RESUMEN

We are reporting the unexpected reaction between bromo-boron subphthalocyanine (Br-BsubPc) and THF, 1,4-dioxane or γ-butyrolactone that results in the ring opening of the solvent and its addition into the BsubPc moiety. Under heating, the endocyclic C-O bond of the solvent is cleaved and the corresponding bromoalkoxy-BsubPc derivative is obtained. These novel alkoxy-BsubPc derivatives have remaining alkyl-bromides suitable for further functionalization. The alkoxy-BsubPcs maintain the characteristic strongly absorption in visible spectrum and their fluorescence quantum yields.

Asunto(s)

Compuestos de Boro/síntesis química , Indoles/síntesis química , Compuestos de Boro/química , Dioxanos/química , Indoles/química , Isoindoles , Lactonas/química , Estructura Molecular

RESUMEN

A family of seven organic triphenylamine-based dyes suitable for dye-sensitized solar cell (DSSC) applications is reported. The donor portion of these dyes has been systematically modified using polymerisable thienyl subunits. The physicochemical properties and device performance are discussed with device efficiencies ranging from 5.51 to 6.65%.

RESUMEN

The syntheses and physicochemical properties for a series of 2,6-disubstituted-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dyes are reported. The use of chromophores or redox active species as π-spacers, such as BODIPY, requires the inclusion of a sufficiently conjugated donor in order to achieve appropriate charge separation upon photoexcitation. The information derived from this study offers guiding principles for incorporating strongly absorbing, non-innocent π-spacers in organic dye design.

RESUMEN

Fluoride abstraction from a BODIPY dye gives a well defined borenium ion which can be converted to a borenium hydride via treatment with DIBAL-H.