RESUMEN

This paper reports on the role of oxidised carbon nanotubes (oxMWCNTs) present in poly-3,4-ethylenedioxytiophene (PEDOT)/graphene oxide (GOx) composite. The final ternary composites (pEDOT/GOx/oxMWCNTs) are synthesised by an electrodeposition process from the suspension-containing monomer, oxidised carbon nanotubes and graphene oxide. Dissociated functional groups on the surface of graphene oxide play a role of counter-ions for the polymer chains. Detailed physicochemical and electrochemical characterisation of the ternary composites is presented in the paper. The results prove that the presence of oxMWCNTs in the ternary composites doubles the capacitance values compared to the binary ones (450 vs. 270 F cm-3 for PEDOT/GOx/oxMWCNTs and PEDOT/GOx, respectively). The amount of carbon nanotubes in the synthesis solution is crucial for physicochemical properties of the composites, their adhesion to the electrode substrate and the electrochemical performance.