1.
Angew Chem Int Ed Engl
; 58(6): 1789-1793, 2019 Feb 04.
Artículo
en Inglés
| MEDLINE
| ID: mdl-30479048
RESUMEN
Primary, secondary, and tertiary alkyl radicals formed by the photocatalyzed oxidation of organosilicates underwent efficient carbonylation with carbon monoxide (CO) to give a variety of unsymmetrical ketones. This study introduces the possibility of radical carbonylation under a photooxidative regime.