RESUMEN

Urban road dust (URD) is one of the most important non-point sources of pollution in agglomerations. The aim of this study was to assess the seasonal toxic effects of URD runoff in two regions of Poland. The concentrations of elements in URD and leachate were studied. The impact of pollutants in URD runoff on water organisms was evaluated using Daphtoxkit F and Rotoxkit F (LC50). The acute toxicity tests for crustaceans and rotifers were selected as the response of these taxa reflects the impact on zooplankton, a key component of aquatic ecosystem and the basis of most food webs. The concentrations of elements were found to vary depending on the site, although URD samples collected in Katowice agglomeration (Upper Silesia) had higher values of elements (Mn, Cu, Zn, As) compared to Wroclaw (Lower Silesia). The concentrations of Mn, Zn, As, Cr, and Mg in water-soluble fraction of URD were higher in summer and winter in the Upper Silesia region due to rainwater runoff resulting from traffic, industries, post-industrial waste, and the presence of old heating systems. When comparing the content of elements in the water-soluble fraction between seasons, Zn, As, Cr, and Al concentrations were slightly higher in winter. The highest mortality of Daphnia magna and Brachiouns calyciflorus was observed in URD from both agglomerations in winter. However, the mortality is likely due to the concentration of elements or/and the coexistence of an unknown compound or a synergistic effect of the studied elements. This study highlights the alarming seasonal sources of elements in URD runoff, which will directly enter the food chain and affect the entire ecosystem, and human health.

Asunto(s)

RESUMEN

Road dust is an important inexhaustible source of particulate matter from traffic and the resuspension of finer particles carried by wind and traffic. The components of this material are of both natural and anthropogenic origin. Sources of particulate pollution are vehicles and road infrastructure. The work aimed to analyze the mass fraction of the finest fractions of road dust (<0.1 mm) collected from highways and expressways with asphalt and concrete surfaces. Sampling points were located in the central and southern parts of Poland. The research material was sieved on a sieve shaker. It has been proven that concrete pavement is less susceptible to abrasion than asphalt pavement. Particles formed under the influence of the erosion of asphalt and concrete belong to the fraction gathering coarser particles than the critical for this research fraction (<0.1 mm). It was found that limiting the area with sound-absorbing screens leads to the accumulation of fine road dust in this place, contrary to the space where are strong air drafts that remove smaller particles from the vicinity of the road. In general, the mass fraction of particles smaller than 100 µm in road dust was from 12.8% to 3.4% for asphalt surfaces and from 12.0% to 6.5% for concrete surfaces.

RESUMEN

The manuscript presents an innovative and holistic approach to quantifying PAHs and BTEX emissions from the grilling process and indicates a novel driven-toxicity-based solution to recognize health effects related to BBQ emissions. The exposure scenario includes the type of grilling device, food type, and individual attitudes, but also a keen understanding of the broad health implications related to the gaseous/particulate PAHs emission, or age-related effects. The calculated incremental lifetime cancer risk (ILCR) associated with the exposure to PAH congeners and BTEX indicates an unacceptable level in the case of charcoal and briquette grilling with the highest values for professional cooks. The sum of 15 PAH concentrations in grilled foods was highest for meat grilling over charcoal briquettes - 382,020.39 ng/m3 and lowest for meat grilling on a gas grill - 1442.16 ng/m3. The emissions of BTEX from lump charcoal grilling were 130 times higher compared to the gaseous grill. In all considered scenarios lump-charcoal and charcoal briquettes grilling derive the ILCR above the 10-4, indicating negative effects of traditional grills on human health. The paper completes knowledge of wide-ranging health implications associated with BBQs, a topic that is almost completely unaddressed among the scientific community and policymakers.

Asunto(s)

RESUMEN

The main objective of the study was to determine the effects of the water extracts of urban road dust (URD) samples on the growth inhibition and mortality rate of Heterocypris incongruens in various site environment type. We collected 24 samples of the road dust close to highways, main roads, crossroads as well as at other places i.e. residential area, and suburbs. We determined the selected metals (Al, As, Ba, Cd, Co, Cr, Cu, Ga, Mg, Mn, Mo, Ni, Pb, Rb, Sr, Ti, Tl, V and Zn) content of the water extracts of these samples as well as we tested the toxicity of the water extracts of URD samples using a commercial test Ostracodtoxkit F. We observed the lowest values of the growth inhibition of H. incongruens for residential areas and suburbs (<50%). The highest growth inhibition we found for water extracts of URD samples collected at the main roads in the Katowice urban area and crossroads in the urban areas. Although the mortality and growth inhibition of H. incongruens were related to the road traffic emissions it was impossible to clearly relate this finding with the urban site category.

RESUMEN

We investigated the contribution of waste fires to air pollution. The annual emission of pollutants (CO, NOx, PM10, SO2) and greenhouse gases (CH4, CO2) were evaluated. The prediction of emissions is based on statistical data from 79 large fires that took place in Poland in 2018. We analyzed the spatial distribution of these fires along with the expected emission factor. The predicted emissions from all large waste fires was in total: 2.05 ± 0.10Gg of CH4, 19.60 ± 0.90Gg of CO, 196 ± 13Gg of CO2, 0.963 ± 0.047Gg of NOx, 5.26 ± 0.58Gg of PM10, and 0.72 ± 0.12Gg of SO2. For the evaluation of the consequences, we used the number of people exposed to PM10 emitted in one very big fire. Almost 6.5 million people were exposed to an additional 1-hour average concentration of PM10 higher than 10 µg/m3 and over 360 thousand were exposed to a concentration higher than 100 µg/m3.

Asunto(s)

RESUMEN

This study aimed to determine the relative densities of populations of particles emitted in fire experiments of selected materials through direct measurement and parametrization of size distribution as number (NSD), volume (VSD), and mass (MSD). As objects of investigation, four typical materials used in construction and furniture were chosen: pinewood (PINE), laminated particle board (LPB), polyurethane (PUR), and poly(methyl methacrylate) (PMMA). The NSD and VSD were measured using an electric low-pressure impactor, while MSD was measured by weighing filters from the impactor using a microbalance. The parametrization of distributions was made assuming that each distribution can be expressed as the sum of an arbitrary number of log-normal distributions. In all materials, except PINE, the distributions of the particles emitted in fire experiments were the sum of two log-normal distributions; in PINE, the distribution was accounted for by only one log-normal distribution. The parametrization facilitated the determination of volume and mass abundances, and therefore, the relative density. The VSDs of particles generated in PINE, LPB, and PUR fires have similar location parameters, with a median volume diameter of 0.2-0.3 µm, whereas that of particles generated during PMMA burning is 0.7 µm. To validate the presented method, we burned samples made of the four materials in similar proportions and compared the measured VSD with the VSD predicted based on the weighted sum of VSD of raw materials. The measured VSD shifted toward smaller diameters than the predicted ones due to thermal decomposition at higher temperatures.