RESUMEN
Mechanochemical reactions, achieved through milling, grinding, or other mechanical actions, have emerged as a solvent-free alternative to traditional solution-based chemistry. Mechanochemistry not only provides the opportunity to eliminate bulk solvent use, reducing waste generation, but also unveils a new reaction strategy which enables the realization of reactions previously inaccessible in solution. While the majority of organic reactions facilitated by mechanical force traditionally follow two-electron transfer pathways similar to their solution-based counterparts, the field of mechanochemically induced single-electron transfer (SET) reactions has witnessed rapid development. This review outlines examples of mechanochemical reactions facilitated by the SET process, focusing on the reagents that initiate SET, thereby positioning mechanochemistry as a burgeoning field within the realm of single-electron chemistry.
RESUMEN
Tibetan cultures reflect deeply rooted, regional interactions and diverse subsistence practices across varied high-altitude environments of the Tibetan Plateau. Yet, it remains unclear how these cultural relationships and social interactions took shape through time and how they were influenced by ecologically oriented behavioral strategies (e.g. mobility) emerging in prehistory. Recent applications of network analysis provide novel tools to quantitatively measure shared forms of material culture, but there have been fewer attempts to couple social network analysis with fine-grained geospatial modelling of prehistoric human mobility in Tibet. In this study, we developed an integrated high-resolution geospatial model and network analysis that simulates and correlates subsistence-based mobility and ceramic-based cultural material connectivity across the Tibetan Plateau. Our analysis suggests that (1) ecologically driven patterns of subsistence-based mobility correspond geographically with Bronze and Iron Ages settlement patterns across the Tibetan Plateau; (2) diverse material interaction networks among communities within western and central Tibet and trans-Himalayan connectivity across the broader Inner Asian Mountain Corridor can be linked to modeled differences in regional networks of subsistence mobility. This research provides ecological and archaeological insights into how subsistence-oriented mobility and interaction may have shaped documented patterns of social and material connectivity among regional Bronze and Iron Age communities of the Tibetan Plateau, prompting a reconsideration of Tibet's long-term cultural geography.
RESUMEN
We report a self-starting mode-locked all-polarization-maintaining (PM) holmium (Ho)-doped fiber oscillator operating at â¼2.08 µm based on nonlinear polarization evolution (NPE). The oscillator is configured as a linear cavity structure with two output ports exhibiting completely different pulse characteristics. One output port of the oscillator can deliver a stable, clean soliton-like pulse with a pulse duration of 439â fs and an average power of 7.5â mW at a fundamental repetition rate of 61.67â MHz. In contrast, the other port delivers a low-quality pulse with a complex structure. Numerical simulations reveal that the pulse difference between the two ports is mainly caused by the nonlinear optical interactions between the slow-axis and fast-axis modes in the PM fibers. Furthermore, the obtained clean pulses show significant improvements in relative intensity noise and power stability compared to complex pulses. Our study can help researchers obtain high-quality, stable pulses from PM-NPE mode-locked fiber oscillators.