RESUMEN
A novel one-step synthesis method of FeCl3-graphite intercalation compounds (FeCl3-GICs) by an arc discharge in aqueous solution was reported for the first time. It presented a simply and controllable way to synthesize FeCl3-GICs. The structure of the stage 7 GICs was examined and characterized by X-ray diffraction. X-ray photoelectron spectroscopic study of stage 7 of FeCl3-GICs was also carried out. The change in the binding energy suggests the nature of charge transfer and lowering of Fermi level as has been reported previously for other acceptor intercalation compounds.
Asunto(s)
Compuestos Férricos/química , Grafito/química , Cloruros , Modelos Moleculares , Oxígeno/química , Soluciones/química , Análisis Espectral , Difracción de Rayos XRESUMEN
The heat resistant property of silver-loading zeolite 4A antibacterial agent (SLZ) was investigated by heat treatment methodology. The morphological and structural changes of the specimens were characterized by using differential thermal analyzer (TG-DTA), scanning electron microscopy, and X-ray diffraction techniques. The particle size of the specimens was measured by Malvern instruments zetasizer systems, and silver content of specimens was determined by inductively coupled plasma spectrometer. Escherichia coli (E. coli) was chosen as indicators of fecal contamination to evaluate the antibacterial effect of the specimens by minimum inhibitory concentration method. The service life of the specimens was also tested. The experimental results indicated that as heat-treatment temperature increases, the particle size increases, more aggregating occurs, silver content decreases, the color of SLZ gradually changes from white to brown, and the antibacterial ability falls. The release rate of Ag(+) cation from SLZ became slow after heat treatment at 400, 450, and 500 degrees C, thus resulting in prolonged service life of SLZ. When the heat-treatment temperature approached 800 degrees C, the collapse of SLZ structure occurred, and the crystals of SiO(2) and Al(2)O(3) were formed after recrystallization. Consequently, the heat resistant temperature of SLZ can be as high as 500 degrees C. SLZ could be used in antibacterial plastics, antibacterial fibers, or biomedical materials.