RESUMEN
This paper presents an overview of unit processes that lead to potential mercury contamination during gold processing, which can pose serious health, environmental and technical concerns. Mercury release in gold processing streams is attributed to its dissolution from mercury bearing gold ores during cyanide leaching, and its mobile nature in the subsequent stages (e.g., carbon adsorption, elution, Zn precipitation/electrowinning, and smelting) and tailing storage facilities. Although retorting prior to smelting and sulphur-impregnated carbon filters have been developed to ensure minimal mercury contamination, these methods deal with gaseous mercury which is highly toxic and still a serious threat for both the environment and workers. Moreover, spent carbon filters containing high mercury concentrations introduce a new environmental issue. Therefore, there is a demonstrated need for safer and more efficient removal and sequestration techniques. Thus, this work includes a review of mercury removal from activated carbon as well as current mercury treatment and stabilization practices including precipitation, adsorption, cementation, ion exchange and solvent extraction. In addition, emerging mercury remediation materials such as nanomaterials and bimetals with a promising potential in sustainable management, sequestration, and stabilization of mercury from aqueous media will be highlighted. In summary, the results show a high mercury removal capacity of the outlined materials and techniques (between 70 to around 100% removal). However, one of the issues that emerges from these studies is the lack of selectivity of reagents for mercury capture from aqueous solutions containing precious metals. In this regard, future studies with more focus on the selective mercury removal from activated carbon, and then its precipitation from solutions using substances with a greater adsorption capacity to mass ratio (suitable for safe disposal), are therefore recommended.
Asunto(s)
Mercurio , Adsorción , Carbón Orgánico , Gases , Oro , HumanosRESUMEN
Laser desorption/ionization time-of-flight mass spectra of three thermally labile low molecular weight organoselenium compounds (selenomethionine, selenoethionine, trimethylselenonium iodide) in human urine matrix have been obtained by using surface-assisted laser desorption/ionization mass spectrometry (SALDI-MS). Four active layers, active carbon, silica sol-gel, and silica sol-gel impregnated with crown ether and with active carbon, were deposited on three different support substrates: (i) microscope slide coverslips; (ii) Al foil; and (iii) Cu tapes. Primarily protonated molecular ions and alkali metal adducts were observed in the mass spectra. A mixed-silica sol-gel and active carbon substrate active layer gave the best signal response for all compounds. Sol-gel substrates offered very clean backgrounds compared to the pure active carbon layers; however, the mass spectral signal intensities acquired were substantially lower for the sol-gel surfaces than those of the pure active carbon under the same conditions. Cu tape and Al foil support materials gave strong mass spectra of molecular ions and alkali metal molecular ion adducts, with lower Na and K adducts found with the Cu tape than with Al foil. Glass coverslips gave no response under all experimental conditions examined. Aerosol deposition was used to prepare SALDI substrates to avoid the localized "sweet spot" phenomenon encountered in conventional SALDI substrate preparation. Various nebulizers were examined and found to be effective in producing SALDI films with controlled and reproducible thicknesses. We were able to obtain exact mass identification of all three selenium species by high-resolution TOF-MS. To the best of our knowledge, this is the first time low molecular weight organoselenium compounds have been identified by SALDI-high-resolution TOF-MS.