RESUMEN
Among the emerging contaminants today, pharmaceuticals are some of the most demanding chemical compounds when it comes to understanding their transport within aquifers. The transport of pharmaceuticals in an unsaturated zone is influenced by many factors, including compound sorption and degradation, which is essential in assessing contaminant migration in soil and groundwater. Coarse-gravel aquifers are particularly important for drinking water sources and industrial water supply. Globally, little data on the transport characteristics of coarse-gravel unsaturated zones is available. However, such data is crucial to understanding the transport of pollutants and to implementing the appropriate management strategies to protect the aquifers. In this article, we present tracer experiments employed to determine pharmaceutical transport parameters in the coarse-gravel unsaturated zone. The tracer experiment was performed as a multi-tracer exercise, where deuterated water was infiltrated as a conservative tracer to define the characteristics of the unsaturated zone, together with pharmaceuticals (propyphenazone, caffeine and carbamazepine) as reactive tracers. Based on the breakthrough curves measured at various depths, inverse modelling in combination with analytical and numerical methods (HYDRUS-1D) was performed. Hydraulic parameters for the unsaturated zone were estimated. Linear sorption coefficients (Kd) and degradation half-lives (t1/2) were evaluated for each pharmaceutical. In the unsaturated zone of the coarse-gravel aquifer caffeine has the lowest sorption capacity (mean Kd = 0.027 Lkg-1), while the sorption coefficient of propyphenazone is higher (Kd = 0.07 Lkg-1). Results for the degradation constant of the first order and t1/2 indicate that caffeine has the fastest decay rate (highest t1/2 = 69.3 days), followed by propyphenazone (highest t1/2 = 92.4 days). The parameters for carbamazepine could not be determined using an advection dispersion equation.
Asunto(s)
Agua Subterránea , Contaminantes Químicos del Agua , Antipirina/análogos & derivados , Cafeína , Carbamazepina , Movimientos del AguaRESUMEN
Storage of bottled waters in varying ambient conditions affects its characteristics. Different storage conditions cause changes in the initial chemical composition of bottled water which lead to the occurrence of precipitates with various morphologies. In order to assess the relationship between water composition, storage conditions and precipitate morphology, a study of four brands of Slovenian bottled water stored in PET bottles was carried out. Chemical analyses of the main ions and measurements of the physical properties of water samples were performed before and after storage of water samples at different ambient conditions. SEM/EDS analysis of precipitates was performed after elapsed storage time. The results show that the presence of Mg2+, SO42-, SiO2, Al, Mn and other impurities such as K+, Na+, Ba and Sr in the water controlled precipitate morphology by inhibiting crystal growth and leading to elongated rhombohedral calcite crystal forms which exhibit furrowed surfaces and calcite rosettes. Different storage conditions, however, affected the number of crystallization nuclei and size of calcite crystals. Hollow calcite spheres composed of cleavage rhombohedrons formed in the water with variable storage conditions by a combination of evaporation and precipitation of water droplets during high temperatures or by the bubble templating method.
Asunto(s)
Carbonato de Calcio , Agua Potable , Dióxido de Silicio , Eslovenia , Contaminantes Químicos del AguaRESUMEN
Northern hemisphere elementary circulation mechanisms, defined with the Dzerdzeevski classification and published on a daily basis from 1899-2012, are analysed with statistical methods as continuous categorical time series. Classification consists of 41 elementary circulation mechanisms (ECM), which are assigned to calendar days. Empirical marginal probabilities of each ECM were determined. Seasonality and the periodicity effect were investigated with moving dispersion filters and randomisation procedure on the ECM categories as well as with the time analyses of the ECM mode. The time series were determined as being non-stationary with strong time-dependent trends. During the investigated period, periodicity interchanges with periods when no seasonality is present. In the time series structure, the strongest division is visible at the milestone of 1986, showing that the atmospheric circulation pattern reflected in the ECM has significantly changed. This change is result of the change in the frequency of ECM categories; before 1986, the appearance of ECM was more diverse, and afterwards fewer ECMs appear. The statistical approach applied to the categorical climatic time series opens up new potential insight into climate variability and change studies that have to be performed in the future.
Asunto(s)
Atmósfera/análisis , Modelos Estadísticos , Predicción , Periodicidad , Estaciones del Año , Factores de TiempoRESUMEN
The stable isotopic composition (delta(2)H and delta(18)O) of short-term (daily) precipitation collected from October 2002 to September 2003 at two stations in a coastal, karstic area in south-western Slovenia was investigated. In addition, monthly composite samples were collected and analysed for comparison with amount-weighted monthly means. The delta(2)H and delta(18)O values obtained show a wide range and reflect seasonal climatic variations. Deuterium excess and local meteoric water lines (LMWLs) were determined and cumulative frequency analysis and coincidence tests were performed. The statistical coincidence test showed that the LMWLs calculated from monthly data for Portoroz and Kozina are coincident, but the LMWLs calculated from daily precipitation events are not. This difference could be explained by the greater variance of the isotopic composition of daily precipitation in comparison to monthly composite samples and also to the influence of evaporation during events below<1 mm at Portoroz during the extremely dry and warm spring-summer season of 2003. Finally, synoptic maps and backward trajectories of a selected precipitation event showed that changes of isotopic composition are related to mixing of air masses originating from the continent and Mediterranean cyclogenesis.
Asunto(s)
Deuterio/análisis , Monitoreo del Ambiente/métodos , Isótopos de Oxígeno/análisis , Lluvia/química , Movimientos del Aire , Clima , Monitoreo del Ambiente/estadística & datos numéricos , Espectrometría de Masas , Estaciones del Año , Eslovenia , Factores de TiempoRESUMEN
Bottled water is a food product that considerably depends on the environment from which it originates, not only at the place where it is produced, but predominantly on the conditions in the recharge area of the wells captured for bottling. According to their source and the bottling process, bottled waters can be divided into natural and artificially sparkling waters, still and flavoured waters. These waters originate from various parts of the hydrological cycle and their natural origin is reflected in their hydrogen and oxygen stable isotopic compositions (delta(2)H and delta(18)O). A total of 58 domestic and foreign brands and 16 replicates of bottled waters, randomly collected on the Slovene market in September 2004, were analysed for delta(2)H and delta(18)O. The isotopic composition varied between -83 per thousand and -46 per thousand with an average of -66 per thousand for hydrogen, and between -11.9 per thousand and -7.5 per thousand with an average of -9.6 per thousand for oxygen. This investigation helped (1) to determine and test the classification of bottled waters, (2) to determine the natural origin of bottled water, and (3) to indicate differences between the natural and production processes. The production process may influence the isotopic composition of flavoured waters and artificially sparkling waters. No such modification was observed for still and natural sparkling waters. The methods applied, together with hydrological knowledge, can be used for the authentication of bottled waters for regulatory and consumer control applications.