs ratios and the statistical analysis showed that fossil fuel and biomass combustions, primarily from local sources, were the dominant PAHs origins. The potential ecological risk was assessed on the basis of the sediment quality guidelines, and it was found that PAHs in the sediments of the Amazon River Estuary do not cause adverse effects on living organisms; however, the abundance of naphthalene and the presence of dibenzo[a,h]anthracene and benzo[a]pyrene deserve more attention.
Asunto(s)
Estuarios , Sedimentos Geológicos/análisis , Hidrocarburos Policíclicos Aromáticos/análisis , Contaminantes Químicos del Agua/análisis , Brasil , Ecotoxicología/métodos , Monitoreo del Ambiente , Combustibles Fósiles , RíosRESUMEN
The 16 priority PAH were determined in sediment samples from the insular zone of Guajará Bay and Guamá River (Southern Amazon River mouth). Low hydrocarbon levels were observed and naphthalene was the most representative PAH. The low molecular weight PAH represented 51% of the total PAH. Statistical analysis showed that the sampling sites are not significantly different. Source analysis by PAH ratios and principal component analysis revealed that PAH are primary from a few rate of fossil fuel combustion, mainly related to the local small community activity. All samples presented no biological stress or damage potencial according to the sediment quality guidelines. This study discuss baselines for PAH in surface sediments from Amazonic aquatic systems based on source determination by PAH ratios and principal component analysis, sediment quality guidelines and through comparison with previous studies data.